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This chapter starts with a summary of the atomistic processes that occur during epitaxy. We then introduce density functional theory (DFT) and describe its implementation into state-of-the-art computations of complex processes in condensed…

Condensed Matter · Physics 2009-09-25 P. Ruggerone , C. Ratsch , M. Scheffler

We introduce a homogenization approach to characterize the dynamical response of a generic dispersive spacetime crystal in the long-wavelength limit. The theory is applied to dispersive spacetime platforms with a travelling-wave modulation.…

Optics · Physics 2023-07-26 João C. Serra , Mário G. Silveirinha

Non-adiabatic effects arising from electron-phonon interactions are often neglected within the Born-Oppenheimer (BO) approximation, which assumes that electronic states adjust instantaneously to nuclear motion. The exact factorization (EF)…

We present a formulation of third-order density-functional perturbation theory which is manifestly invariant with respect to unitary transfomations within the occupied-states manifold and is particularly suitable for a practical…

Condensed Matter · Physics 2009-10-22 Alberto Debernardi , Stefano Baroni

Fractional occupation numbers can be used in density functional theory to create a symmetric Kohn-Sham potential, resulting in orbitals with degenerate eigenvalues. We develop the corresponding perturbation theory and apply it to a system…

Materials Science · Physics 2016-09-09 Mark C. Palenik , Brett I. Dunlap

Phonons are quantized vibrations of a crystal lattice that play a crucial role in understanding many properties of solids. Density functional theory (DFT) provides a state-of-the-art computational approach to lattice vibrations from…

Diffusion of electrons in two-dimensional disordered systems with spin-orbit interactions is investigated numerically. Asymptotic behaviors of the second moment of the wave packet and of the temporal auto-correlation function are examined.…

Condensed Matter · Physics 2009-10-28 Tohru Kawarabayashi , Tomi Ohtsuki

Two-dimensional mixtures of dipolar colloidal particles with different dipole moments exhibit extremely rich self-assembly behaviour and are relevant to a wide range of experimental systems, including charged and super-paramagnetic colloids…

Soft Condensed Matter · Physics 2019-04-16 W. R. C. Somerville , J. L. Stokes , A. M. Adawi , T. S. Horozov , A. J. Archer , D. M. A. Buzza

The thorough treatment of electron-lattice interactions from first principles is one of the main goals in condensed matter physics. While the commonly applied adiabatic Born-Oppenheimer approximation is sufficient for describing many…

The effective response depends sensitively on composite microstructure due to large fluctuations in the local electric field. For metallic clusters embedded in a dielectric host, the local field distributions are extremely inhomogeneous in…

Soft Condensed Matter · Physics 2007-05-23 Ying Gu , K. W. Yu , Hong Sun

Anharmonic effects in an atomic monolayer thin crystal with honeycomb lattice structure are investigated by analytical and numerical lattice dynamical methods. Starting from a semi-empirical model for anharmonic couplings of third and…

Materials Science · Physics 2015-05-20 K. H. Michel , S. Costamagna , F. M. Peeters

This paper gives a summary of basic concepts of density-functional theory (DFT) and its use in state-of-the-art computations of complex processes in condensed matter physics and materials science. In particular we discuss how microscopic…

Materials Science · Physics 2008-02-03 C. Ratsch , P. Ruggerone , M. Scheffler

We investigate an extension of excited state mean-field theory in which the energy expression is augmented with density functional components in an effort to include the effects of weak electron correlations. The approach remains…

Chemical Physics · Physics 2020-02-05 Luning Zhao , Eric Neuscamman

We review the progress that has been recently made in the application of time-dependent density functional theory to thermoelectric phenomena. As the field is very young, we emphasize open problems and fundamental issues. We begin by…

Mesoscale and Nanoscale Physics · Physics 2017-04-26 F. G. Eich , M. Di Ventra , G. Vignale

In the current density functional theory of linear and nonlinear time-dependent phenomena, the treatment of exchange and correlation beyond the level of the adiabatic local density approximation is shown to lead to the appearance of…

Condensed Matter · Physics 2009-10-30 G. Vignale , C. A. Ullrich , S. Conti

We introduced a new electron density n({\epsilon}) by projecting the spatial electron density n(r) onto the energy coordinate {\epsilon} defined with the external potential \upsion (r) of interest. Then, a density functional theory (DFT)…

Chemical Physics · Physics 2018-02-20 Hideaki Takahashi

We develop a formalism for the calculation of the macroscopic dielectric response of composite systems made of particles of one material embedded periodically within a matrix of another material, each of which is characterized by a well…

We propose a way to improve energy density functionals (EDFs) in the density functional theory based on the combination of the inverse Kohn--Sham method and the density functional perturbation theory. Difference between the known EDF and…

Chemical Physics · Physics 2019-11-22 Tomoya Naito , Daisuke Ohashi , Haozhao Liang

A first principles density functional based linear response theory (the so called Density Functional Perturbation theory \cite{dfpt}) has been combined separately with two recently developed formalism for a systematic study of the lattice…

Materials Science · Physics 2013-12-25 Aftab Alam , Subhradip Ghosh , Abhijit Mookerjee

The repulsion between free electrons inside a metal makes its optical response spatially dispersive, so that it is not described by Drude's model but by a hydrodynamic model. We give here fully analytic results for a metallic slab in this…

Optics · Physics 2017-07-26 Armel Pitelet , Emilien Mallet , Emmanuel Centeno , Antoine Moreau