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A variational approach is used to develop a robust numerical procedure for solving the nonlinear Poisson-Boltzmann equation. Following Maggs et al., we construct an appropriate constrained free energy functional, such that its…

Soft Condensed Matter · Physics 2020-04-29 M. Baptista , R. Schmitz , B. Duenweg

The Poisson-Boltzmann (PB) equation provides a mean-field theory of electrolyte solutions at interfaces and in confinement, describing how ions reorganize close to charged surfaces to form the so-called electrical double layer (EDL), with…

Soft Condensed Matter · Physics 2024-09-10 Cecilia Herrero , Laurent Joly

We consider the reconstruction of a heterogeneous coefficient field in a Robin boundary condition on an inaccessible part of the boundary in a Poisson problem with an uncertain (or unknown) inhomogeneous conductivity field in the interior…

Optimization and Control · Mathematics 2018-09-26 Ruanui Nicholson , Noemi Petra , Jari Kaipio

A multiscale numerical method is proposed for the solution of semi-linear elliptic stochastic partial differential equations with localized uncertainties and non-linearities, the uncertainties being modeled by a set of random parameters. It…

Numerical Analysis · Mathematics 2019-01-23 Anthony Nouy , Florent Pled

A nonlinear Poisson--Boltzmann equation with transmission boundary conditions at the interface between two materials is investigated. The model describes the electrostatic potential generated by a vector of ion concentrations in a periodic…

Analysis of PDEs · Mathematics 2018-10-22 Klemens Fellner , Victor Kovtunenko

The accurate determination of electron properties is fundamental to low-temperature plasma simulations, necessitating precise solutions to the spatially inhomogeneous electron Boltzmann equation (EBE). This work explores the use of…

Plasma Physics · Physics 2026-05-07 Ihda Chaerony Siffa , Detlef Loffhagen , Markus M. Becker , Jan Trieschmann

The computational study of chemical reactions in complex, wet environments is critical for applications in many fields. It is often essential to study chemical reactions in the presence of applied electrochemical potentials, taking into…

Materials Science · Physics 2016-01-20 G. Fisicaro , L. Genovese , O. Andreussi , N. Marzari , S. Goedecker

This paper develops a computational framework with unfitted meshes to solve linear piezoelectricity and flexoelectricity electromechanical boundary value problems including strain gradient elasticity at infinitesimal strains. The high-order…

Numerical Analysis · Mathematics 2020-10-08 David Codony , Onofre Marco , Sonia Fernández-Méndez , Irene Arias

We present the open source distributed software package Poisson-Boltzmann Analytical Method (PB-AM), a fully analytical solution to the linearized Poisson Boltzmann equation, for molecules represented as non-overlapping spherical cavities.…

Biomolecules · Quantitative Biology 2016-09-27 Lisa E. Feldberg , David H. Brookes , Eng-Hui Yap , Elizabeth Jurrus , Nathan Baker , Teresa Head-Gordon

Understanding the behavior of biomolecules such as proteins requires understanding the critical influence of the surrounding fluid (solvent) environment--water with mobile salt ions such as sodium. Unfortunately, for many studies, fully…

Soft Condensed Matter · Physics 2015-05-27 J. P. Bardhan , D. A. Tejani , N. S. Wieckowski , A. Ramaswamy , M. G. Knepley

A Poisson-Boltzmann approach is used to determine the double-layer integral and differential capacitances in a finite-length situation for an electrolytic cell. By means of simple analytical calculations, it is shown how these quantities…

Statistical Mechanics · Physics 2012-04-03 Roberta Rarumy Ribeiro de Almeida , Luiz Roberto Evangelista , Giovanni Barbero

In this paper we present a fully deterministic method for the numerical solution to the Boltzmann equation of rarefied gas dynamics in a bounded domain for multi-scale problems. Periodic, specular reflection and diffusive boundary…

Numerical Analysis · Mathematics 2011-06-07 Francis Filbet

The Boltzmann equation describes the evolution of the phase-space probability distribution of classical particles under binary collisions. Approximations to it underlie the basis for several scholarly fields, including aerodynamics and…

Plasma Physics · Physics 2023-08-09 George J. Wilkie , Torsten Keßler , Sergej Rjasanow

We introduce the stochastic Boltzmann equation (SBE) as an approach for exploring the spin dynamics of magnetic molecules coupled to a stochastic environment. The SBE is a time-evolution equation for the probability density of the spin…

Materials Science · Physics 2016-03-15 Daniel M. Packwood , Helmut G. Katzgraber , Winfried Teizer

In a large variety of spectroscopical applications Bloch-Boltzmann equations (BBE) play an essential role. They describe the evolution of the reduced density operator of an active atom which is coupled to radiation (Bloch part) and which…

Quantum Physics · Physics 2007-05-23 Stanislaw Kryszewski , Justyna Czechowska

In this paper we propose a nonlinear elasticity model of macromolecular conformational change (deformation) induced by electrostatic forces generated by an implicit solvation model. The Poisson-Boltzmann equation for the electrostatic…

Analysis of PDEs · Mathematics 2010-01-12 Yongcheng Zhou , Michael Holst , James Andrew McCammon

The energy functional, the governing partial differential equation(s) (PDE), and the boundary conditions need to be consistent with each other in a modeling system. In electrolyte solution study, people usually use a free energy form of an…

Soft Condensed Matter · Physics 2017-02-07 Xuejiao Liu , Yu Qiao , Benzhuo Lu

We present a 3D finite element solver for the nonlinear Poisson-Nernst-Planck (PNP) equations for electrodiffusion, coupled to the Stokes system of fluid dynamics. The model serves as a building block for the simulation of macromolecule…

Computational Physics · Physics 2017-04-05 Gregor Mitscha-Baude , Andreas Buttinger-Kreuzhuber , Gerhard Tulzer , Clemens Heitzinger

Many physical problems can be modelled by partial differential equations on unknown domains. Several examples can easily be found in the dynamics of free interfaces in fluid dynamics, solid mechanics or in fluid-solid interactions. To solve…

Numerical Analysis · Mathematics 2018-10-25 Javier Rivero-Rodriguez , Miguel Perez-Saborid , Benoit Scheid

Although quant mech is linear, there are nevertheless quant sys with multiple interacting particles in which the effective evo of a single particle is governed by a nonlinear eq. This includes Bose-Einstein condensates, which are gov by the…

Quantum Physics · Physics 2015-06-16 Thomas G. Wong