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A thermodynamic framework has been developed for a class of amorphous polymers used in fused deposition modeling (FDM), in order to predict the residual stresses and the accompanying distortion of the geometry of the printed part (warping).…

Classical Physics · Physics 2021-02-09 P. Sreejith , K. Kannan , K. R. Rajagopal

The shear-transformation-zone (STZ) theory of plastic deformation in glass-forming materials is reformulated in light of recent progress in understanding the roles played the effective disorder temperature and entropy flow in nonequilibrium…

Materials Science · Physics 2009-11-13 J. S. Langer

Numerical simulations by Tanaka and coworkers indicate that glass forming systems of moderately polydisperse hard-core particles, in both two and three dimensions, exhibit diverging correlation lengths. These correlations are described by…

Statistical Mechanics · Physics 2013-06-21 J. S. Langer

While lot of measurements describe the relaxation dynamics of the liquid state, experimental data of the glass dynamics at high temperatures are much scarcer. We use ultrafast scanning calorimetry to expand the timescales of the glass to…

The dielectric alpha relaxation is the dielectric manifestation of the glass transition. In spite of this fact, the more commonly used models, the Arrhenius model and the Williams--Landel--Ferry model, do not take into account the…

Materials Science · Physics 2007-05-23 J. Sellares , J. C. Canadas , J. A. Diego , M. Mudarra , J. Belana

The glass transition in amorphous poly(ethylene terephthalate) is studied by thermally stimulated depolarization currents (TSDC) and differential scanning calorimetry (DSC). The ability of TSDC to decompose a distributed relaxation, as the…

Materials Science · Physics 2009-11-11 J. A. Diego , J. Sellares , A. Aragoneses , J. C. Canadas , M. Mudarra , J. Belana

We derive an equation for the glass relaxation. In the derivation, the Zwanzig-Mori projection method is not applied explicitly, which makes our equation different from the mode coupling theory. Due to the nonlinearity, it is difficult to…

Disordered Systems and Neural Networks · Physics 2023-02-17 Li Wan

The smooth emergence of shear elasticity is an hallmark of the liquid to glass transition. In a liquid, viscous stresses arise from local structural rearrangements. In the solid, Eshelby has shown that stresses around an inclusion decay as…

Soft Condensed Matter · Physics 2024-11-08 Niklas Grimm , Martin von Bischopinck , Andreas Zumbusch , Matthias Fuchs

We show that the dynamics of disordered charge density waves (CDWs) and spin density waves (SDWs) is a collective phenomenon. The very low temperature specific heat relaxation experiments are characterized by: (i) ``interrupted'' ageing…

Statistical Mechanics · Physics 2009-11-07 R. Mélin , K. Biljakovic , J. C. Lasjaunias , P. Monceau

The isothermal Navier-Stokes-Korteweg system is a classical diffuse interface model for compressible two-phase flow. However, the numerical solution faces two major challenges: due to a third-order dispersion contribution in the momentum…

Fluid Dynamics · Physics 2020-08-26 Timon Hitz , Jens Keim , Claus-Dieter Munz , Christian Rohde

We combine the shear-transformation-zone (STZ) theory of amorphous plasticity with Edwards' statistical theory of granular materials to describe shear flow in a disordered system of thermalized hard spheres. The equations of motion for this…

Statistical Mechanics · Physics 2013-11-14 Charles K. C. Lieou , J. S. Langer

Relaxation in glasses is often approximated by a stretched-exponential form: $f(t) = A \exp [-(t/\tau)^{\beta}]$. Here, we show that the relaxation in a model of sheared non-Brownian suspensions developed by Cort\'e et al. [Nature Phys. 4,…

Soft Condensed Matter · Physics 2017-02-02 Joseph D. Paulsen , Sidney R. Nagel

Shear-mechanical and dielectric measurements on the two monohydroxy (mono-alcohol) molecular glass formers 2-ethyl-1-hexanol and 2-butanol close to the glass transition temperature are presented. The shear-mechanical data are obtained using…

Soft Condensed Matter · Physics 2008-11-14 Bo Jakobsen , Claudio Maggi , Tage Christensen , Jeppe C. Dyre

We compute the rheological properties of inelastic hard spheres in steady shear flow for general shear rates and densities. Starting from the microscopic dynamics we generalise the Integration Through Transients (\textsc{itt}) formalism to…

Soft Condensed Matter · Physics 2020-03-03 W. Till Kranz , Fabian Frahsa , Annette Zippelius , Matthias Fuchs , Matthias Sperl

We apply a generalized Kibble-Zurek out-of-equilibrium scaling ansatz to simulated annealing when approaching the spin-glass transition at temperature $T=0$ of the two-dimensional Ising model with random $J= \pm 1$ couplings. Analyzing the…

Statistical Mechanics · Physics 2017-05-31 Shanon J. Rubin , Na Xu , Anders W. Sandvik

Glass-forming liquids have only a modest tendency to crystallize and hence their dynamics can be studied even below the melting temperature. The relaxation dynamics of most of these liquids shows at a temperature $T_c$, somewhat above the…

Soft Condensed Matter · Physics 2025-01-17 Francesco Rusciano , Raffaele Pastore , Francesco Greco , Walter Kob

Specific heat and linear thermal expansivity are fundamental thermal dynamics and have been proven as interesting relaxing quantities to investigate in glass transition and glassy state. However, their possibility has much less been…

Soft Condensed Matter · Physics 2021-09-06 Pengfei Zhang , Marco Gandolfi , Francesco Banfi , Christ Glorieux , Liwang Liu

Constitutive equations are derived for the viscoelastoplastic response of amorphous glassy polymers at isothermal loading with small strains. A polymer is treated as an ensemble of cooperatively relaxing regions (CRR) which rearrange at…

Materials Science · Physics 2007-05-23 Aleksey D. Drozdov

Recent numerical simulations of a disordered system (Preprint arXiv:condmat/0307554) have shown the existence of two different relaxational processes (called stimulated and spontaneous) characterizing the relaxation observed in structural…

Disordered Systems and Neural Networks · Physics 2007-05-23 F. Ritort

We review the recently proposed elastic approach to glass transition. This approach is based on a simple and a physically transparent idea of elastic interactions between local relaxation events in a liquid. Central to this picture is the…

Soft Condensed Matter · Physics 2008-07-25 Kostya Trachenko