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Related papers: Electron-vacancy scattering in SrNbO$_3$ and SrTiO…

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We investigate the behavior of oxygen vacancies in three different metal-oxide semiconductors (rutile and anatase TiO2, monoclinic WO3, and tetragonal ZrO2) using a recently proposed hybrid density-functional method in which the fraction of…

We present a study of delta ($\delta$) doping at LaTiO$_3$/SrTiO$_3$ (LTO/STO) interface with iso-structural antiferromagnetic perovskite LaCrO$_3$ (LCO) that dramatically alters the properties of the two dimensional electron gas (2-DEG) at…

Strongly Correlated Electrons · Physics 2015-06-03 Shubhankar Das , A. Rastogi , Lijun Wu , Jin-Cheng Zheng , Z. Hossain , Yimei Zhu , R. C. Budhani

We report a magnetotransport study of spin relaxation in 1.4-21.2 nm epitaxial SrIrO$_3$ thin films coherently strained on SrTiO$_3$ substrates. Fully charge compensated semimetallic transport has been observed in SrIrO$_3$ films thicker…

Strongly Correlated Electrons · Physics 2020-06-16 L. Zhang , X. Jiang , X. Xu , X. Hong

Oxygen-deficient TiO$_2$ in the rutile structure as well as the Ti$_3$O$_5$ Magn{\'e}li phase is investigated within the charge self-consistent combination of density functional theory (DFT) with dynamical mean-field theory (DMFT). It is…

Materials Science · Physics 2017-06-07 Frank Lechermann , Wolfgang Heckel , Oleg Kristanovski , Stefan Müller

In this article, density functional theory (DFT) and natural bond orbital (NBO) calculations are performed to understand experimental observations of dissociative electron attachment (DEA) to SO$_2$. The molecular structure, fundamental…

Atomic and Molecular Clusters · Physics 2018-07-09 Irina Jana , Sumit Naskar , Mousumi Das , Dhananjay Nandi

We use density functional theory (DFT) calculations to show that oxygen vacancies ($v_\mathrm{O}$) and mobility induce noncentrosymmetric polar structures in SrTi$_{1-x-y}$Fe$_{x}$Co$_{y}$O$_{3-\delta}$ ($x=y=0.125$) with $\delta = \{0.125,…

Materials Science · Physics 2022-11-02 Emilio A. Cortes , Shyue Ping Ong , C. A. Ross , Juan M. Florez

The existence of band gaps in Mott insulators such as perovskite oxides with partially filled 3d shells has been traditionally explained in terms of strong, dynamic inter-electronic repulsion codified by the on-site repulsion energy U in…

Materials Science · Physics 2019-07-24 Julien Varignon , Manuel Bibes , Alex Zunger

In this paper we study, both with theoretical and experimental approach, the effect of iron doping in zirconia. Combining density functional theory (DFT) simulations with the experimental characterization of thin films, we show that iron is…

We investigate effects of doping on formation energy and concentration of oxygen vacancies at a metal oxide surface, using MgO (100) as an example. Our approach employs density-functional theory, where the performance of the…

Materials Science · Physics 2013-05-24 Norina A. Richter , Sabrina Sicolo , Sergey V. Levchenko , Joachim Sauer , Matthias Scheffler

The neutron powder diffraction, specific heat, thermal conductivity, and Raman scattering measurements were presented to study the interplays of lattice, phonons and electrons of the Sr-doping Ba1-xSrxSnO3 (x was less than or equal to 0.1).…

Oxygen vacancies in strontium titanate surfaces (SrTiO3) have been linked to the presence of a two-dimensional electron gas with unique behavior. We perform a detailed density functional theory study of the lattice and electronic structure…

Strongly Correlated Electrons · Physics 2015-06-22 Harald O. Jeschke , Juan Shen , Roser Valenti

Distortions of the oxygen octahedra influence the fundamental electronic structure of perovskite oxides, such as their bandwidth and exchange interactions. Utilizing a fully ab-initio methodology based on density functional theory plus…

Strongly Correlated Electrons · Physics 2021-07-02 Alexander Hampel , Jeremy Lee-Hand , Antoine Georges , Cyrus E. Dreyer

We investigate the electronic structure of the epitaxial VO$_2$ films in the rutile phase using the density functional theory combined with the slave spin method (DFT+SS). In DFT-SS, the multiorbital Hubbard interactions are added to a…

The addition of electron donors to the vacant A site of defect-perovskite structure tungsten trioxide causes a series of structural and chemical phase transitions; for instance, in the well-known case of the sodium tungsten bronzes…

Materials Science · Physics 2009-11-10 Andrew D. Walkingshaw , Nicola A. Spaldin , Emilio Artacho

We present a theoretical study of the effect of electron-electron interactions and Sr doping on the electronic structure of infinite-layer (Nd,Sr)NiO$_2$ using the density functional+dynamical mean-field theory approach. In particular, we…

Strongly Correlated Electrons · Physics 2022-09-16 I. Leonov , S. Y. Savrasov

In a common paradigm, the electronic structure of condensed matter is divided into weakly and strongly correlated compounds. While conventional band theory usually works well for the former class, many-body effects are essential for the…

Materials Science · Physics 2016-03-17 Frank Lechermann , Harald O. Jeschke , Aaram J. Kim , Steffen Backes , Roser Valenti

Using \emph{ab initio} band structure and DFT+dynamical mean-field theory methods we examine the effects of electron-electron interactions on the electronic structure, magnetic state, and structural phase stability of the recently…

Strongly Correlated Electrons · Physics 2026-01-26 I. V. Leonov

Hybrid functionals and empirical correction schemes are compared to conventional semi-local density functional theory (DFT) calculations in order to assess the predictive power of these methods concerning the formation energy and the charge…

Materials Science · Physics 2013-07-02 Sung Sakong , Johann Gutjahr , Peter Kratzer

We investigate the effect of oxygen vacancies and hydrogen dopants at the surface and inside slabs of LaAlO3, SrTiO3, and LaAlO3/SrTiO3 heterostructures on the electronic properties by means of electronic structure calculations as based on…

Strongly Correlated Electrons · Physics 2019-05-03 I. I. Piyanzina , V. Eyert , Yu. V. Lysogorskiy , D. A. Tayurskii , T. Kopp

Point defect engineering is widely used to tailor the electronic and transport properties of complex oxides, yet its influence on dislocation plasticity remains poorly understood. Here, we establish how donor (Nb) doping modifies…