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Rovibrational transitions in the hydrogen and antihydrogen molecular ions $H_2^+$ and $\overline{H}_2^-$ offer the possibility of testing Lorentz and CPT symmetry to extremely high precision, in principle attaining $O(10^{-17})$. In this…
Doppler and Sisyphus cooling of $^{174}$YbOH are achieved and studied. This polyatomic molecule has high sensitivity to physics beyond the Standard Model and represents a new class of species for future high-precision probes of new…
Quantum interference between multiple pathways in molecular photodissociation often results in angular momentum polarization of atomic products and this can give deep insight into fundamental physical processes. For dissociation of diatomic…
The rich internal structure and long-range dipole-dipole interactions establish polar molecules as unique instruments for quantum-controlled applications and fundamental investigations. Their potential fully unfolds at ultracold…
We establish a correspondence between the electric dipole matrix elements of a polyatomic symmetric top molecule in a state with nonzero projection of the total angular momentum on the symmetry axis of the molecule and the magnetic dipole…
The quantum description of a particle moving in a deformed potential is investigated. A pseudostate (PS) basis is used to represent the states of the composite system. This PS basis is obtained by diagonalizing the system Hamiltonian in a…
In astrophysics, atomic transition line opacity is a primary source of uncertainty in theoretical calculations of radiative transfer. Much of this uncertainty is dominated by the inability to resolve the lines in frequency, leading to the…
This thesis is mainly devoted to the study of the quantum properties of optical parametric oscillators (OPOs), which are nowadays the sources of the highest-quality quantum-correlated light, apart from fundamental tools in the…
Ultra-hot Jupiters are perfect targets for transmission spectroscopy. However, their atmospheres feature strong spatial variations in temperature, chemistry, dynamics, cloud coverage, and scale height. This makes transit observations at…
We want to study the rotational spectra of CH$_3^{13}$C(O)CH$_3$ and $^{13}$CH$_3$C(O)CH$_3$ and search for them in Sagittarius B2(N2). We investigated the laboratory rotational spectrum of isotopically enriched CH$_3^{13}$C(O)CH$_3$…
Based on a simplest molecular orbital theory of H$_{2}^{+}$, a three-parameter model potential function is proposed to describe ground-state diatomic systems with closed-shell and/or S-type valence-shell constituents over a significantly…
We present various types of reduced models including five vibrational modes and three electronic states for the pyrazine molecule in order to investigate the lifetime of electronic coherence in a rigid and neutral system. Using an ultrafast…
We demonstrate that the Dynamic Mode Decomposition technique can effectively reduce the amount of noise in Dispersive Fourier Transform dataset; and allow for finer quantitative analysis of the experimental data. We therefore were able to…
Spectral characterization of Super-Earth atmospheres for planets orbiting in the Habitable Zone of M-dwarf stars is a key focus in exoplanet science. A central challenge is to understand and predict the expected spectral signals of…
A method for determination of the bimolecular recombination constant in working double-injection diodes such as organic light-emitting diodes (OLEDs) and organic photovoltaics (OPVs) using impedance spectroscopy is proposed. The proposed…
We propose a system-oriented basis-set design based on even-tempered basis functions to variationally encode electronic ground-state information into molecular orbitals. First, we introduce a reduced formalism of concentric even-tempered…
In the past decade, photoemission orbital tomography (POT) has evolved into a powerful tool to investigate the electronic structure of organic molecules adsorbed on surfaces. Here we show that POT allows for the comprehensive experimental…
Out-of-time-order correlators (OTOCs) can be used to probe how quickly a quantum system scrambles information when the initial conditions of the dynamics are changed. In sufficiently large quantum systems, one can extract from the OTOC the…
Chapman's model for ozone concentration is studied. In this nonlinear model, the photodissociation coefficients for $O_{2}$ and $O_{3}$ are time-depending due to earth-rotation. From the Kapitsa's method, valid in the high frequency limit,…
Three-quasiparticle $K$-isomeric states in odd-mass $N=106$ isotones within the $A\sim 180$ mass region are systematically investigated using configuration-constrained potential energy surface calculations. The calculations successfully…