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The unitary coupled cluster (UCC) ansatz is a promising tool for achieving high-precision results using the variational quantum eigensolver (VQE) algorithm in the NISQ era. However, results on quantum hardware are thus far very limited and…

Quantum Physics · Physics 2024-11-27 Mark R. Hirsbrunner , Diana Chamaki , J. Wayne Mullinax , Norm M. Tubman

Recently, integrated photonic circuits have brought new capabilities to electron microscopy and been used to demonstrate efficient electron phase modulation and electron-photon correlations. Here, we quantitatively analyze the feasibility…

Quantum Physics · Physics 2023-06-30 Guanhao Huang , Nils J. Engelsen , Ofer Kfir , Claus Ropers , Tobias J. Kippenberg

Quantum computing is viewed as a promising technology because of its potential for polynomial growth in complexity, in contrast to the exponential growth observed in its classical counterparts. In the current Noisy Intermediate-Scale…

Chemical Physics · Physics 2026-01-13 Maitreyee Sarkar , Lisa Roy , Akash Gutal , Atul Kumar , Manikandan Paranjothy

Many quantum algorithms rely on a quality initial state for optimal performance. Preparing an initial state for specific applications can considerably reduce the cost of probabilistic algorithms such as the well studied quantum phase…

Quantum Physics · Physics 2024-12-10 Alexandre Fleury , James Brown , Erika Lloyd , Maritza Hernandez , Isaac H. Kim

Most quantum systems that are used for generating entanglement and for practical applications are not isolated from the environment, and are hence susceptible to noise. Entanglement in more than one degree of freedom between two systems,…

Quantum Physics · Physics 2022-10-27 Akshay Kannan Sairam , C. M. Chandrashekar

We experimentally demonstrate a qubit-efficient variational quantum eigensolver (VQE) algorithm using a superconducting quantum processor, employing minimal quantum resources with only a transmon qubit coupled to a high-coherence photonic…

To understand quantum optics experiments, we must perform calculations that consider the principal sources of noise, such as losses, spectral impurity and partial distinguishability. In both discrete and continuous variable systems, these…

Quantum Physics · Physics 2025-08-15 Jacob F. F. Bulmer , Javier Martínez-Cifuentes , Bryn A. Bell , Nicolás Quesada

The number of excitations in a large quantum system (harmonic oscillator or qudit) can be measured in a quantum nondemolition manner using a dispersively coupled qubit. It typically requires a series of qubit pulses that encode various…

Coherent scattering of light by a single quantum emitter is a fundamental process at the heart of many proposed quantum technologies. Unlike atomic systems, solid-state emitters couple to their host lattice by phonons. Using a quantum dot…

A pulsed balanced homodyne detector has been developed for precise measurements of electric field quadratures of pulsed optical quantum states. A high level of common mode suppression (> 85 dB) and low electronic noise (730 electrons per…

Quantum Physics · Physics 2009-11-07 H. Hansen , T. Aichele , C. Hettich , P. Lodahl , A. I. Lvovsky , J. Mlynek , S. Schiller

Variational quantum eigensolvers (VQE) are among the most promising approaches for solving electronic structure problems on near-term quantum computers. A critical challenge for VQE in practice is that one needs to strike a balance between…

In the vibrational strong coupling (VSC) regime, molecular vibrations and resonant low-frequency cavity modes form light-matter hybrid states, named vibrational polaritons, with characteristic IR spectroscopic signatures. Here, we introduce…

Chemical Physics · Physics 2025-12-02 Eric W. Fischer , Jan A. Syska , Peter Saalfrank

The recent developments of quantum computing present potential novel pathways for quantum chemistry, as the increased computational power of quantum computers could be harnessed to naturally encode and solve electronic structure problems.…

Quantum Physics · Physics 2024-03-01 Lila Cadi Tazi , Alex J. W. Thom

Recently the possibility of generating nonclassical polariton states by means of parametric scattering has been demonstrated. Excitonic polaritons propagate in a complex interacting environment and contain real electronic excitations…

Mesoscale and Nanoscale Physics · Physics 2007-10-16 S. Portolan , O. Di Stefano , S. Savasta , F. Rossi , R. Girlanda

We propose an orbital optimized method for unitary coupled cluster theory (OO-UCC) within the variational quantum eigensolver (VQE) framework for quantum computers. OO-UCC variationally determines the coupled cluster amplitudes and also…

Strongly Correlated Electrons · Physics 2020-09-23 Wataru Mizukami , Kosuke Mitarai , Yuya O. Nakagawa , Takahiro Yamamoto , Tennin Yan , Yu-ya Ohnishi

Reducing circuit depth is essential for implementing quantum simulations of electronic structure on near-term quantum devices. In this work, we propose a variational quantum eigensolver (VQE) based perturbation theory algorithm to…

Quantum Physics · Physics 2024-01-17 Jie Liu , Zhenyu Li , Jinlong Yang

Quantum algorithms for Noisy Intermediate-Scale Quantum (NISQ) machines have recently emerged as new promising routes towards demonstrating near-term quantum advantage (or supremacy) over classical systems. In these systems samples are…

Quantum computing presents a promising path toward precise quantum chemical simulations, particularly for systems that challenge classical methods. This work investigates the performance of the Variational Quantum Eigensolver (VQE) in…

Quantum Physics · Physics 2025-10-28 Zakaria Boutakka , Nouhaila Innan , Muhammed Shafique , Mohamed Bennai , Z. Sakhi

Bosonic quantum devices offer a novel approach to realize quantum computations, where the quantum two-level system (qubit) is replaced with the quantum (an)harmonic oscillator (qumode) as the fundamental building block of the quantum…

Quantum technologies promise profound advances in communication security, sensing and computing. The underpinning hardware must be engineered to generate, manipulate and detect quantum phenomena with exceptional performance, whilst being…

Quantum Physics · Physics 2025-07-15 R. N. Clark , B. Puzio , O. M. Green , S. T. Pradyumna , O. Trojak , A. Politi , J. C. F. Matthews