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Most next-generation Li-ion battery chemistries require a functioning lithium metal (Li) anode. However, its application in secondary batteries has been inhibited because of uncontrollable dendrite growth during cycling. Mechanical…

Materials Science · Physics 2017-01-11 Chen Xu , Zeeshan Ahmad , Asghar Aryanfar , Venkatasubramanian Viswanathan , Julia R. Greer

Predicting the compositional phase stability of strongly correlated electron materials is an outstanding challenge in condensed matter physics. In this work, we employ the DFT+U formalism to address the effects of local correlations due to…

Strongly Correlated Electrons · Physics 2017-02-01 Eric B. Isaacs , Chris A. Marianetti

Spinel Li$_x$Mn$_2$O$_4$ is a key cathode material that is used extensively in commercial Li-ion batteries. A challenge with this material has been that the capacity of the battery fades with cycling, an effect that can be traced to the…

Nowdays, multiferroic materials with magnetoelectric coupling have many real-world applications in the fields of novel memory devices. It is challenging is to create multiferroic materials with strongly coupled ferroelectric and…

Materials Science · Physics 2018-05-29 Deobrat Singh , Sanjeev K. Gupta , Haiying He , Yogesh Sonvane

Following the successful utilization of LiFePO4 as a novel cathode material for rechargeable lithium batteries, interest and efforts have grown in the research of another olivine structured material LiMnPO4 due to its higher operating…

High performance lead-free multiferroic composites are desired to replace the lead-based ceramics in multifunctional devices applications. Laminated compounds were prepared from ferroelectric and ferromagnetic materials. In this work, we…

We show the effect of composition on structural and magnetic characteristics of pure phase polycrystalline Ga<2-x>Fe<x>O<3> (GFO) for compositions between 0.8 <= x <= 1.3. X-ray analysis reveals that lattice parameters of GFO exhibit a…

Materials Science · Physics 2013-08-01 Somdutta Mukherjee , Vishal Ranjan , Rajeev Gupta , Ashish Garg

Context: Lithium is a fragile element, which is easily destroyed in the stellar interior. The existence of lithium-rich giants still represents a challenge for stellar evolution models. Aims: We have collected a large database of…

Solar and Stellar Astrophysics · Physics 2015-05-27 L. Monaco , S. Villanova , C. Moni Bidin , G. Carraro , D. Geisler , P. Bonifacio , O. A. Gonzalez , M. Zoccali , L. Jilkova

Lithium metal batteries (LMBs), when coupled with a localized high-concentration electrolyte and a high-voltage nickel-rich cathode, offer a solution to the increasing demand for high energy density and long cycle life. However, the…

Materials Science · Physics 2024-01-12 Tao Meng , Shanshan Yang , Yitong Peng , Xiwei Lan , Pingan Li , Kangjia Hu , Xianluo Hu

Key to advancing lithium-ion battery technology, and in particular fast charging capabilities, is our ability to follow and understand the dynamic processes occurring in operating materials under realistic conditions, in real time, and on…

Materials Science · Physics 2021-06-28 Alice J. Merryweather , Christoph Schnedermann , Quentin Jacquet , Clare P. Grey , Akshay Rao

Next generation batteries based on lithium (Li) metal anodes have been plagued by the dendritic electrodeposition of Li metal on the anode during cycling, resulting in short circuit and capacity loss. Suppression of dendritic growth through…

The existing solid electrolytes for lithium ion batteries suffer from low total ionic conductivity, which restricts its usefulness for the lithium-ion battery technology. Among them, the NASICON-based materials, such as…

Chemical Physics · Physics 2020-08-03 K. Kwatek , W. Ślubowska , J. Trébosc , O. Lafon , J. L. Nowiński

We construct a phase diagram of the parent compound Fe1+xTe as a function of interstitial iron x in terms of the electronic, structural, and magnetic properties. For a concentration of x < 10%, Fe1+xTe undergoes a "semimetal" to metal…

Strongly Correlated Electrons · Physics 2015-06-17 E. E. Rodriguez , D. A. Sokolov , C. Stock , M. A. Green , O. Sobolev , J. A. Rodriguez-Rivera , H. Cao , A. Daoud-Aladine

We present an x-ray absorption study of the oxidation states of transition-metal-ions of LiMnO2 and its related materials, widely used as cathodes in Li-ion batteries. The comparison between the obtained spectrum and the…

Materials Science · Physics 2010-07-15 H. Wadati , D. G. Hawthorn , T. Z. Regier , G. Chen , T. Hitosugi , T. Mizokawa , A. Tanaka , G. A. Sawatzky

Crack growth in lithium-ion battery electrodes is typically detrimental and undesirable. However, recent experiments suggest that stabilized fracture of cathode active materials in liquid electrolytes can increase electrochemically active…

Lithium-intercalated layered transition-metal oxides, LixTMO2, brought about a paradigm change in rechargeable batteries in recent decades and show promise for use in memristors, a type of device for future neural computing and on-chip…

Materials Science · Physics 2021-05-31 Tianli Feng , Andrew O'Hara , Sokrates T. Pantelides

Novel imaging spin-filter techniques, which are based on low energy electron diffraction, are currently of high scientific interest. To improve the spin-detection efficiency a variety of new materials have been introduced in recent years. A…

Computational Physics · Physics 2015-11-18 Stephan Borek , Jürgen Braun , Hubert Ebert , Ján Minár

Multiferroic materials have driven significant research interest due to their promising technological potential. Developing new room-temperature multiferroics and understanding their fundamental properties are important to reveal…

Nickelate materials offer diverse functionalities for energy and computing applications. Lithium nickel oxide (LiNiO$_2$) is an archetypal layered nickelate, but the electronic structure of this correlated material is not yet fully…

Solid electrolytes for solid-state Li-ion batteries are stimulating considerable interest for next-generation energy storage applications. The Li$_7$La$_3$Zr$_2$O$_{12}$ garnet-type solid electrolyte has received appreciable attention as a…

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