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Raman study on a select few orthochromites, RCrO$_3$ (R = Y, Lu, Gd, Eu and Sm) shows that the phonon behavior at TN in compounds with magnetic R-ion (Gd and Sm) is remarkably different from that of non-magnetic R-ion (Y, Lu and Eu). While…

Materials Science · Physics 2013-06-11 Venkata Srinu Bhadram , B. Rajeswaran , A. Sundaresan , Chandrabhas Narayana

We report on the structural evolution, spin phonon interactions, and magnetoelastic effects in bulk LaFeO3 perovskite across its antiferromagnetic transition. We found that while the lattice constants exhibit slight deviations at the Neel…

The interplay between different degrees of freedom such as charge, spin, orbital, and lattice has received a great deal of interest due to its potential to engineer materials properties and their functionalities for device applications. In…

Materials Science · Physics 2021-10-26 Bommareddy Poojitha , Ankit Kumar , Anjali Rathore , Devesh Negi , Surajit Saha

We theoretically study origins of the ferroelectricity in the multiferroic phases of the rare-earth (R) Mn perovskites, RMnO3, by constructing a realistic spin model including the spin-phonon coupling, which reproduces the entire…

Strongly Correlated Electrons · Physics 2011-02-21 Masahito Mochizuki , Nobuo Furukawa , Naoto Nagaosa

We report the influence of Ce$^{3+}$ substitution on the magnetic structures and phonon dynamics in SmCrO$_3$ perovskites. Magnetic landscapes are spanned by long-range canted anti-ferromagnetism, AFM with Neel temperatures $\sim$196 K…

Materials Science · Physics 2025-12-30 Shaona Das , Ravi Kiran Dokala , Subhash Thota

Polarization induced spin switching of atoms in magnetic materials opens for possibilities to design and develop advanced spintronic devices, in particular, storage devices where the magnetic state can be controlled by an electric field. We…

Materials Science · Physics 2018-10-09 Indukuru Ramesh Reddy , Peter M. Oppeneer , Kartick Tarafder

Hybrid organic-inorganic perovskites are famous for the diversity of their chemical compositions, phases and phase transitions, and associated physical properties. We use a combination of experimental and computational techniques to reveal…

A remarkable hardening (~ 30 cm-1) of the normal mode of vibration associated with the symmetric stretching of the oxygen octahedra for the Ba2FeReO6 and Sr2CrReO6 double perovskites is observed below the corresponding magnetic ordering…

The emergence of magnetism in quantum materials creates a platform to realize spin-based applications in spintronics, magnetic memory, and quantum information science. A key to unlocking new functionalities in these materials is the…

The coupling between localized spins and phonons can lead to shifts in the dielectric constant of insulating materials at magnetic ordering transitions. Studies on isostructural SeCuO3 (ferromagnetic) and TeCuO3 (antiferromagnetic)…

Materials Science · Physics 2009-04-14 G. Lawes , T. Kimura , C. M. Varma , M. A. Subramanian , R. J. Cava , A. P. Ramirez

The temperature dependence of eigenfrequencies and intensities of the IR active modes has been investigated for the antiferromagnetic chromium spinel compounds CdCr2O4, ZnCr2O4, ZnCr2S4, ZnCr2Se4, and HgCr2S4 by IR spectroscopy for…

Strongly Correlated Electrons · Physics 2007-07-05 T. Rudolf , Ch. Kant , F. Mayr , J. Hemberger , V. Tsurkan , A. Loidl

Weak antiferromagnetic (AF) interaction in the ferromagnetic (FM) partially ordered La2CoMnO6 (LCMO) was detected by Raman spectroscopy by monitoring spin-phonon coupling. Because of the sensibility to probe short-range disorder and lattice…

Materials Science · Physics 2022-05-17 R. X. Silva , C. C. Santos , H. Reichlova , X. Marti , R. Paniago , C. W. A. Paschoal

While 3$d$-containing materials display strong electron correlations, narrow band widths, and robust magnetism, 5$d$ systems are recognized for strong spin-orbit coupling, increased hybridization, and more diffuse orbitals. Combining these…

Spin-phonon interactions in 2D magnetic materials are crucial in advancing next-generation spintronic devices. Therefore, identifying new materials with significant spin-phonon interactions is of great importance. In this context, MnSe,…

Materials Science · Physics 2025-02-27 Suman Kalyan Pradhan , Arnab Bera , Soham Das , Yongli Yu , Jicheng Wang , Rui Wu

Transition-metal perovskite oxides exhibit moderately correlated metallic phases, several of which exhibit a $T^2$ resistivity scaling up to temperatures far exceeding the regime where Fermi-liquid electron-electron scattering is expected…

Materials Science · Physics 2026-04-02 Jennifer Coulter , Fabian B. Kugler , Harrison LaBollita , Antoine Georges , Cyrus E. Dreyer

The temperature dependence of phonon excitations and the presence of spin phonon coupling in polycrystalline Pr2NiMnO6 samples were studied using micro-Raman spectroscopy and magnetometry. Magnetic properties show a single…

Materials Science · Physics 2011-01-17 K. D. Truong , M. P. Singh , S. Jandl , P. Fournier

We report detailed Raman spectroscopic and magnetic susceptibility studies on the spin-driven ferroelectric compounds Mn4Nb2O9 (MNO) and Mn4Ta2O9 (MTO). Both systems exhibit strong spin-phonon coupling below the short-range magnetic…

Materials Science · Physics 2026-02-09 Rajesh Jana , Alka Garg , Rekha Rao , Thomas Meier

Spin-phonon coupling and magnetodielectric effects of ZnCr2Se4 were investigated by means of infrared (IR) spectroscopy as a function of temperature and magnetic field. ZnCr2Se4 is dominated by ferromagnetic exchange but undergoes…

Strongly Correlated Electrons · Physics 2007-07-05 T. Rudolf , Ch. Kant , F. Mayr , J. Hemberger , V. Tsurkan , A. Loidl

Using first-principles density functional calculations, we study the electronic and magnetic properties of ferromagnetic insulating double-perovskite compound La2NiMnO6, which has been reported to exhibit interesting magnetic field…

Materials Science · Physics 2008-05-09 Hena Das , Umesh V. Waghmare , T. Saha-Dasgupta , D. D. Sarma

Quantum tunneling of the magnetization is a phenomenon that impedes the use of small anisotropic spin systems for storage purposes even at the lowest temperatures. Phonons, usually considered for temperature dependent relaxation of…

Strongly Correlated Electrons · Physics 2021-04-07 K. Irländer , H. -J. Schmidt , J. Schnack