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We present some novel thermodynamic ideas based on the Maupertuis principle. By considering Hamiltonians written in terms of appropriate action-angle variables we show that thermal states can be characterized by the action variables and by…

Statistical Mechanics · Physics 2008-04-15 V. Garcia-Morales , J. Pellicer , J. A. Manzanares

In the classical irreversible thermodynamics (CIT) framework, the Navier Stokes Fourier (NSF) constitutive equations are obtained so as they satisfy the entropy inequality, by and large assuming that the entropy flux is equal to the heat…

Fluid Dynamics · Physics 2023-02-07 Anirudh Singh Rana , Sukratu Barve

We provide a thermodynamic framework for binary mixtures of Korteweg fluids with two velocities and two temperatures. The constitutive functions are allowed to depend on the diffusion velocity and the specific internal energy of both…

Fluid Dynamics · Physics 2021-09-22 Vito Antonio Cimmelli , Matteo Gorgone , Francesco Oliveri , Angelo Raffaele Pace

In this paper we propose the use of concepts from thermodynamics in the study of crowd dynamics. Our continuous model consists of the continuity equation for the density of the crowd and a kinetic equation for the velocity field. The latter…

Analysis of PDEs · Mathematics 2013-05-15 Joep Evers , Adrian Muntean , Fons van de Ven

A general nonequilibrium thermodynamic theory is developed for time-dependent Langevin dynamics, starting from the common definition of nonequilibrium Gibbs entropy. It is shown that the notations appearing in the First and the Second Law…

Statistical Mechanics · Physics 2009-04-15 Hao Ge

A complete thermodynamical analysis for a blood model, based on mixture theory, is performed. The model is developed considering the blood as a suspension of red blood cells (solid component) in the plasma (fluid component), and taking into…

Fluid Dynamics · Physics 2025-06-03 M. Gorgone , C. F. Munafo' , A. Palumbo , P. Rogolino

We discuss heat conductivity from the point of view of a variational multi-fluid model, treating entropy as a dynamical entity. We demonstrate that a two-fluid model with a massive fluid component and a massless entropy can reproduce a…

Fluid Dynamics · Physics 2011-09-07 N. Andersson , G. L. Comer

We derive two different generalized heat-transport equations: The most general one, of the first order in time and second order in space, encompasses some well known heat equations and describes the hyperbolic regime in the absence of…

Statistical Mechanics · Physics 2019-06-11 Patrizia Rogolino , Róbert Kovács , Péter Ván , Vito Antonio Cimmelli

A complete thermodynamical analysis for a non-reacting binary mixture exhibiting the features of a third grade fluid is analyzed. The constitutive functions are allowed to depend on the mass density of the mixture and the concentration of…

Mathematical Physics · Physics 2023-11-21 Matteo Gorgone , Patrizia Rogolino

We show that for any liquid or solid with strong correlation between its $NVT$ virial and potential-energy equilibrium fluctuations, the temperature is a product of a function of excess entropy per particle and a function of density,…

Soft Condensed Matter · Physics 2012-03-13 Trond S. Ingebrigtsen , Lasse Bøhling , Thomas B. Schrøder , Jeppe C. Dyre

The continuum equations of fluid mechanics are rederived with the intention of keeping certain mechanical and thermodynamic concepts separate. A new "mechanical" mass density is created to be used in computing inertial quantities, whereas…

Fluid Dynamics · Physics 2017-01-25 Melissa Morris

A peculiarity of the hydrodynamic Navier-Stokes equations for a granular gas is the modification of the Fourier law, with the presence of an additional contribution to the heat flux that is proportional to the density gradient.…

Statistical Mechanics · Physics 2015-06-11 J. Javier Brey , M. J. Ruiz-Montero

The constitutive equations for the heat flux and the Navier tensor are established for a high temperature dilute gas in two spatial dimensions. The Chapman-Enskog procedure to first order in the gradients is applied in order to obtain the…

Statistical Mechanics · Physics 2019-09-04 A. L. Garcia-Perciante , A. R. Méndez

We formulate a geometric framework in which physical laws emerge from restricted access to microscopic information. Measurement constraints are modeled as a gauge symmetry acting on density operators, inducing a gauge-reduced space of…

Quantum Physics · Physics 2026-05-19 Tiago Pernambuco , Lucas Chibebe Céleri

Irreversible processes play a major role in the description and prediction of atmospheric dynamics. In this paper, we present a variational derivation of the evolution equations for a moist atmosphere with rain process and subject to the…

Mathematical Physics · Physics 2018-04-27 François Gay-Balmaz

Deriving the laws of thermodynamics from a microscopic picture is a central quest of statistical mechanics. This tutorial focuses on the derivation of the first and second law for closed and open quantum systems far from equilibrium, where…

Quantum Physics · Physics 2021-08-31 Philipp Strasberg , Andreas Winter

The second law of thermodynamics is a useful and universal tool to derive the generalizations of the Fourier's law. In many cases, only linear relations are considered between the thermodynamic fluxes and forces, i.e., the conduction…

Statistical Mechanics · Physics 2019-12-25 Róbert Kovács , Patrizia Rogolino

In this paper, heat and Carnot's working substance are defined respectively by the equations $E=3pV$ and $E=3/2pV$, relating the energy $E$, the pressure $p$ and the volume $V$ of these two corpuscular systems. The thermodynamic-kinetic…

Chemical Physics · Physics 2019-10-08 Claudio Zamitti Mammana

Second law of thermodynamics imposes that in any thermodynamic process the entropy production must be nonnegative. In continuum physics such a requirement is fulfilled by postulating the constitutive equations which represent the material…

Mathematical Physics · Physics 2022-02-03 V. A. Cimmelli , P. Rogolino

A thermodynamic framework that predicts the thermal conductivity $\lambda$ of simple fluids beyond the dilute-gas limit is introduced. By generalizing the transition-rate approach of particles on a lattice to conserved quantities in…

Statistical Mechanics · Physics 2025-12-03 Miguel Hoyuelos