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We investigate a cavity quantum electrodynamic effect, where the alignment of two-dimensional freely rotating optical dipoles is driven by their collective coupling to the cavity field. By exploiting the formal equivalence of a set of…

Quantum Physics · Physics 2017-08-02 Erika Cortese , Pavlos Lagoudakis , Simone De Liberato

As pioneering experiments have shown, strong vibrational coupling between molecular vibrations and light modes in an optical cavity can significantly alter molecular properties and even affect chemical reactivity. However, the current…

Chemical Physics · Physics 2024-07-26 Thomas Schnappinger , Markus Kowalewski

We investigate Jahn-Teller (JT) polaritons, which emerge from the interaction of the two normal-incidence electromagnetic modes with perpendicular polarizations in a Fabry-Perot cavity resonator with JT active systems. These JT polaritons…

Chemical Physics · Physics 2023-06-21 Krishna Nandipati , Oriol Vendrell

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

Strong coupling between cavity photons and molecular vibrations can lead to the formation of vibron-polaritons. In a recent experiment with PVAc molecules in a metal-metal microcavity [A.Shalabney et al., Ang.Chem.Int.Ed. 54 7971 (2015)],…

Optics · Physics 2016-08-31 Artem Strashko , Jonathan Keeling

The experimental observation of quantum phenomena in strongly correlated many particle systems is difficult because of the short length- and timescales involved. Obtaining at the same time detailed control of individual constituents appears…

Quantum Physics · Physics 2007-05-23 Michael J. Hartmann , Fernando G. S. L. Brandao , Martin B. Plenio

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…

Chemical Physics · Physics 2021-03-17 Tor S. Haugland , Christian Schäfer , Enrico Ronca , Angel Rubio , Henrik Koch

Cavity quantum electrodynamics advances the coherent control of a single quantum emitter with a quantized radiation field mode, typically piecewise engineered for the highest finesse and confinement in the cavity field. This enables the…

Under vibrational strong coupling (VSC), the formation of molecular polaritons may significantly modify the photo-induced or thermal properties of molecules. In an effort to understand these intriguing modifications, both experimental and…

Chemical Physics · Physics 2022-04-07 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

We report on polariton condensation in photonic molecules formed by two coupled micropillars. We show that the condensation process is strongly affected by the interaction with the cloud of uncondensed excitons. Depending on the spatial…

Polaritons, formed as a result of strong hybridization of matter with light, are promising for important applications including organic solar cells, optical logic gates, and qubits. Owing to large binding energies of Frenkel excitons…

We present a microscopic theory for nonlinear optical spectroscopy of N molecules in an optical cavity. A quantum Langevin analytical expression is derived for the time- and frequency-resolved signals accounting for arbitrary numbers of…

Quantum Physics · Physics 2023-03-29 Zhedong Zhang , Xiaoyu Nie , Dangyuan Lei , Shaul Mukame

Linear spectra of molecular polaritons formed by $N$ molecules coupled to a microcavity photon mode are usually well described by classical linear optics, raising the question of where the expected nonlinear effects in these strongly…

Quantum Physics · Physics 2024-11-19 Arghadip Koner , Joel Yuen-Zhou

A quantum system composed of a molecule and an atomic ensemble, confined in a microscopic cavity, is investigated theoretically. The indirect coupling between atoms and the molecule, realized by their interaction with the cavity radiation…

Chemical Physics · Physics 2020-05-05 Tamás Szidarovszky , Gábor J. Halász , Ágnes Vibók

Molecular polaritons have become an emerging platform for remotely controlling molecular properties through strong light-matter interactions. Herein, a semiclassical approach is developed for describing molecular polaritons by…

Chemical Physics · Physics 2022-04-19 Tao E. Li , Zhen Tao , Sharon Hammes-Schiffer

Strong light-matter interactions between molecules and quantized electromagnetic fields inside an optical cavity open up novel possibilities, though inevitably influenced by disorder, an inherent attribute of realistic molecular systems.…

Chemical Physics · Physics 2025-05-29 Robert F. Catuto , Hsing-Ta Chen

The observation that materials can change their properties when placed inside or near an optical resonator, has sparked a fervid interest in understanding the effects of strong light-matter coupling on molecular dynamics, and several…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Gerrit Groenhof

Strong coupling of molecules to the vacuum field of micro cavities can modify the potential energy surfaces opening new photophysical and photochemical reaction pathways. While the influence of laser fields is usually described in terms of…

Quantum Physics · Physics 2016-02-08 Markus Kowalewski , Kochise Bennett , Shaul Mukamel

Photons strongly coupled to material systems constitute a novel system for studying the dynamics of non-equilibrium quantum many-body systems. We give a fully analytical description of the dynamics of photons coupled to a one-dimensional…

Quantum Physics · Physics 2023-01-04 Björn Schrinski , Anders S. Sørensen

We show how to simulate a model of many molecules with both strong coupling to many vibrational modes and collective coupling to a single photon mode. We do this by combining process tensor matrix product operator methods with a mean-field…

Quantum Gases · Physics 2022-10-24 Piper Fowler-Wright , Brendon W. Lovett , Jonathan Keeling