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Harnessing the interaction between light and matter at the quantum level has been a central theme in atomic physics and quantum optics, with applications from quantum computation to quantum metrology. Combining complex interactions with…

Cavity quantum electrodynamics (QED) generalizations of time-dependent (TD) density functional theory (DFT) and equation-of-motion (EOM) coupled-cluster (CC) theory are used to model small molecules strongly coupled to optical cavity modes.…

Chemical Physics · Physics 2023-07-19 Marcus D. Liebenthal , Nam Vu , A. Eugene DePrince

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

The availability of efficient photon sources with specific properties is important for quantum-technological applications. However, the realization of such photon sources is often challenging and hence alternative perspectives that suggest…

Quantum electrodynamics (QED) with self-conjugated equations with spinor wave functions for fermion fields is considered. In the low order of the perturbation theory, matrix elements of some of QED physical processes are calculated. The…

General Physics · Physics 2021-08-11 V. P. Neznamov , V. E. Shemarulin

We investigate the accuracy of a number of wavefunction based methods at the heart of quantum chemistry for metallic systems. Using Hartree-Fock as a reference, perturbative (M{\o}ller-Plesset, MP) and coupled cluster (CC) theories are used…

Chemical Physics · Physics 2013-10-24 James J. Shepherd , Andreas Grüneis

We present a time-dependent variational approach with the multiple Davydov $D_2$ trial state to simulate the dynamics of light-matter systems when the field is in a coherent state with an arbitrary finite mean photon number. The variational…

Quantum Physics · Physics 2024-07-18 Yiying Yan , Zhiguo Lü , JunYan Luo

In cavity quantum electrodynamics (QED), photons leaving the cavity can be irreversibly lost or reused as a power source. This dichotomy is reflected in two different thermodynamic bookkeepings of the light field, both corresponding to…

Quantum Physics · Physics 2026-02-09 Marcelo Janovitch , Sander Stammbach , Matteo Brunelli , Patrick P. Potts

A common experimental setup in cavity quantum electrodynamics (QED) consists of a single two-level atom interacting with a single mode of the electromagnetic field inside an optical cavity. The cavity is externally driven and the output is…

Quantum Physics · Physics 2009-11-07 Andrei N. Soklakov , Ruediger Schack

Macroscopic quantum electrodynamics (MQED) provides a unified framework to describe quantum electromagnetic fields in the presence of arbitrary macroscopic environments. Central to this theory is the field correlation, which governs both…

Quantum Physics · Physics 2026-03-02 Daigo Oue

Multideterminant calculations have been performed on model systems to emphasize the role of many-body effects in the general description of charge quantization experiments. We show numerically and derive analytically that a closed-shell…

Mesoscale and Nanoscale Physics · Physics 2015-05-13 V. Geskin , R. Stadler , J. Cornil

Quantum computational chemistry has emerged as an important application of quantum computing. Hybrid quantum-classical computing methods, such as variational quantum eigensolvers (VQE), have been designed as promising solutions to quantum…

Coupled quantum electrodynamics (QED) cavities have been recently proposed as new systems to simulate a variety of equilibrium and non-equilibrium many-body phenomena. We present a brief review of their main properties together with a…

Strongly Correlated Electrons · Physics 2010-05-04 Andrea Tomadin , Rosario Fazio

First-order electric dipole response functions are implemented for cavity quantum electrodynamics (QED) generalizations of Hartree-Fock (HF) and Kohn-Sham density functional theory (DFT) in order to assess the degree to which static…

Chemical Physics · Physics 2025-07-31 A. Eugene DePrince , Stephen H. Yuwono

We study theoretically the quantum optical properties of hybrid molecules composed of an individual quantum dot and a metallic nanoparticle. We calculate the resonance fluorescence of this hybrid system. Its incoherent part, the one arising…

Quantum Physics · Physics 2010-04-12 A. Ridolfo , O. Di Stefano , N. Fina , R. Saija , S. Savasta

Cavity quantum electrodynamics (QED) studies the interaction between resonator-confined radiation and natural atoms or other formally equivalent quantum excitations, under conditions where the quantum nature of photons is relevant.…

Despite significant theoretical efforts devoted to studying the interaction between quantized light modes and matter, the so-called ultra-strong coupling regime still presents significant challenges for theoretical treatments and prevents…

Quantum Physics · Physics 2024-03-22 Maksim Lednev , Francisco J. García-Vidal , Johannes Feist

The calculation of electron-phonon (e-ph) coupling from first principles is a topic of great interest in materials science, offering a robust, non-empirical framework to understand and predict a wide range of physical phenomena. While…

Materials Science · Physics 2025-03-17 Savio Laricchia , Casey Eichstaedt , Dimitar Pashov , Mark van Schilfgaarde

We employ various quantum-mechanical approaches for studying the impact of electric fields on both nonretarded and retarded noncovalent interactions between atoms or molecules. To this end, we apply perturbative and non-perturbative methods…

Chemical Physics · Physics 2022-02-03 Mohammad Reza Karimpour , Dmitry V. Fedorov , Alexandre Tkatchenko

Light-front coordinates offer a scenario in which a constituent picture of hadron structure can emerge from QCD, after several difficulties are addressed. Field theoretic difficulties force us to introduce cutoffs that violate Lorentz…

High Energy Physics - Theory · Physics 2008-02-03 Robert J. Perry
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