Related papers: Nonlinear opto-vibronics in molecular systems
Model optomechanical systems with photon-vibration interactions linear, quadratic, and cubic in mechanical displacements are studied under conditions for adiabatic elimination of the photon field. The opportunity of transformation of…
We study cavity optomechanics of a mixture of ultracold atoms with tunable nonlinear collisions. We show that atomic collisions provide linear couplings between fictitious condensate oscillators, leading to possibilities of achieving a…
We propose a novel approach to calculate dynamical processes at ultrafast time scale in molecules in which vibrational and electronic motions are strongly mixed. The relevant electronic orbitals and their interactions are described by a…
Optical microcavities and metallic nanostructures have been shown to significantly modulate the dynamics and spectroscopic response of molecular systems. We present a study of the nonlinear optics of a model consisting of $N$ anharmonic…
This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…
Manifesting across all time, mass and length scales, nonlinearities lie at the core of numerous physical phenomena. Next-generation quantum applications, such as quantum sensing, require the combination of nonlinearity with non-classical…
We study non-linear optical effects in electron systems with and without inversion symmetry in a Fabry-Perot cavity. General photon up- and down-conversion processes are modeled by the coupling of a noninteracting lattice model to two modes…
We derive an electron-vibration model Hamiltonian in a quantum chemical framework, and explore the extent to which such a Hamiltonian can capture key effects of nonadiabatic dynamics. The model Hamiltonian is a simple two-body operator, and…
We study theoretically the quantum dynamics and spectroscopy of rovibrational polaritons formed in a model system composed of a single rovibrating diatomic molecule, which interacts with two degenerate, orthogonally polarized modes of an…
Optomechanical systems explore and exploit the coupling between light and the mechanical motion of matter. A nonlinear coupling offers access to rich new physics, in both the quantum and classical regimes. We investigate a dynamic, as…
The idea of making photons effectively interact has attracted a lot of interest in recent years, for several reasons. Firstly, since photons do not naturally interact with each other, it is of fundamental physical interest to see what kind…
We characterize both entanglement and quantum coherence in a molecular system by connecting the linear entropy of electronic-nuclear entanglement with Wigner-Yanase skew information measuring vibronic coherence and local quantum uncertainty…
Linear oscillators contribute to most branches of contemporary quantum science. They have already successfully served as quantum sensors and memories, found applications in quantum communication, and hold promise for cluster-state-based…
Nonlinear interactions between phonon modes govern the behavior of vibrationally highly excited solids and molecules. Here, we demonstrate theoretically that optical cavities can be used to control the redistribution of energy from a highly…
Recent experiments have observed that the chemical and photophysical properties of molecules can be modified inside an optical Fabry-Perot microcavity under collective vibrational strong coupling (VSC) conditions, and such modification is…
Quantum light-matter systems at strong coupling are notoriously challenging to analyze due to the need to include states with many excitations in every coupled mode. We propose a nonperturbative approach to analyze light-matter correlations…
We study the nonlinear driven dissipative quantum dynamics of an array of optomechanical systems. At each site of such an array, a localized mechanical mode interacts with a laser-driven cavity mode via radiation pressure, and both photons…
Optomechanical systems are a promising candidate for the implementation of quantum interfaces for storing and redistributing quantum information. Here we focus on the case of a high-finesse optical cavity with a thin vibrating…
The generation of nonclassical light states bears a paramount importance in quantum optics and is largely relying on the interaction between intense laser pulses and nonlinear media. Recently, electron beams, such as those used in ultrafast…
Recent years have seen significant developments in the study of strong light-matter coupling including the control of chemical reactions by altering the vibrational normal modes of molecules. In the vibrational strong coupling regime the…