English

Attractive and repulsive terms in multi-filament dispersion interactions

Materials Science 2026-02-24 v4 Soft Condensed Matter Biological Physics

Abstract

Filamentary objects such as nano-wires, nanotubes and DNA are of current interest in physics, nanoscience, chemistry, biology and medicine. They can interact via strong, exceptionally long-ranged many-object van der Waals (vdW, dispersion) forces, causing them to cluster into multi-object bundles. We analyse their vdW interactions perturbatively, predicting NN-object vdW energy contributions that alternate in sign with increasing NN. Our findings are confirmed here via the first detailed analysis of a 4-cylinder vdW model. We also provide novel insights permitting these tendencies to be understood simply in terms of electronic screening and anti-screening. Our results suggest that a non-perturbative calculation will be required for reliable prediction of dispersion interactions in these ubiquitous systems.

Keywords

Cite

@article{arxiv.2409.00419,
  title  = {Attractive and repulsive terms in multi-filament dispersion interactions},
  author = {Subhojit Pal and John F. Dobson and Mathias Boström},
  journal= {arXiv preprint arXiv:2409.00419},
  year   = {2026}
}

Comments

12 pages, 5 figures

R2 v1 2026-06-28T18:29:53.563Z