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Intermolecular interactions are pivotal for aggregation, solvation, and crystallization. We demonstrate that the collective strong coupling of several molecules to a single optical mode results in notable changes in the molecular…

Quantum Physics · Physics 2024-02-19 Matteo Castagnola , Tor S. Haugland , Enrico Ronca , Henrik Koch , Christian Schäfer

Molecular strong coupling offers exciting prospects in physics, chemistry and materials science. Whilst attention has been focused on developing realistic models for the molecular systems, the important role played by the entire photonic…

Strong coupling exhibits unique ability to preserve quantum sates between light and matter, which is essential for the development of quantum information technology. To explore the physical mechanism behind this phenomenon, we employ the…

Photonic resonances are a powerful tool for controlling light-matter interactions. However, unlocking many of the most scientifically intriguing and technologically promising phenomena requires entering the strong coupling regime, where…

In the last decade, much theoretical research has focused on studying the strong coupling between organic molecules (or quantum emitters, in general) and light modes. The description and prediction of polaritonic phenomena emerging in this…

An optical nanoantenna and adjacent atomic systems are strongly coupled when an excitation is repeatedly exchanged between these subsystems prior to its eventual dissipation into the environment. It remains challenging to reach the strong…

Mesoscale and Nanoscale Physics · Physics 2013-11-15 Karolina Słowik , Robert Filter , Jakob Straubel , Falk Lederer , Carsten Rockstuhl

The notion of strong light-matter coupling is typically associated with the observation of Rabi splitting, corresponding to the formation of the hybrid light-matter states known as polaritons. However, this relationship is derived based on…

Chemical Physics · Physics 2025-12-03 Wei-Kuo Li , Hsing-Ta Chen

Molecular polaritons, hybrid light-matter states formed from the strong coupling of molecular transitions and discrete photonic modes, are a compelling platform for optical control of chemical reactivity. Despite the origins of the field of…

Chemical Physics · Physics 2026-02-11 Jane C. Nelson , Trevor H. Wright , Neo Lin , Madeline Rohde , Marissa L. Weichman

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

The light-matter coupling between electromagnetic modes guided by a semiconductor nanowire and excitonic states of molecules localized in its surrounding media is studied from both classical and quantum perspectives, with the aim of…

We present a new methodology to calculate the strong light-matter coupling between photonic modes in microcavities and large molecular aggregates that consist of hundreds of molecular fragments. To this end, we combine our fragment…

Chemical Physics · Physics 2024-07-30 Richard Einsele , Luca Nils Philipp , Roland Mitrić

Starting from a microscopic model, we investigate the optical spectra of molecules in strongly-coupled organic microcavities examining how they might self-consistently adapt their coupling to light. We consider both rotational and…

Mesoscale and Nanoscale Physics · Physics 2016-03-25 Justyna A. Cwik , Peter Kirton , Simone De Liberato , Jonathan Keeling

Enhancement of light-matter interactions is of great importance for many nanophotonic devices, and one way to achieve it is to feed energy perfectly to the strongly coupled system. Here, we propose gap-perturbed dimerized gratings based on…

Optics · Physics 2023-02-08 Xin Gu , Xing Liu , Xiaofei Yan , Qi Lin , Wenjuan Du , Lingling Wang , Guidong Liu

Optical microcavities and metallic nanostructures have been shown to significantly modulate the dynamics and spectroscopic response of molecular systems. We present a study of the nonlinear optics of a model consisting of $N$ anharmonic…

Strong coupling between cavity photons and molecular vibrations can lead to the formation of vibron-polaritons. In a recent experiment with PVAc molecules in a metal-metal microcavity [A.Shalabney et al., Ang.Chem.Int.Ed. 54 7971 (2015)],…

Optics · Physics 2016-08-31 Artem Strashko , Jonathan Keeling

Exploring the fundamental quantum behaviour of optomechanical resonators is of great interest recently but requires the realization of the strong coupling regime. We study the optical photon-phonon coupling of the so-called membrane in the…

Quantum Physics · Physics 2015-06-23 Keyu Xia , Jason Twamley

We study the strong coupling between the molecular excited state and the plasmonic modes of silver hole arrays with a resonant frequency very close to the asymptotic line of the plasmonic dispersion relation, at the nonlinear regime. We…

Mesoscale and Nanoscale Physics · Physics 2017-01-26 Lihi Efremushkin , Maxim Sukharev , Adi Salomon

A single quantum emitter can possess a very strong intrinsic nonlinearity, but its overall promise for nonlinear effects is hampered by the challenge of efficient coupling to incident photons. Common nonlinear optical materials, on the…

The strong interaction of individual quantum emitters with resonant cavities is of fundamental interest for understanding light matter interactions. Plasmonic cavities hold the promise of attaining the strong coupling regime even under…

Optics · Physics 2016-06-28 Kotni Santhosh , Ora Bitton , Lev Chuntonov , Gilad Haran

Polaritons are compositional light-matter quasiparticles that arise as a result of strong coupling between a vacuum field of a resonant optical cavity and electronic excitations in quantum emitters. Reaching such a regime is often hard, as…