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We investigate the influence of vibrational screening on the excitonic and optical properties of solids based on first-principles electronic-structure calculations. We solve the Bethe-Salpeter equation - the state-of-the-art description of…

Materials Science · Physics 2024-09-24 Maximilian Schebek , Pasquale Pavone , Claudia Draxl , Fabio Caruso

Excitons dominate the optical response of two-dimensional (2D) semiconductors. Strong interactions produce peculiar excitonic complexes, which provide a testing ground for exciton and quantum many-body theories. Here, we report a hitherto…

Excitons, Coulomb-bound electron-hole pairs, are the fundamental excitations governing the optoelectronic properties of semiconductors. While optical signatures of excitons have been studied extensively, experimental access to the excitonic…

We study the coherent light-matter interactions of GaAs quantum wells associated with excitons, biexcitons and many-body effects. For most polarization configurations, excitonic features dominate the phase-resolved two-dimensional…

Other Condensed Matter · Physics 2011-12-13 Alan D. Bristow , Denis Karaiskaj , Xingcan Dai , Richard. P. Mirin , Steven T. Cundiff

Nonlinear spectroscopic techniques using entangled photon pairs can provide an opportunity to exploit non-classical correlations encoded in two-photon wavefunctions to manipulate two-exciton wavefunctions. We propose an entangled photon…

Quantum Physics · Physics 2026-04-10 Arunangshu Debnath , Shaul Mukamel

Excitons are key quasiparticles determining the optical properties of solids. As such, they can be utilized to coherently control the electronic structure of materials using optical femtosecond pulses. Identifying the decoherence mechanism…

In high-performance solar cells based on polymeric semiconductors, the mechanism of photocarrier generation on $<100$-fs timescales is yet to be unravelled. In particular the dynamics of early-time electronic coupling between excitons on…

An emergent quantized field enriches quantum many-body systems. We propose an antiparticle analog of the exciton in semimetals as an emergent collective mode in interacting electron systems. We show that inter-band excitations in semimetals…

Mesoscale and Nanoscale Physics · Physics 2022-12-26 Lingxian Kong , Ryuichi Shindou , Yeyang Zhang

Presence of bound pairs (excitons) in a low-temperature electron-hole plasma is accounted for by including correlation between fermions at the ladder level. Using a simplified one-dimensional model with on-site Coulomb interaction, we…

Mesoscale and Nanoscale Physics · Physics 2009-10-31 C. Piermarocchi , F. Tassone

An exciton theory for quasi-one dimensional organic materials is developed in the framework of the Su-Schrieffer-Heeger Hamiltonian augmented by short range extended Hubbard interactions. Within a strong electron-electron correlation…

Soft Condensed Matter · Physics 2009-10-30 Z. G. Yu , A. Saxena , A. R. Bishop

The elementary optical excitations of a two-dimensional electron or hole system have been identified as exciton-Fermi-polarons. Nevertheless, the connection between the bound state of an exciton and an electron, termed trion, and…

Mesoscale and Nanoscale Physics · Physics 2020-06-30 Atac Imamoglu , Ovidiu Cotlet , Richard Schmidt

The transmission of light through an ensemble of two-level emitters in a one-dimensional geometry is commonly described by one of two emblematic models of quantum electrodynamics (QED): the driven-dissipative Dicke model or the…

Quantum Physics · Physics 2025-11-05 Kasper J. Kusmierek , Max Schemmer , Sahand Mahmoodian , Klemens Hammerer

Optical measurements and first-principles calculations of the band structure and exciton states in direct-gap bulk and few-layer PbI2 indicate that the n = 1 exciton is Frenkel-like in nature in that its energy exhibits a weak dependence on…

Mesoscale and Nanoscale Physics · Physics 2015-05-20 Alexis S. Toulouse , Benjamin P. Isaacoff , Guangsha Shi , Marie Matuchová , Emmanouil Kioupakis , Roberto Merlin

Excitons, electron-hole pairs bound by the Coulomb potential, are fundamental quasiparticles of coherent light-matter interaction energizing processes from photosynthesis to optoelectronics. Excitons are observed in semiconductors, and…

Mesoscale and Nanoscale Physics · Physics 2015-06-19 Xuefeng Cui , Cong Wang , Adam Argondizzo , Sean Garrett-Roe , Branko Gumhalter , Hrvoje Petek

The Frenkel exciton model was adapted to describe X-ray absorption and resonant inelastic scattering spectra of polynuclear transition metal complexes by means of restricted active space self-consistent field method. The proposed approach…

Chemical Physics · Physics 2016-06-07 Marie Preuße , Sergey I. Bokarev , Saadullah G. Aziz , Oliver Kühn

Component of photoexcited states with large spatial extent is investigated for optical absorption spectra of the electroluminescent conjugated polymers by using the intermediate exciton theory. We calculate the ratio of oscillator strengths…

Soft Condensed Matter · Physics 2008-02-03 Kikuo Harigaya

This is a review of exciton dynamics in conjugated polymers. Exciton dynamics encompass multiple time and length scales. Ultrafast femtosecond processes are intrachain and involve a quantum mechanical correlation of the exciton and nuclear…

Chemical Physics · Physics 2021-02-15 William Barford

We investigate the effects of disorder on Frenkel excitons in disordered conjugated polymers with allowed rotations about single bonds. In these materials, the principal effect of the disorder is to modify the transfer integrals appearing…

Disordered Systems and Neural Networks · Physics 2007-05-23 I. Avgin , D. L. Huber

The Photoluminescent (PL) measurements on photons and the transport measurements on excitons are the two types of independent and complementary detection tools to search for possible exciton superfluids in electron-hole semi-conductor…

Strongly Correlated Electrons · Physics 2013-01-16 Jinwu Ye , Fadi Sun , Yi-Xiang Yu , Wuming Liu

We quantify the excitonic coupling in the homodimer of dimeric Venus fluorescent protein using a quantum-classical hybrid workflow. Employing a transition-density coupling formalism, we calculate $J = 74.38~\mathrm{cm^{-1}}$, which is 5.6…

Chemical Physics · Physics 2026-05-04 Robson Christie , Cerys Murray , Youngchan Kim , Jaewoo Joo