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Intermolecular van der Waals interactions are central to chemical and physical phenomena ranging from biomolecule binding to soft-matter phase transitions. However, there are currently very limited approaches to manipulate van der Waals…

Dispersion interactions such as the van der Waals interaction between atoms or molecules derive from quantum fluctuations of the electromagnetic field and can be understood as the exchange of virtual photons between the interacting…

Quantum Physics · Physics 2015-06-11 Harald R. Haakh , Stefan Scheel

We present an approach for computing long-range van der Waals (vdW) interactions between complex molecular systems and arbitrarily shaped macroscopic bodies, melding atomistic treatments of electronic fluctuations based on density…

Mesoscale and Nanoscale Physics · Physics 2017-07-05 Prashanth S. Venkataram , Jan Hermann , Alexandre Tkatchenko , Alejandro W. Rodriguez

We explain in depth the previously proposed theory of the coherent Van der Waals(cVdW) interaction - the counterpart of Van der Waals (VdW) force - emerging in spatially coherently fluctuating electromagnetic fields. We show that cVdW…

Soft Condensed Matter · Physics 2015-06-22 Igor M. Kulic , Miodrag L. Kulic

Many-body phenomena in quantum materials emerge from the interplay among a broad continuum of electronic states, and controlling these interactions is critical for engineering novel phases. One promising approach exploits fluctuations of…

Materials Science · Physics 2025-04-24 F. Helmrich , H. S. Adlong , I. Khanonkin , M. Kroner , G. Scalari , J. Faist , A. Imamoglu , T. F. Nova

Noncovalent van der Waals (vdW) interactions are responsible for a wide range of phenomena in matter. Popular density-functional methods that treat vdW interactions use disparate physical models for these intricate forces, and as a result…

Materials Science · Physics 2020-04-15 Jan Hermann , Alexandre Tkatchenko

Structuring the photon density of states and light-matter coupling in optical cavities has emerged as a promising approach to modifying the equilibrium properties of materials through strong light-matter interactions. In this article, we…

Materials Science · Physics 2025-08-08 Hang Liu , Simone Latini , I-Te Lu , Dongbin Shin , Angel Rubio

We propose a robust and efficient way of controlling the optical spectra of two-dimensional materials and van der Waals heterostructures by quantum cavity embedding. The cavity light-matter coupling leads to the formation of…

Mesoscale and Nanoscale Physics · Physics 2019-06-19 Simone Latini , Enrico Ronca , Umberto de Giovannini , Hannes Hübener , Angel Rubio

We present a new scheme to include the van der Waals (vdW) interactions in approximated Density Functional Theory (DFT) by combining the Quantum Harmonic Oscillator model with the Maximally Localized Wannier Function technique. With respect…

Materials Science · Physics 2015-06-16 Pier Luigi Silvestrelli

Controlling matter-light interactions with cavities is of fundamental importance in modern science and technology. It is exemplified in the strong-coupling regime, where matter-light hybrid modes form, with properties controllable via the…

Mesoscale and Nanoscale Physics · Physics 2021-11-03 Long Zhang , Fengcheng Wu , Shaocong Hou , Zhe Zhang , Yu-Hsun Chou , Kenji Watanabe , Takashi Taniguchi , Stephen R. Forrest , Hui Deng

Harnessing strong light-matter interactions to control chemical reactions in confined electromagnetic fields offers a promising route toward deepening our understanding of chemical dynamics at the collective quantum-mechanical level, with…

Chemical Physics · Physics 2026-01-21 Yaling Ke

Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact via strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion)…

Materials Science · Physics 2026-02-24 Subhojit Pal , John F. Dobson , Mathias Boström

Molecular polaritons arise when molecules interact so strongly with light that they become entangled with each other. This light-matter hybridization alters the chemical and physical properties of the molecular system and allows chemical…

Chemical Physics · Physics 2023-07-28 Tor S. Haugland , John P. Philbin , Tushar K. Ghosh , Ming Chen , Henrik Koch , Prineha Narang

Weinvestigate the generation of antibunching photons and photon pairs in a two-atom cavity QED system leveraging interatomic van der Waals (vdW) interaction. We show that the vdW interaction shifts the two-atom excited state, enabling the…

Quantum Physics · Physics 2025-09-16 Zhouyang Yu , Jinping Xu , Chengjie Zhu , Zhengyang Bai , Yaping Yang

We consider the resonant van der Waals interaction between two correlated identical two-level atoms (at least one of which being excited) within the framework of macroscopic cavity quantum electrodynamics in linear, dispersing and absorbing…

Quantum Physics · Physics 2018-05-09 Saeideh Esfandiarpour , Robert Bennett , Hassan Safari , Stefan Yoshi Buhmann

Van der Waals (vdW) materials offer new ways to assemble artificial electronic media with properties controlled at the design stage, by combining atomically defined layers into interfaces and heterostructures. Their potential for…

Molecular-scale manipulation of electronic/ionic charge accumulation in materials is a preeminent challenge, particularly in electrochemical energy storage. Layered van der Waals (vdW) crystals exemplify a diverse family of materials that…

Using fourth-order perturbation theory, a general formula for the van der Waals potential of two neutral, unpolarized, ground-state atoms in the presence of an arbitrary arrangement of dispersing and absorbing magnetodielectric bodies is…

Quantum Physics · Physics 2007-05-23 Hassan Safari , Stefan Yoshi Buhmann , Dirk-Gunnar Welsch , Ho Trung Dung

In this article, we theoretically study the quantum statistical properties of the light transmitted through or reflected from an optical cavity, filled by an atomic medium with strong optical non-linearity induced by Rydberg-Rydberg van der…

Quantum Physics · Physics 2019-06-14 A. Grankin , E. Brion , E. Bimbard , R. Boddeda , I. Usmani , A. Ourjoumtsev , P. Grangier

Photonics has been revolutionized by breakthroughs in optical metasurfaces and layered two-dimensional materials. Yet, integrating these two fields in a singular system has remained challenging. Here, we introduce the concept of van der…

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