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The metal-insulator transition (MIT) in rare-earth nickelates exemplifies the intricate interplay between electronic correlations and lattice dynamics in quantum materials. This work focuses on SmNiO$_3$ as a prototypical system, employing…

Materials Science · Physics 2025-03-12 Guoyong Shi , Fenglin Deng , Ri He , Dachuan Chen , Xuejiao Chen , Peiheng Jiang , Zhicheng Zhong

Photoexcitation has been utilized to control quantum matter and to uncover metastable phases far from equilibrium. Among demonstrations to date, the most common is the photo-induced transition from correlated insulators to metallic states;…

Vanadium dioxide (VO2) is a thermochromic material that undergoes a phase transition from a monoclinic semiconducting state to a rutile metallic state at 68 degrees C, a temperature close to room temperature. This property makes VO2…

Vanadium Dioxide (VO2) is a strongly correlated material, which exhibits insulator to metal transition at ~68 C along with large resistivity and infrared optical reflectance modulation. In this work, we use atmospheric pressure thermal…

Applied Physics · Physics 2021-06-29 Ashok P , Yogesh Singh Chauhan , Amit Verma

We investigated optical absorption coefficient spectra of an epitaxial VO2 film in wide photon energy (0.5 - 5.0 eV) and temperature (100 - 380 K) regions. In its insulating phase, we observed two d-d transition peaks around 1.3 eV and 2.7…

Strongly Correlated Electrons · Physics 2007-05-23 C. H. Koo , J. S. Lee , M. W. Kim , Y. J. Chang , T. W. Noh , J. H. Jung B. G. Chae , H. -T. Kim

VO2 features concomitant structural and metal-insulator transitions. This poses a challenge for understanding the underlying mechanism: is the transition triggered by a structural or by an electronic instability? The two scenarios are…

Recent development of ultrashort laser pulses allows for optical control of structural and electronic properties of complex quantum materials. The layered transition metal dichalcogenide MoTe2, which can crystalize into several different…

Materials Science · Physics 2019-05-29 M. Y. Zhang , Z. X. Wang , Y. N. Li , L. Y. Shi , D. Wu , T. Lin , S. J. Zhang , Y. Q. Liu , C. N. Wang , Q. M. Liu , J. Wang , T. Dong , N. L. Wang

The high-pressure behavior of monoclinic VO$_2$ is revisited by a combination of Raman spectroscopy and X-ray diffraction on a single crystal under hydrostatic conditions at room temperature. A soft mode is observed up to P$_c$ = 13.9(1)…

Strongly Correlated Electrons · Physics 2025-01-14 P. Bouvier , L. Bussmann , D. Machon , I. Breslavetz , G. Garbarino , P. Strobel , V. Dmitriev

Nine of the known vanadium oxides, VO$_{2-1/n}$ (n - a positive or negative integer) with n=2 - 6, 8, 9, $\infty$ and -6, undergo metal-insulator transitions accompanied by structural transitions, at various temperatures T$_{MIT}$…

Strongly Correlated Electrons · Physics 2015-12-09 B. Fisher , J. Genossar , G. M. Reisner

The electronic structure of the vanadium dioxide VO_2 in the tetragonal R and two monocinic M_1 and M_2 structural modifications was calculated in frames of the local-density functional (LDA) approach and the LSDA + U formalism of…

Strongly Correlated Electrons · Physics 2007-05-23 M. A. Korotin , N. A. Skorikov , V. I. Anisimov

Laser-induced phase transitions offer pathways of phase transitions that are inaccessible by conventional stimuli. In this study, we conduct ab initio simulations to numerically demonstrate a novel laser-induced structural transformation:…

Optics · Physics 2025-08-07 Shuang Liu , Oren Cohen , Ofer Neufeld , Peng Chen

Technology moves towards ever faster switching between different electronic and magnetic states of matter. Manipulating properties at terahertz rates requires accessing the intrinsic timescales of electrons (femtoseconds) and associated…

Vanadium oxides are strongly correlated materials which display metal-insulator transitions as well as various structural and magnetic properties that depend heavily on oxygen stoichiometry. Therefore, it is crucial to precisely control…

Materials Science · Physics 2020-12-21 Min-Han Lee , Yoav Kalcheim , Javier del Valle , Ivan K. Schuller

We study the photo-induced metallization process in niobium dioxide NbO$_2$. This compound undergoes the thermal insulator-to-metal transition at the remarkably high temperature of 1080 K. Our optical pump - terahertz probe measurements…

Strongly Correlated Electrons · Physics 2019-01-09 Rakesh Rana , J. Michael Klopf , Jörg Grenzer , Harald Schneider , Manfred Helm , Alexej Pashkin

$VO_2$ undergoes the insulator-metal transition (IMT) and monoclinic-rutile structural phase transition (SPT) near $67^oC$. The IMT switching has many applications. However, there is an unresolved issue whether the IMT is a Mott transition…

Strongly Correlated Electrons · Physics 2021-01-18 Chang-Yong Kim , Tetiana Slusar , Jinchul Cho , Hyun-Tak Kim

Vanadium dioxide ($VO_{2}$) exhibits strong infrared optical switching due to its insulator-metal phase-transition property. However, in the visible wavelengths, it's intrinsic optical switching is quite low. Current research explores…

Applied Physics · Physics 2024-01-09 Shubhangi Saini , Ashok P , Amit Verma

From thermodynamic analysis we demonstrate that during metal-insulator transitions in pure matters, a nonequilibrium homogeneous state may be unstable against charge density modulations with certain wavelengths, and thus evolves to the…

Strongly Correlated Electrons · Physics 2020-11-06 Yin Shi , Long-Qing Chen

Vanadium dioxide is a complex oxide material, which shows large resistivity and optical reflectance change while transitioning from the insulator to metal phase at ~68 {\deg}C. In this work, we use a modified atmospheric thermal oxidation…

Applied Physics · Physics 2021-05-24 P Ashok , Yogesh Singh Chauhan , Amit Verma

Vanadium dioxide (VO$_2$) has received significant interest in the context of nanophotonic metamaterials and memories owing to its reversible insulator-metal transition associated with significant changes in its optical and electronic…

Mesoscale and Nanoscale Physics · Physics 2025-02-25 Peter Kepič , Michal Horák , Jiří Kabát , Vlastimil Křápek , Andrea Konečná , Tomáš Šikola , Filip Ligmajer

We use polarization- and temperature-dependent x-ray absorption spectroscopy, in combination with photoelectron microscopy, x-ray diffraction and electronic transport measurements, to study the driving force behind the insulator-metal…