Related papers: Robustness of the pyrochlore structure in rare-ear…
A2Ir2O7 iridates were proven to crystallise in the geometrically frustrated pyrochlore structure, which remains stable upon rare-earth cation substitution, temperature variation, and external pressure application. However, the change of…
We have investigated the structural, electronic, and magnetic properties of the pyrochlore iridates Eu2Ir2O7 and Pr2Ir2O7 using a combination of resonant elastic x-ray scattering, x-ray powder diffraction, and resonant inelastic x-ray…
We study the structural evolution of Sr$_3$Ir$_2$O$_7$ as a function of pressure using x-ray diffraction. At a pressure of 54 GPa at room temperature, we observe a first-order structural phase transition, associated with a change from…
Neutron powder diffraction and inelastic measurements were performed examining the 5d pyrochlore Y$_2$Ir$_2$O$_7$. Temperature dependent measurements were performed between 3.4 K and 290 K, spanning the magnetic transition at 155 K. No sign…
The interplay of spin-orbit interactions and electronic correlations dominates the physical properties of pyrochlore iridates, R2Ir2O7 (R = Y, rare earth element), which are typically magnetic insulators. We report an…
Tb2Ti2O7, a pyrochlore system, has garnered significant interest due to its intriguing structural and physical properties and their dependence on external physical parameters. In this study, utilizing high-brilliance synchrotron X-ray…
We report a detailed study of structural and magnetic properties of the pyrochlore-type (Bi2-xPrx)Ru2O7 series. Eleven compositions with 0 <= x <= 2 were prepared by solid state reaction at 1050 degrees C and found to form a solid solution…
Geometrical frustration and spin-orbit coupling effect together play vital role to influence properties in pyrochlore based iridium oxides. Here we have investigated detailed structural, magnetic, thermodynamic and transport properties of…
We address the concomitant metal-insulator transition (MIT) and antiferromagnetic ordering in the novel pyrochlore iridate Eu2Ir2O7 by combining x-ray absorption spectroscopy, x-ray and neutron diffractions and density functional theory…
Several rare earth magnetic pyrochlore materials are well modeled by a spin-1/2 quantum Hamiltonian with anisotropic exchange parameters Js. For the Er2Ti2O7 material, the Js were recently determined from high-field inelastic neutron…
Superconducting and structural phase transitions in a pyrochlore oxide Cd2Re2O7 are studied under high pressure by x-ray diffraction and electrical resistivity measurements. A rich P-T phase diagram is obtained, which contains at least two…
Although materials that exhibit nearest-neighbor-only antiferromagnetic interactions and geometrical frustration theoretically should not magnetically order in the absence of disorder, few such systems have been observed experimentally. One…
The pyrochlore iridates, A$_2$Ir$_2$O$_7$, show a wide variety of structural, electronic, and magnetic properties controlled by the interplay of different exchange interactions, which can be tuned by external pressure. In this work, we…
Tuning of spin-orbit coupling and electron correlation effects in pyrochlore iridates is considered for many interesting phenomena. We have investigated the temperature evolution of structural, magnetic and electronic properties in doped…
We report the X-ray study for the pyrochlore oxide Cd2Re2O7. Two symmetry-lowering structural transitions were observed at Ts1=200K and Ts2=120K. The former is of the second order from the ideal cubic pyrochlore structure with space group…
The electrical resistivity, magnetic susceptibility, and heat capacity of sintered samples of Ca2Ir2O7, in which pentavalent Ir atoms with 5d4 electron configuration form a pyrochlore structure, have been studied. The obtained experimental…
We report the growth of large high quality crystals of the frustrated magnet, Pr2Zr2O7 by the floating zone technique. Several crystals have been produced starting with varying levels of excess of Pr6O11 to compensate for the loss of Pr2O3…
We report structural and magnetic properties studies of large high quality single-crystals of the frustrated magnet, Nd$_2$Zr$_2$O$_7$. Powder x-ray diffraction analysis confirms that Nd$_2$Zr$_2$O$_7$ adopts the pyrochlore structure.…
We examine the resistivity and thermopower of single crystal specimens of the pyrochlore oxide Cd2Re2O7 at pressures up to 2GPa. Thermopower proves to be a sensitive tool in the study of the phase diagram of Cd2Re2O7. The 200K…
Muon spin rotation and relaxation experiments in the pyrochlore iridate Eu2Ir2O7 yield a well-defined muon spin precession frequency below the metal-insulator/antiferromagnetic transition temperature TM = 120 K, indicative of long-range…