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The tunable bandgap from 0.3 eV to 2 eV of black phosphorus (BP) makes it to fill the gap in graphene. When studying the properties of BP more comprehensive, scientists have discovered that many two-dimensional materials, such as tellurene,…

Optics · Physics 2021-03-01 Ying-Ying Li , Bo Gao , Ying Han , Bing-Kun Chen , Jia-Yu Huo

We perform a systematic first-principles study of phosphorene in the presence of typical monovalent (hydrogen, fluorine) and divalent (oxygen) impurities. The results of our modeling suggest a decomposition of phosphorene into weakly bonded…

Materials Science · Physics 2015-05-01 D. W. Boukhvalov , A. N. Rudenko , D. A. Prishchenko , V. G. Mazurenko , M. I. Katsnelson

Within the past few years, atomically thin black phosphorus (BP) has been demonstrated as a fascinating new 2D material that is promising for novel nanoelectronics and nanophotonics applications, due to its many unique properties such as…

Applied Physics · Physics 2019-08-06 Zi-Yu Chen , Rui Qin

We report on the mechanical properties of few-layer black phosphorus (BP) nanosheets, in high vacuum and as a function of time of exposure to atmospheric conditions [1]. BP flakes with thicknesses ranging from 4 to 30 nm suspended over…

We study the effect that the electron-electron interaction has on the properties of a multilayer electron system. We consider the case corresponding to filling factor unity in each layer. We find that as a function of the sample parameters…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 Luis Brey

Based on density functional theory calculations, the structural and electronic properties of polythiophene in periodic and oligomer forms have been investigated. In particular, the effects of Li or Cl adsorption onto a monolayer and Li or…

Materials Science · Physics 2015-01-28 T. P. Kaloni , G. Schreckenbach , M. S. Freund

We investigate the effect of charge carrier interaction with surface optical phonons on the band properties of monolayer black phosphorus induced by polar substrates. We develop an analytical method based on the Lee-Low-Pines theory to…

Mesoscale and Nanoscale Physics · Physics 2016-02-12 A. Mogulkoc , Y. Mogulkoc , A. N. Rudenko , M. I. Katsnelson

Boron phosphide (BP) is a (super)hard semiconductor constituted of light elements, which is promising for high demand applications at extreme conditions. The behavior of BP at high temperatures and pressures is of special interest but is…

Electronic properties of few-layer phosphorenes are investigated by the generalized tight-binding model. They are greatly diversified by the electric and magnetic fields ($E_z$ and $B_z$). The $E_z$-induced gap transition, Dirac cones,…

Materials Science · Physics 2017-03-15 Jhao-Ying Wu , Szu-Chao Chen , Godfrey Gumbs

We review the basic optical, electronic, optoelectronic, thermoelectric and mechanical properties of few-layer black phosphorus (BP), a layered semiconductor that can be exfoliated from bulk BP, the most stable allotrope of phosphorus. The…

Mesoscale and Nanoscale Physics · Physics 2017-10-17 Andrey Chaves , W. Ji , J. Maassen , T. Dumitrica , T. Low

Phosphorene, the single- or few-layer form of black phosphorus, was recently rediscovered as a twodimensional layered material holding great promise for applications in electronics and optoelectronics. Research into its fundamental…

Materials Science · Physics 2015-06-19 Liangzhi Kou , Changfeng Chen , Sean C. Smith

We investigate the semiclassical electronic transport properties of the bilayer silicene-like system in the presence of charged impurity. The trigonal warping due to the interlayer hopping, and its effect to the band structure of bilayer…

Mesoscale and Nanoscale Physics · Physics 2018-09-18 Chen-Huan Wu

We investigated theoretically the effect of covalent edge functionalization, with organic functional groups, on the electronic properties of graphene nanostructures and nano-junctions. Our analysis shows that functionalization can be…

Materials Science · Physics 2012-03-30 Caterina Cocchi , Alice Ruini , Deborah Prezzi , Marilia J. Caldas , Elisa Molinari

The electron-phonon interaction in monolayer graphene is investigated by using density functional perturbation theory. The results indicate that the electron-phonon interaction strength is of comparable magnitude for all four in-plane…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 K. M. Borysenko , J. T. Mullen , E. A. Barry , S. Paul , Y. G. Semenov , J. M. Zavada , M. Buongiorno Nardelli , K. W. Kim

We study theoretically the structural and electronic response of layered bulk black phosphorus to in-layer strain. Ab initio density functional theory (DFT) calculations reveal that the strain energy and interlayer spacing display a strong…

Materials Science · Physics 2016-10-04 Jie Guan , Wenshen Song , Li Yang , David Tomanek

Using density functional theory, we determine parameters of tight-binding Hamiltonians for a variety of Fabre charge transfer salts, focusing in particular on the effects of temperature and pressure. Besides relying on previously published…

Strongly Correlated Electrons · Physics 2013-04-25 A. C. Jacko , H. Feldner , E. Rose , F. Lissner , M. Dressel , Roser Valentí , Harald O. Jeschke

Using density functional tight-binding theory, we investigated the elastic properties and deformation and failure behaviors of pristine and defective carbon-phosphide (CP) monolayers subjected to uniform uniaxial tensile strain along…

Materials Science · Physics 2018-09-26 V. Sorkin , Y. W. Zhang

We investigate the electro-optic properties of black phosphorus (BP) thin films for optical modulation in the mid-infrared frequencies. Our calculation indicates that an applied out-of-plane electric field may lead to red-, blue-, or…

Mesoscale and Nanoscale Physics · Physics 2016-04-20 Charles Lin , Roberto Grassi , Tony Low , Amr S. Helmy

Spectral and transport properties of electrons in confined phosphorene systems are investigated in a five hopping parameter tight-binding model, using analytical and numerical techniques. The main emphasis is on the properties of the…

Mesoscale and Nanoscale Physics · Physics 2016-03-23 B. Ostahie , A. Aldea

We theoretically investigate the electronic and magneto-optical properties of rectangular, hexangular, and triangular monolayer phosphorene quantum dots (MPQDs) utilizing the tight-binding method. The electronic states, density of states,…

Mesoscale and Nanoscale Physics · Physics 2015-12-10 Rui Zhang , X. Y. Zhou , D. Zhang , W. K. Lou , F. Zhai , Kai Chang