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The strong coupling of an IR-active molecular transition with an optical mode of the cavity results in vibrational polaritons, which opens a new way to control chemical reactivity via confined electromagnetic fields of the cavity. In this…

Polaritons are quasi-particles originating from the coupling of light with matter that demonstrated quantum phenomena at the many-particle mesoscopic level, such as BEC and superfluidity. A highly sought and long-time missing feature of…

Polaritons, mixed light-matter quasiparticles, undergo a transition to a condensed, macroscopically coherent state at low temperatures or high densities. Recent experiments show that coupling light to organic molecules inside a microcavity…

Quantum Gases · Physics 2014-03-06 Justyna A. Cwik , Sahinur Reja , Peter B. Littlewood , Jonathan Keeling

Polaritons - hybrid light-matter states formed in cavity - strongly change the properties of the underlying matter. In optical or plasmonic nanocavities, polaritons decay by radiative emission of the cavity, which is accessible…

Chemical Physics · Physics 2022-10-19 Csaba Fábri , Gábor J. Halász , Lorenz S. Cederbaum , Ágnes Vibók

A light-matter hybrid quasiparticle, called a polariton, is formed when molecules are strongly coupled to an optical cavity. Recent experiments have shown that polariton chemistry can manipulate chemical reactions. Polariton chemistry is a…

Chemical Physics · Physics 2024-01-11 Xinyang Li , Nicholas Lubbers , Sergei Tretiak , Kipton Barros , Yu Zhang

Core-excitations on different atoms are highly localized and therefore decoupled. By placing molecules in an X-ray cavity the core-transitions become coupled via the exchange of cavity photons and form delocalized hybrid light-matter…

Quantum Physics · Physics 2021-02-08 Bing Gu , Artur Nenov , Francesco Segatta , Marco Garavelli , Shaul Mukamel

Multi-particle correlations of exciton-polaritons and reservoir-excitons in the strong light-matter coupling regime dictate the quantum dynamics of optical microcavities. In this letter, we examine the many-body exciton-polariton dynamics…

Coupling between light and material excitations underlies a wide range of optical phenomena. Polaritons are eigenstates of a coupled system with hybridized wave function. Owing to their hybrid composition, polaritons exhibit at the same…

Optics · Physics 2022-12-27 Denis G. Baranov , Christian Schäfer , Maxim V. Gorkunov

Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons possess much smaller effective masses and much larger group…

Chemical Physics · Physics 2023-10-18 Zeyu Zhou , Hsing-Ta Chen , Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

Phase transitions, where observable properties of a many-body system change discontinuously, can occur in both open and closed systems. Ultracold atoms have provided an exemplary model system to demonstrate the physics of closed-system…

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Recently, we predicted theoretically that in cavities that support several longitudinal modes, strong coupling can occur in very different manners, depending on the system parameters. Distinct longitudinal cavity modes are either entangled…

Quantum Physics · Physics 2023-10-10 M. Godsi , A. Golombek , M. Balasubrahmaniyam , T. Schwartz

Chemical reactions and energy transport phenomena have been experimentally reported to be significantly affected by strong light-matter interactions and vibrational polariton formation. These quasiparticles exhibit nontrivial transport…

Chemical Physics · Physics 2023-07-21 Enes Suyabatmaz , Raphael F. Ribeiro

An ensemble of identical, intrinsically non-interacting molecules exposed to quantum light is discussed. Their interaction with the quantum light induces interactions between the molecules. The resulting hybrid light-matter states exhibit…

Chemical Physics · Physics 2024-06-19 Lorenz S. Cederbaum

Plasmonic nanocavities enable the confinement of molecules and electromagnetic fields within nano-metric volumes. As a consequence, the molecules experience a remarkably strong interaction with the electromagnetic field, to such an extent…

Chemical Physics · Physics 2021-09-01 Jacopo Fregoni , Tor S. Haugland , Silvio Pipolo , Tommaso Giovannini , Henrik Koch , Stefano Corni

Polaritons are quasiparticles arising from the strong coupling of electromagnetic waves in cavities and dipolar oscillations in a material medium. In this framework, localized surface plasmon in metallic nanoparticles defining optical…

The coherent strong coupling of molecules with confined light fields to create polaritons - part matter, part light - is opening exciting opportunities ranging from extended exciton transport and inter-molecular energy transfer to modified…

We assess the cavity molecular dynamics method for the calculation of vibrational polariton spectra, using liquid water as a specific example. We begin by disputing a recent suggestion that nuclear quantum effects may lead to a broadening…

We present a combined analytical and numerical study for coherent terahertz control of a single molecular polariton, formed by strongly coupling two rotational states of a molecule with a single-mode cavity. Compared to the bare molecules…

Quantum Physics · Physics 2023-02-08 Li-Bao Fan , Chuan-Cun Shu , Daoyi Dong , Jun He , Niels E. Henriksen , Franco Nori

Recent experiments have demonstrated that polariton formation provides a novel strategy for modifying local molecular processes when a large ensemble of molecules is confined within an optical cavity. Herein, a numerical strategy based on…

Chemical Physics · Physics 2025-05-16 Andres Felipe Bocanegra Vargas , Tao E. Li