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A semiempirical parametric method is proposed for modeling three-dimensional (time-resolved) vibronic spectra of polyatomic molecules. The method is based on the use of the fragment approach in the formation of molecular models for excited…

Chemical Physics · Physics 2007-05-23 S. A. Astakhov , V. I. Baranov

In this paper, we introduce Harmonics Virtual Lights (HVL), to model indirect light sources for interactive global illumination of dynamic 3D scenes. Virtual Point Lights (VPL) are an efficient approach to define indirect light sources and…

Graphics · Computer Science 2022-01-06 Pierre Mézières , François Desrichard , David Vanderhaeghe , Mathias Paulin

The encapsulation of hydrogen within fullerene/fullerane cages offers a promising avenue for studying high pressure hydrogen dynamics. Through ab initio molecular dynamics simulations, we investigate the behavior of a system consisting of…

Materials Science · Physics 2025-02-11 Leonard Constantin Gebac , Vasile Bercu

This work presents a computational framework for studying reaction dynamics via wavepacket propagation, employing the multiconfiguration time-dependent Hartree (MCTDH) method and its multilayer extension (ML-MCTDH) as the core…

Chemical Physics · Physics 2025-07-09 Xingyu Zhang , Qingyong Meng

A spectral element solver is developed for the high-fidelity simulation of the unsteady flow over an aerospike nozzle. The Navier-Stokes solver is a kinetic-energy-preserving, discontinuous Galerkin spectral element method (DGSEM) combined…

Fluid Dynamics · Physics 2025-11-20 Zachary Pyle , Gustaaf B. Jacobs

We present an implementation of the multiconfiguration time-dependent Hartree-Fock method based on the adaptive finite element method for molecules under intense laser pulses. For efficient simulations, orbital functions are propagated by a…

Quantum Physics · Physics 2023-01-09 Yuki Orimo , Takeshi Sato , Kenichi L. Ishikawa

Precision measurements are performed on highly excited vibrational quantum states of molecular hydrogen. The $v=12, J=0-3$ rovibrational levels of H$_2$ ($X^1\Sigma_g^+$), lying only $2000$ cm$^{-1}$ below the first dissociation limit, were…

Atomic Physics · Physics 2015-09-30 M. L. Niu , E. J. Salumbides , W. Ubachs

A vibrational wavepacket in SF$_6$, created by impulsive stimulated Raman scattering with a few-cycle infrared pulse, is mapped onto five sulfur core-excited states using table-top soft X-ray transient absorption spectroscopy between…

A new synchrotron study for CH$_2$F$_2$ from has been combined with earlier data. The onset of absorption, band I and also band IV, is resolved into broad vibrational peaks, which contrast with the continuous absorption previously claimed.…

We propose an ab-initio molecular dynamics method, capable to reduce dramatically the autocorrelation time required for the simulation of classical and quantum particles at finite temperature. The method is based on an efficient…

Strongly Correlated Electrons · Physics 2017-01-11 Sandro Sorella , Guglielmo Mazzola

We present a combined experimental and theoretical study of the vibrationally resolved valence photoelectron spectra of the complete series of thiouracils (2-thiouracil, 4-thiouracil and 2,4-dithiouracil) for binding energies between 8 and…

A new model for calculating nuclear level densities is investigated. The single-nucleon spectra are calculated in a relativistic mean-field model with energy-dependent effective mass, which yields a realistic density of single-particle…

Nuclear Theory · Physics 2008-11-26 R. Pezer , A. Ventura , D. Vretenar

We present a hybrid spectral element-Fourier spectral method for solving the coupled system of Navier-Stokes and Cahn-Hilliard equations to simulate wall-bounded two-phase flows in a three-dimensional domain which is homogeneous in at least…

Fluid Dynamics · Physics 2018-10-10 S. H. Challa , S. Dong , L. D. Zhu

The intrinsic difficulties in extracting the hadron resonances from reaction data are illustrated by using several exactly soluble $\pi\pi$ scattering models. The finite-volume Hamiltonian method is applied to predict spectra using two…

Nuclear Theory · Physics 2016-10-12 T. -S. H. Lee , Jia-jun Wu , Hiroyuki Kamano

We address the double hydrogen transfer (DHT) dynamics of the porphycene molecule: A complex paradigmatic system where the making and breaking of H-bonds in a highly anharmonic potential energy surface requires a quantum mechanical…

Chemical Physics · Physics 2019-02-05 Yair Litman , Jeremy O. Richardson , Takashi Kumagai , Mariana Rossi

While quantum computing algorithms have been widely applied for electronic structure calculations, applications to molecular dynamics remain scarce. Complex and varied landscapes of molecular potential energy surfaces give rise to…

Quantum Physics · Physics 2026-04-02 K. Asnaashari , D. Bondarenko , R. V. Krems

Waveform decomposition is needed as a first step in the extraction of various types of geometric and spectral information from hyperspectral full-waveform LiDAR echoes. We present a new approach to deal with the "Pseudo-monopulse" waveform…

Signal Processing · Electrical Eng. & Systems 2023-06-12 Yuhao Xia , Shilong Xu , Hui Shao , Ahui Hou , Jiajie Fang , Fei Han , Youlong Chen , Jiaqi Wen , Yuwei Chen , Yihua Hu

We show that the single emitter linewidth underlying a broadened ensemble emission spectrum can be extracted from correlations among the stochastic intensity fluctuations in the ensemble spectrum. Spectral correlations can be observed at…

Optics · Physics 2009-03-13 Xavier Brokmann , Lisa Marshall , Moungi Bawendi

The vibrational spectra of CdSe/CdS superlattices (SLs) with different layer thicknesses are calculated from first principles within the density functional theory. It is shown that, along with folded acoustic and confined optical modes, a…

Materials Science · Physics 2023-02-27 A. I. Lebedev

In this paper we develop hydrodynamic models using spectral differential operators to investigate the spatial stability of swirling fluid systems. Including viscosity as a valid parameter of the fluid, the hydrodynamic model is derived…

Spectral Theory · Mathematics 2012-04-02 Diana Alina Bistrian , Florica Ioana Dragomirescu , George Savii