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The accuracy at which total energies of open-shell atoms and organic radicals may be calculated is assessed for selected coupled cluster perturbative triples expansions, all of which augment the coupled cluster singles and doubles (CCSD)…

Chemical Physics · Physics 2016-05-17 Janus Juul Eriksen , Devin A. Matthews , Poul Jørgensen , Jürgen Gauss

We reveal limitations of several standard coupled-cluster (CC) methods with perturbation-theorybased noniterative or approximate iterative treatments of triple excitations when applied to thedetermination of highly accurate potential energy…

Chemical Physics · Physics 2021-10-04 Jan Schnabel , Lan Cheng , Andreas Köhn

In order to explore the effects of high levels of electron correlation on the real-time coupled cluster formalism and algorithmic behavior, we introduce a time-dependent implementation of the CC3 singles, doubles and approximate triples…

Chemical Physics · Physics 2025-01-23 Zhe Wang , Håkon Emil Kristiansen , Thomas Bondo Pedersen , T. Daniel Crawford

We propose a scheme to generate cluster states of atomic qubits by using cavity quantum electrodynamics (QED) and linear optics, in which each atom is confined in a resonant optical cavity with two orthogonally polarized modes. Our scheme…

Quantum Physics · Physics 2007-05-23 X. L. Zhang , K. L. Gao , M. Feng

The expansion of laser-irradiated clusters or nanodroplets depends strongly on the amount of energy delivered to the electrons and can be controlled by using appropriately shaped laser pulses. In this paper, a self-consistent kinetic model…

Plasma Physics · Physics 2009-11-13 F. Peano , J. L. Martins , R. A. Fonseca , F. Peinetti , R. Mulas , G. Coppa , I. Last , J. Jortner , L. O. Silva

We propose two schemes for the generation of the cluster states. One is based on cavity quantum electrodynamics (QED) techniques. The scheme only requires resonant interactions between two atoms and a single-mode cavity. The interaction…

Quantum Physics · Physics 2009-11-11 Ping Dong , Zheng-Yuan Xue , Ming Yang , Zhuo-Liang Cao

The Coupled-Cluster theory is one of the most successful high precision methods used to solve the stationary Schr\"odinger equation. In this article, we address the mathematical foundation of this theory with focus on the advances made in…

Chemical Physics · Physics 2019-09-04 Andre Laestadius , Fabian M. Faulstich

The many-body Coulomb repulsive energy of strictly correlated electrons provides direct information of the exact Hohenberg-Kohn exchange-correlation functional in the strong interaction limit. Until now the treatment of strictly correlated…

Chemical Physics · Physics 2013-03-13 Christian B. Mendl , Lin Lin

We present a diagrammatic notation to derive the quantum-electrodynamic coupled cluster (QED-CC) equations needed for the description for polaritonic ground and excited states. Our presented notation is a generalization of the existing…

Chemical Physics · Physics 2024-07-02 Laurenz Monzel , Stella Stopkowicz

The relativistic Hartree-Fock and electron correlation methods without the negative-energy orbital problem are examined on the basis of the quantum electrodynamics (QED) Hamiltonian. First, several QED Hamiltonians previously proposed are…

Chemical Physics · Physics 2023-01-02 Nobuki Inoue , Yoshihiro Watanabe , Haruyuki Nakano

The exploration of the root structure of coupled cluster equations holds both foundational and practical significance for computational quantum chemistry. This study provides insight into the intricate root structures of these non-linear…

Chemical Physics · Physics 2024-09-12 Svala Sverrisdóttir , Fabian M. Faulstich

The ability to achieve ultra-strong coupling between light and matter promises to bring about new means to control material properties, new concepts for manipulating light at the atomic scale, and fundamentally new insights into quantum…

Quantum Physics · Physics 2019-05-22 Nicholas Rivera , Johannes Flick , Prineha Narang

A mobile Coulomb gas permeating a fixed background crystalline lattice of charged colloidal crystals is subject to an electrostatic-elastic coupling, which we study on the continuum level by introducing a minimal coupling between…

Soft Condensed Matter · Physics 2025-02-14 Hao Wu , Zhong-Can Ou-Yang , Rudolf Podgornik

We analyzed the dynamics of the initial singlet electronic state in the two interacting single-level quantum dots (QDs) with Coulomb correlations, weakly tunnel coupled to an electronic reservoir. We obtained correlation functions of all…

Mesoscale and Nanoscale Physics · Physics 2015-02-12 N. S. Maslova , V. N. Mantsevich , P. I. Arseyev

We present an excited-state-specific coupled-cluster approach in which both the molecular orbitals and cluster amplitudes are optimized for an individual excited state. The theory is formulated via a pseudoprojection of the traditional…

Chemical Physics · Physics 2023-11-27 Harrison Tuckman , Eric Neuscamman

The recently introduced coupled cluster (CC) downfolding techniques for reducing the dimensionality of quantum many-body problems recast the CC formalism in the form of the renormalization procedure allowing, for the construction of…

Quantum Physics · Physics 2021-11-08 Nicholas P. Bauman , Karol Kowalski

The coupled cluster method (CCM) is a method of quantum many-body theory that may provide accurate results for the ground-state properties of lattice quantum spin systems even in the presence of strong frustration and for lattices of…

Strongly Correlated Electrons · Physics 2009-11-11 D. J. J. Farnell , J. Schulenburg , J. Richter , K. A. Gernoth

Highly accurate methods such as coupled cluster (CC) techniques can be used for periodic systems within the framework of the method of increments. Its extension to low-dimensional conducting system is considered. To demonstrate the…

Materials Science · Physics 2012-01-31 Elena Voloshina

We analyzed the localized charge dynamics in the system of $N$ interacting single-level quantum dots (QDs) coupled to the continuous spectrum states in the presence of Coulomb interaction between electrons within the dots. Different dots…

Mesoscale and Nanoscale Physics · Physics 2013-07-09 Vladimir Mantsevich , Natalya Maslova , Petr Arseyev

The multipolar Hamiltonian of quantum electrodynamics (QED) is extensively employed in chemical and optical physics to treat rigorously the interaction of electromagnetic fields with matter. It is also widely used to evaluate intermolecular…

Quantum Physics · Physics 2018-01-25 David L. Andrews , Garth A. Jones , A Salam , R. Guy Woolley
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