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A new weak Galerkin (WG) finite element method is introduced and analyzed in this paper for the biharmonic equation in its primary form. This method is highly robust and flexible in the element construction by using discontinuous piecewise…

Numerical Analysis · Mathematics 2013-03-06 Lin Mu , Junping Wang , Xiu Ye

The second-order Green's function method (GF2) was shown recently to be an accurate self-consistent approach for electronic structure of correlated systems since the self-energy accounts for both the weak and some of the strong correlation.…

Chemical Physics · Physics 2016-03-31 Daniel Neuhauser , Roi Baer , Dominika Zgid

Within the framework of the full potential projector-augmented wave methodology, we present a promising low-scaling $GW$ implementation. It allows for quasiparticle calculations with a scaling that is cubic in the system size and linear in…

Materials Science · Physics 2016-10-12 Peitao Liu , Merzuk Kaltak , Jiří Klimeš , Georg Kresse

We construct a new phase-field model for the solvation of charged molecules with a variational implicit solvent. Our phase-field free-energy functional includes the surface energy, solute-solvent van der Waals dispersion energy, and…

Numerical Analysis · Mathematics 2017-12-07 Yanxiang Zhao , Yanping Ma , Hui Sun , Bo Li , Qiang Du

We demonstrate the feasibility of the time-linear scaling formulation of the $GW$ method [Phys. Rev. Lett. {\bf 124}, 076601 (2020)] for {\it ab initio} simulations of optically driven two-dimensional materials. The time-dependent $GW$…

Mesoscale and Nanoscale Physics · Physics 2022-01-19 E. Perfetto , Y. Pavlyukh , G. Stefanucci

Machine learning applications in the chemical sciences, especially when based on neural networks, critically depend on the availability of large quantities of high quality data. As they provide excellent accuracy for both charged and…

Chemical Physics · Physics 2025-12-12 Dario Baum , Arno Förster , Lucas Visscher

Near-term quantum computers are expected to facilitate material and chemical research through accurate molecular simulations. Several developments have already shown that accurate ground-state energies for small molecules can be evaluated…

The accuracy of the many-body perturbation theory GW formalism to calculate electron-phonon coupling matrix elements has been recently demonstrated in the case of a few important systems. However, the related computational costs are high…

Computational Physics · Physics 2015-06-23 C. Faber , P. Boulanger , C. Attaccalite , E. Cannuccia , I. Duchemin , T. Deutsch , X. Blase

The electronic structure of the zincblende $\beta$-HgS is not well understood. Previous first-principles calculations using fully-relativistic density functional theory and many-body perturbation theory in the fully-relativistic $GW$…

Materials Science · Physics 2022-03-31 Bradford A. Barker , Steven G. Louie

The self-consistent GW{\Gamma} method satisfies the Ward-Takahashi identity (i.e., the gauge invariance or the local charge continuity) for arbitrary energy ($\omega$) and momentum ($\bf q$) transfers. Its self-consistent first-principles…

Other Condensed Matter · Physics 2016-10-12 Riichi Kuwahara , Yoshifumi Noguchi , Kaoru Ohno

We have developed a multi-GPU version of the quasiparticle self-consistent $GW$ (QSGW), a cutting-edge method for describing electronic excitations in a first-principles approach. While the QSGW calculation algorithm is inherently…

Computational Physics · Physics 2025-06-05 Masao Obata , Takao Kotani , Tatsuki Oda

The formulation of vertex corrections beyond the $GW$ approximation within the framework of perturbation theory is a subtle and challenging task, which accounts for the wide variety of schemes proposed over the years. Exact self-energies…

Chemical Physics · Physics 2025-07-18 Fabien Bruneval , Arno Förster , Yaroslav Pavlyukh

The drastically expanded use of the Woods-Saxon potential in modern day nuclear physics and the availability of new nuclear data motivated us to review and optimize the parameters of this potential to the experimental single-nucleon spectra…

Nuclear Theory · Physics 2007-09-25 N. Schwierz , I. Wiedenhover , A. Volya

The development of a novel exact two-component (X2C) scheme with the inclusion of the picture-change correction for the fluctuation potential, the X2Ccorr scheme, is reported, hereby establishing a hierarchy of X2C schemes with systematic…

Chemical Physics · Physics 2026-03-02 Xubo Wang , Sen Wang , Yixuan Wu , Lan Cheng

We present an approach for GW calculations of quasiparticle energies with quasi-quadratic scaling by approximating high-energy contributions to the Green's function in its Lehmann representation with effective stochastic vectors. The method…

Materials Science · Physics 2023-12-07 Aaron R. Altman , Sudipta Kundu , Felipe H. da Jornada

We present two new developments for computing excited state energies within the $GW$ approximation. First, calculations of the Green's function and the screened Coulomb interaction are decomposed into two parts: one is deterministic while…

Computational Physics · Physics 2020-10-28 Mariya Romanova , Vojtěch Vlček

On the basis of the self-consistent calculation scheme for the electron self-energy with the use of the three-point vertex function always satisfying the Ward identity, we find that the obtained quasiparticle dispersion in the normal state…

Superconductivity · Physics 2016-01-12 Yasutami Takada

The shifted Tietz-Wei (sTW) oscillator is as good as traditional Morse potential in simulating the atomic interaction in diatomic molecules. By using the Pekeris-type approximation to deal with the centrifugal term, we obtain the…

Chemical Physics · Physics 2015-04-22 Babatunde J. Falaye , Sameer M. Ikhdair , Majid Hamzavi

Finding an accurate ab initio approach for calculating the electronic properties of transition metal oxides has been a problem for several decades. In this paper, we investigate the electronic structure of the transition metal monoxides…

Strongly Correlated Electrons · Physics 2015-06-23 Suvadip Das , John E. Coulter , Efstratios Manousakis

Ab initio many-body perturbation theory within the $GW$ approximation is a Green's function formalism widely used in the calculation of quasiparticle excitation energies of solids. In what has become an increasingly standard approach,…