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The classical thermostatics of equilibrium processes is shown to possess a quantum-mechanical dual theory with a finite-dimensional Hilbert space of quantum states. Specifically, the kernel of a certain Hamiltonian operator becomes the…

Mathematical Physics · Physics 2017-04-05 D. Cabrera , P. Fernandez de Cordoba , J. M. Isidro , J. Vazquez Molina

In the Schr{\"o}dinger picture, the state of a quantum system evolves in time and the quantum speed limit describes how fast the state of a quantum system evolves from an initial state to a final state. However, in the Heisenberg picture…

Quantum Physics · Physics 2022-12-07 Brij Mohan , Arun Kumar Pati

An observer-based Hamiltonian identification algorithm for quantum systems is proposed. For the 2-level case an exponential convergence result based on averaging arguments and some relevant transformations is provided. The convergence for…

Mathematical Physics · Physics 2007-05-23 Mazyar Mirrahimi , Pierre Rouchon

Traditional measures of entropy, like the Von Neumann entropy, while fundamental in quantum information theory, are insufficient when interpreted as thermodynamic entropy due to their invariance under unitary transformations, which…

Quantum Physics · Physics 2025-05-20 Shivam Sinha , Nripendra Majumbdar , S. Aravinda

The vacuum expectation value of the evolution operator for a general class of Hamiltonians used in quantum field theory and statistical physics and which include unstable particles is considered. An exact formula which describes the large…

High Energy Physics - Theory · Physics 2007-05-23 Dmitrii V. Prokhorenko

A time-dependent product is introduced between the observables of a dissipative quantum system, that accounts for the effects of dissipation on observables and commutators. In the $t \to \infty$ limit this yields a contracted algebra. The…

Quantum Physics · Physics 2012-05-07 Dariusz Chruściński , Paolo Facchi , Giuseppe Marmo , Saverio Pascazio

In this work we study the unitary time-evolutions of quantum systems defined on infinite-dimensional separable time-dependent Hilbert spaces. Two possible cases are considered: a quantum system defined on a stochastic interval and another…

Quantum Physics · Physics 2019-05-22 Luca Curcuraci , Stefano Bacchi , Angelo Bassi

If there exists a classical, i.e. deterministic theory underlying quantum mechanics, an explanation must be found of the fact that the Hamiltonian, which is defined to be the operator that generates evolution in time, is bounded from below.…

Quantum Physics · Physics 2009-11-13 Gerard 't Hooft

We discuss the thermodynamics of closed quantum systems driven out of equilibrium by a change in a control parameter and undergoing a unitary process. We compare the work actually done on the system with the one that would be performed…

Quantum Physics · Physics 2015-01-20 F. Plastina , A. Alecce , T. J. G. Apollaro , G. Falcone , G. Francica , F. Galve , N. Lo Gullo , R. Zambrini

A simple model of quantum particle is proposed in which the particle in a {\it macroscopic} rest frame is represented by a {\it microscopic d}-dimensional oscillator, {\it s=(d-1)/2} being the spin of the particle. The state vectors are…

Quantum Physics · Physics 2007-05-23 Blagowest Nikolov

The meaning of time in an open quantum system is considered under the assumption that both, system and environment, are quantum mechanical objects. The Hamilton operator of the system is non-Hermitian. Its imaginary part is the time…

Quantum Physics · Physics 2012-06-11 Ingrid Rotter

Traditional quantum thermodynamic frameworks associate work to energy exchanges induced by unitary transformations generated by external controls, and heat to energy exchanges induced by bath interaction. Recently, a framework was…

Quantum Physics · Physics 2026-01-06 Tiago F. F. Santos , Camille Latune

The emergence of statistical mechanics from quantum dynamics is a central problem in quantum many-body physics. Deriving observables aligned with the prediction of the canonical ensemble for a quantum system relies on the presence of a bath…

Statistical Mechanics · Physics 2026-01-05 Nikolay V. Gnezdilov , Andrei I. Pavlov

A slight modification of one axiom of quantum theory changes a reversible theory into a time asymmetric theory. Whereas the standard Hilbert space axiom does not distinguish mathematically between the space of states (in-states of…

Quantum Physics · Physics 2014-11-18 A. Bohm , Mark Loewe , Bryan Van de Ven

We investigate the thermodynamic behavior of open quantum systems through the Hamiltonian of Mean Force, focusing on two models: a two-qubit system interacting with a thermal bath and a Jaynes-Cummings Model without the rotating wave…

Quantum Physics · Physics 2025-09-03 Neha Pathania , Devvrat Tiwari , Subhashish Banerjee

The role of time in quantum mechanics is discussed. The differences between ordinary observables and an observable which corresponds to the time of an event is examined. In particular, the time-of-arrival of a particle to a fixed location…

Quantum Physics · Physics 2009-10-31 J. Oppenheim , B. Reznik , W. G. Unruh

We assume that markovian dynamics on a finite graph enjoys a gauge symmetry under local scalings of the probability density, derive the transformation law for the transition rates and interpret the thermodynamic force as a gauge potential.…

Statistical Mechanics · Physics 2015-05-30 Matteo Polettini

Bounds to the speed of evolution of a quantum system are of fundamental interest in quantum metrology, quantum chemical dynamics and quantum computation. We derive a time-energy uncertainty relation for open quantum systems undergoing a…

Quantum Physics · Physics 2013-03-05 A. del Campo , I. L. Egusquiza , M. B. Plenio , S. F. Huelga

In this chapter we offer an introduction to weak values from a three-fold perspective: first, outlining the protocols that enable their experimental determination; next, deriving their correlates in the quantum formalism and, finally,…

Quantum Physics · Physics 2026-02-04 Xabier Oianguren-Asua , Albert Solé , Carlos F. Destefani , Xavier Oriols

We model the dynamics of a closed quantum system brought out of mechanical equilibrium, undergoing a non-driven, spontaneous, thermodynamic transformation. In particular, we consider a quantum particle in a box with a moving and insulating…

Quantum Physics · Physics 2024-02-21 Sofia Sgroi , Mauro Paternostro