Related papers: Molecular deuterations in massive Starless Clump C…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
Context: In the last years, the H2D+ and D2H+ molecules have gained great attention as probes of cold and depleted dense molecular cloud cores. These ions are at the basis of molecular deuterium fractionation, a common characteristic…
The aim of this study is to investigate systematic chemical differentiation of molecules in regions of high mass star formation. We observed five prominent sites of high mass star formation in HCN, HNC, HCO+, their isotopes, C18O, C34S and…
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…
The results of a spectral survey of the region of massive star formation DR21OH in the 4-mm wavelength range are presented. Sixty-nine molecules and their isotopologues have been detected, ranging from simple diatomic or triatomic species…
Deuterium fractionation is a well-established evolutionary tracer in low-mass star formation, but its applicability to the high-mass regime remains an open question. The abundances and ratios of deuterated species have often been proposed…
Deuteration is a crucial tool to understand the complexity of interstellar chemical processes, especially when they involve the interplay of gas-phase and grain-surface chemistry. In the case of multiple deuteration, comparing observation…
We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found extremely high, [D2CO]/[H2CO] ~ 1-10 %, similar to that reported in…
High levels of deuterium fractionation of $\rm N_2H^+$ (i.e., $\rm D_{frac}^{N_2H^+} \gtrsim 0.1$) are often observed in pre-stellar cores (PSCs) and detection of $\rm N_2D^+$ is a promising method to identify elusive massive PSCs. However,…
Using the IRAM 30m telescope, we mapped the methanol emission in the pre-stellar core L1544 and observed singly deuterated methanol (CH$_2$DOH and CH$_3$OD) towards the dust peak of L1544. Non-LTE radiative transfer modelling was performed…
We used the NRAO Very Large Array to search for 3.6 cm continuum emission from embedded protostars in a sample of 8 nearby ``starless'' cores that show spectroscopic evidence for infalling motions in molecular emission lines. We detect a…
We report on the detection of deuterated molecular hydrogen, HD, at $z = 0.18$. HD and H$_{\rm 2}$ are detected in HST/COS data of a low metallicity ($Z \sim 0.07Z_\odot$) damped Ly$\alpha$ system at $z = 0.18562$ toward QSO B0120$-$28,…
The deuteration of molecules forming in the ices such as methanol (CH$_3$OH) is sensitive to the physical conditions during their formation in dense cold clouds and can be probed through observations of deuterated methanol in hot cores.…
Young massive stars are usually found embedded in dense and massive molecular clumps and are known for being highly obscured and distant. During their formation process, deuteration is regarded as a potentially good indicator of the…
High-mass stars are expected to form from dense prestellar cores. Their precise formation conditions are widely discussed, including their virial condition, which results in slow collapse for super-virial cores with strong support by…
Since the emission of water molecules cannot be observed from Earth, less abundant isotopologues, such as H$_2^{18}$O and HDO, are used to trace water in star-forming regions. The main aim of this study is to determine HDO abundance in the…
The abundance of deuterated molecules in a star-forming region is sensitive to the environment in which they are formed. Deuteration fractions therefore provide a powerful tool for studying the physical and chemical evolution of a…
We report the first detection in space of the single deuterated isotopologue of methyldiacetylene, CH2DC4H. A total of 12 rotational transitions, with J = 8-12 and Ka = 0 and 1, were identified for this species in TMC-1 in the 31.0-50.4 GHz…
We have observed the deuterated gas in the high-mass star formation region IRAS 05345+3157 at high-angular resolution, in order to determine the morphology and the nature of such gas. We have mapped the N2H+ (1-0) line with the Plateau de…
[abridged] The enhanced degrees of deuterium fractionation observed in envelopes around protostars demonstrate the importance of chemistry at low temperatures, relevant in pre- and protostellar cores. formaldehyde is an important species in…