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First principles calculations based on density functional theory reveal some unusual properties of BN sheet functionalized with hydrogen and fluorine. These properties differ from those of similarly functionalized graphene even though both…

Materials Science · Physics 2015-05-14 Jian Zhou , Qian Wang , Qiang Sun , Puru Jena

Black phosphorus (BP) offers considerable promise for infrared and visible photonics. Efficient tuning of the bandgap and higher subbands in BP by modulation of the Fermi level or application of vertical electric fields has been previously…

Controlling a thickness dependence of electronic properties for two-dimensional (2d) materials is among primary goals for their large-scale applications. Herein, employing a first-principles computational approach, we predict that Si…

Materials Science · Physics 2018-02-14 Oleksandr I. Malyi , Kostiantyn V. Sopiha , Ihor Radchenko , Ping Wu , Clas Persson

Using both DFT as well as $G_0W_0$ calculations, we investigate static and dynamic effects on the phosphorene band gap upon deposition and encapsulation on/in BN multilayers. We demonstrate how competing long- and short-range effects cause…

Materials Science · Physics 2016-10-05 Lukas Eugen Marsoner Steinkasserer , Simon Suhr , Beate Paulus

Silicon can be heavily doped with phosphorus in a single atomic layer (a $\delta$ layer), significantly altering the electronic structure of the conduction bands within the material. Recent progress has also made it possible to further dope…

Materials Science · Physics 2026-02-26 Quinn T. Campbell , Andrew D. Baczewski , Shashank Misra , Evan M. Anderson

We theoretically study the effect of electron-electron interactions in one-dimensional partially mixed helical states. These helical states can be realized at the edges of two-dimensional topological insulators with partially broken…

Strongly Correlated Electrons · Physics 2025-01-03 Zeinab Bakhshipour , Mir Vahid Hosseini

Nonmonotonic bending-induced changes of fundamental band gaps and quasiparticle energies are observed for realistic nanoscale phosphorene nanosheets. Calculations using stochastic many-body perturbation theory (sGW) show that even slight…

Materials Science · Physics 2019-06-12 Vojtech Vlcek , Eran Rabani , Roi Baer , Daniel Neuhauser

We investigated a suspended bilayer graphene where the bottom (top) layer is doped by boron (nitrogen) substitutional atoms by using Density Functional Theory (DFT) calculations. We found that at high dopant concentration (one B-N pair…

Materials Science · Physics 2016-05-25 Daniele Giofré , Davide Ceresoli , Mario I. Trioni

Electronic structures of single crystalline black phosphorus were studied by state-of-art angleresolved photoemission spectroscopy. Through high resolution photon energy dependence measurements, the band dispersions along out-of-plane and…

Materials Science · Physics 2015-06-16 C. Q. Han , M. Y. Yao , X. X. Bai , Lin Miao , Fengfeng Zhu , D. D. Guan , Shun Wang , C. L. Gao , Canhua Liu , Dong Qian , Y. Liu , Jin-feng Jia

Experimental studies on two-dimensional (2D) materials are still in the early stages, and most of the theoretical studies performed to screen these materials are limited to the room-temperature carrier-mobility in the free standing 2D…

Mesoscale and Nanoscale Physics · Physics 2020-07-30 Gautam Gaddemane , Maarten L. Van de Put , William G. Vandenberghe , Edward Chen , Massimo V. Fischetti

The electron-phonon interaction plays a crucial role in many fields of physics and chemistry. Nevertheless, its actual calculation by means of modern many-body perturbation theory is weakened by the use of model Hamiltonians that are based…

Materials Science · Physics 2015-05-15 Andrea Marini , Samuel Poncé , Xavier Gonze

Borophene has triggered a surge of interest due to its outstanding properties including mechanical flexibility, polymorphism, and opto-electrical anisotropy. Very recently, a novel semi-hydrogenated borophene, called $\alpha'$-4H, was…

We performed density functional theory calculations with self-consistent van der Waals corrected exchange-correlation (XC) functionals to capture the structure of black phosphorus and twelve monochalcogenide monolayers and find the…

Mesoscale and Nanoscale Physics · Physics 2020-01-01 Shiva P. Poudel , John W. Villanova , Salvador Barraza-Lopez

We propose a new paradigm of electronic devices based only on two electrodes separated by a gap, i.e. without any functional element bridging them. We use a tight-binding model to show that, depending on the type of material of the…

Mesoscale and Nanoscale Physics · Physics 2020-01-22 V. M. García-Suárez

As a new two-dimensional layered material, black phosphorus (BP) is a promising material for nanoelectronics and nano-optoelectronics. We use Raman spectroscopy and first-principles theory to report our findings related to low-frequency…

Many-body effects in condensed matter yield novel quantum states when the electronic density of states is enhanced. A vivid example is flat bands, which suppress kinetic energy and let interactions dominate, when they are filled with an…

In this work we introduce a low-energy Hamiltonian for single layer and bilayer black phosphorus that describes the electronic states at the vicinity of the gamma point. The model is based on a recently proposed tight-binding description…

Mesoscale and Nanoscale Physics · Physics 2015-09-02 J. M. Pereira , M. I. Katsnelson

We study the effects of insulating oxides in their crystalline forms on the energy band structure of monolayer and bilayer graphene using a \textit{first principles} density functional theory based electronic structure method and a local…

Materials Science · Physics 2011-12-09 Priyamvada Jadaun , Sanjay K. Banerjee , Leonard F. Register , Bhagawan Sahu

Fluorite structure ferroelectrics, especially hafnium oxide, are widely investigated for their application in non-volatile memories, sensors, actuators, RF devices and energy harvesters. Due to the metastable nature of the ferroelectric…

We study the environmental instability of mechanically exfoliated few-layer black phosphorus (BP). From continuous measurements of flake topography over several days, we observe an increase of over 200% in volume due to the condensation of…

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