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We investigate the effective potential and scattering length of ultracold polar molecules under different shielding techniques. First, we derive the effective potential for two polar molecules in the presence of an elliptical polarization…

Quantum Gases · Physics 2025-05-29 Peng Xu , Gang Chen

By applying a circularly polarized and slightly blue-detuned microwave field with respect to the first excited rotational state of a dipolar molecule, one can engineer a long-range, shallow potential well in the entrance channel of the two…

Quantum Gases · Physics 2018-10-24 Lucas Lassablière , Goulven Quéméner

The prospects for shielding ultracold, paramagnetic, dipolar molecules from inelastic and chemical collisions are investigated. Molecules placed in their first rotationally excited states are found to exhibit effective long-range repulsion…

Atomic Physics · Physics 2016-01-20 Goulven Quéméner , John L. Bohn

We study collisions of ultracold CaF molecules in strong static electric fields. These fields allow the creation of long-range barriers in the interaction potential, effectively preventing the molecules from reaching the short-range region…

The ability to tune interparticle interactions is one of the main advantages of using ultracold quantum gases for quantum simulation of many-body physics. Current experiments with ultracold polar molecules employ shielding with microwave or…

Quantum Gases · Physics 2026-03-24 Christopher J. Ho , Joy Dutta , Bijit Mukherjee , Jeremy M. Hutson , Michael R. Tarbutt

We investigate the electric field shielding of ultracold collisions of dipolar rotors, initially in their first rotational excited state, using an adimensional approach. We establish a map of good and bad candidates for efficient…

Atomic Physics · Physics 2017-10-04 Maykel L. González-Martínez , John L. Bohn , Goulven Quéméner

We explore the total cross section of ground state polar molecules in an electric field at various energies, focusing on RbCs and RbK. An external electric field polarizes the molecules and induces strong dipolar interactions leading to…

Atomic Physics · Physics 2009-11-13 Christopher Ticknor

We report on the optical polarizability of microwave-shielded ultracold NaCs molecules in an optical dipole trap. While dressing a pair of rotational states with a microwave field, we observe a marked dependence of the optical…

Quantum Gases · Physics 2025-01-16 Siwei Zhang , Weijun Yuan , Niccolò Bigagli , Claire Warner , Ian Stevenson , Sebastian Will

We explore one-dimensional (1-D) samples of ultracold polar molecules with attractive dipole-dipole interactions and show the existence of a repulsive barrier due to a strong quadrupole interaction between molecules. This barrier can…

Chemical Physics · Physics 2015-06-05 Jason N. Byrd , John A. Montgomery , Robin Côté

We propose and analyze a technique that allows to suppress inelastic collisions and simultaneously enhance elastic interactions between cold polar molecules. The main idea is to cancel the leading dipole-dipole interaction with a suitable…

Statistical Mechanics · Physics 2008-09-29 A. V. Gorshkov , P. Rabl , G. Pupillo , A. Micheli , P. Zoller , M. D. Lukin , H. P. Büchler

We use microwaves to engineer repulsive long-range interactions between ultracold polar molecules. The resulting shielding suppresses various loss mechanisms and provides large elastic cross sections. Hyperfine interactions limit the…

Atomic Physics · Physics 2018-10-24 Tijs Karman , Jeremy M. Hutson

We propose a method to suppress collisional loss in strongly dipolar, rotationally excited ultracold molecules using a combination of static (dc) and microwave (ac) electric fields. By tuning two excited pair molecular rotational states…

Quantum Gases · Physics 2026-01-30 Reuben R. W. Wang

We propose a method to suppress the chemical reactions between ultracold bosonic ground-state $^{23}$Na$^{87}$Rb molecules based on optical shielding. By applying a laser with a frequency blue-detuned from the transition between the lowest…

Quantum Gases · Physics 2020-10-14 T. Xie , M. Lepers , R. Vexiau , A. Orban , O. Dulieu , N. Bouloufa-Maafa

We consider a Bose-Einstein condensate of polar molecules in a harmonic trap, where the effective dipole may be tuned by an external field. We demonstrate that taking into account the dependence of the scattering length on the dipole moment…

Statistical Mechanics · Physics 2009-11-11 Shai Ronen , Daniele C. E. Bortolotti , D. Blume , John L. Bohn

We explore the impact of the short range interaction on the scattering of ground state polar molecules, and study the transition from a weak to strong dipolar scattering over an experimentally reasonable range of energies and electric field…

Atomic Physics · Physics 2009-11-13 Christopher Ticknor

Microwave shielding is an important technique that can suppress the losses that arise from collisions of ultracold polar molecules. It has been instrumental in achieving molecular Bose-Einstein condensation (BEC) for NaCs [Bigagli et al.,…

Quantum Gases · Physics 2025-05-07 Joy Dutta , Bijit Mukherjee , Jeremy M. Hutson

Quantum gases of ultracold polar molecules have novel properties because of the strong dipolar forces between molecules. Current experiments shield the molecules from destructive collisions by engineering long-range repulsive interactions…

Quantum Gases · Physics 2025-09-26 Bijit Mukherjee , Luis Santos , Jeremy M. Hutson

Collisions of polar $^{1}\Sigma$ state molecules at ultralow energies are considered, within a model that accounts for long-range dipole-dipole interactions, plus rotation of the molecules. We predict a substantial suppression of…

Atomic Physics · Physics 2016-09-08 Alexander V. Avdeenkov , Masatoshi Kajita , John L. Bohn

In this paper, we present an electrode geometry for the manipulation of ultracold rovibrational ground state NaK molecules. The electrode system allows to induce a dipole moment in trapped diatomic NaK molecules with a magnitude up to $68…

Quantum Gases · Physics 2016-05-18 M. W. Gempel , T. Hartmann , T. A. Schulze , K. K. Voges , A. Zenesini , S. Ospelkaus

We present first steps toward understanding the ultracold scattering properties of polar molecules in strong electric field-seeking states. We have found that the elastic cross section displays a quasi-regular set of potential resonances as…

Atomic Physics · Physics 2009-11-11 Christopher Ticknor , John L. Bohn
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