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Solar modules are currently characterized at standard test conditions (STC), defined at 1000W/m2 and 25 {\deg}C. However, solar modules in actual outdoor operating conditions typically operate at lower illumination and higher temperature…

Applied Physics · Physics 2021-07-02 Jean Cattin , Olivier Dupré , Brahim Aïssa , Jan Haschke , Christophe Ballif , Mathieu Boccard

Halide perovskites excel in the pursuit of highly efficient thin film photovoltaics, with power conversion efficiencies reaching 25.5% in single junction and 29.5% in tandem halide perovskite/silicon solar cell configurations. Operational…

The Shockley-Queisser (S-Q) theory defines the thermodynamic upper limits for Jsc, Voc, FF, and efficiency of a solar cell. The classical calculation assumes an abrupt onset of absorption at the band-edge, perfect absorption for all…

General Physics · Physics 2015-07-02 M. Ryyan Khan , Peter Bermel , Muhammad A. Alam

Two-dimensional (2D) layered lead iodide (PbI2) is an important precursor and common residual species during the synthesis of lead-halide perovskites. There currently exist some debates and uncertainties about the effect of excess PbI2 on…

Materials Science · Physics 2022-04-20 Hongfei Chen , Hejin Yan , Yongqing Cai

The honeycomb connection of carbon atoms by covalent bonds in a macroscopic two-dimensional scale leads to fascinating graphene and solar cell based on graphene/silicon Schottky diode has been widely studied. For solar cell applications,…

Mesoscale and Nanoscale Physics · Physics 2015-07-30 Xiaoqiang Li , Shengjiao Zhang , Peng Wang , Huikai Zhong , Zhiqian Wu , Hongshen Chen , Cheng Liu , Shisheng Lin

Modern photovoltaic devices are often based on a heterojunction structure where two components with different optoelectronic properties are interfaced. The properties of each side of the junction can be tuned by either utilizing different…

Polymer solar cells are considered as very promising candidates for development of photovoltaics of the future. They are cheap and easy to fabricate, however, up to now, they possess fundamental drawback, low effectiveness. In the most…

Applied Physics · Physics 2017-09-05 Jacek Wojtkiewicz , Marek Pilch

Theoretically and experimentally we have proved the existence of optimal thickness of the porous layer used as an anti-reflection coating in solar cells. We have taken into account the joint mechanisms of generation and recombination of…

Mesoscale and Nanoscale Physics · Physics 2017-02-17 Zeinulla Zhanabaev , Kadyrzhan Dikhanbayev

Quaternary mixed-metal chalcohalides (Sn$_2$BCh$_2$X$_3$) are emerging as promising lead-free perovskite-inspired photovoltaic absorbers. Motivated by recent developments of a first Sn$_2$BCh$_2$X$_3$-based device, we used density…

Materials Science · Physics 2023-09-28 Pascal Henkel , Jingrui Li , G. Krishnamurthy Grandhi , Paola Vivo , Patrick Rinke

Hybrid halide perovskites are currently under intense investigation due to their potential applications in optoelectronics and solar cells. Among them, MAPbI$_3$ where MA stands for the methylammonium cation, exhibits ideal properties for…

Materials Science · Physics 2017-07-10 A. Koliogiorgos , S. Baskoutas , I. Galanakis

Lead-free all-inorganic halide perovskite solar cells (PSCs) have emerged as a promising alternative to toxic lead-based solar cells and organic solar cells, which have limited stability. This work explores such a PSC with sodium tin…

Materials Science · Physics 2025-03-05 Md Tashfiq Bin Kashem , Sadia Anjum Esha

We introduce a limit for the strength of coupling light into the modes of solar cells. This limit depends on both a cell's thickness and its modal properties. For a cell with refractive index n and thickness d, we obtain a maximal coupling…

Optics · Physics 2013-04-29 A. Naqavi , F. -J. Haug , C. Ballif , T. Scharf , H. P. Herzig

Photon impingement is capable of liberating electrons in semiconductors. When the electron transport is primarily governed by temperature gradients, high irreversibilities will result, thus lowering converters' efficiencies. A fundamental…

Materials Science · Physics 2014-09-12 Shanhe Su , Jincan Chen , Tien-Mo Shih

Cu(In,Ga)Se2 based solar cells exceed power conversion efficiencies of 23 %. Yet, the fill factor of these solar cells, with best values around 80 %, is relatively low (Si reaches 84.9%) mostly due to diode factors greater than one.…

The present article reports a comprehensive energy balance analysis of a photon-enhanced thermionic emission (PETE) device when it is used for concentrated solar power (CSP) generation. To this end, we consider a realistic PETE device…

Applied Physics · Physics 2021-04-06 A. N. M. Taufiq Elahi , Mohammad Ghashami , Devon Jensen , Keunhan Park

Detailed-balance limits for transition-metal dichalcogenide (TMD) solar cells have been reported, but existing TMD-specific limits do not simultaneously resolve thickness-dependent optics, carrier multiplication (CM), hot-carrier (HC)…

Applied Physics · Physics 2026-05-04 Seungwoo Lee

Selenium is experiencing renewed interest as a promising candidate for the wide bandgap photoabsorber in tandem solar cells. However, despite the potential of selenium-based tandems to surpass the theoretical efficiency limit of single…

We conduct a comprehensive assessment of the electronic and optical properties, as well as photovoltaic (PV) performance parameters for Mg$_{2}$Si and Ca$_{2}$Si using density-functional theory and Bethe-Salpeter equation (BSE) based…

Materials Science · Physics 2025-03-04 Vinod Kumar Solet , Sudhir K. Pandey

The decrease of solar cell efficiency with temperature is a known problem for photovoltaics (PV). Temperature sensitivity can lead to a considerable amount of energy losses over the lifetime of solar panels. In this perspective Hybrid…

Applied Physics · Physics 2023-11-01 Bruno Lorenzi , Paolo Mariani , Andrea Reale , Aldo Di Carlo , Gang Chen , Dario Narducci

Antimony sulfide (Sb$_2$S$_3$), a compound of earth-abundant elements with highly anisotropic, quasi-layered crystal structure, triggered growing interest as a solar absorber in photovoltaics and as a phase change material in memory…