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In this study, we have delineated the preparation and influence of Fe doping on microstructural and optical properties of the pristine and Fe incorporated TiO$_2$ thin film with different Fe concentrations (0, 2, 4, 6, and 8 at.% ). The…

Applied Physics · Physics 2021-03-08 Tapash Chandra Paul , Jiban Podder , Lincoln Paik

We report detailed magnetometry and high-frequency electron spin resonance (HF-ESR) measurements which allow detailed investigation on Li-Fe antisite disorder in single-crystalline LiFePO$_4$, i.e., exchange of Fe$^{2+}$- and Li$^+$-ions.…

Materials Science · Physics 2020-12-17 J. Werner , C. Neef , C. Koo , S. Zvyagin , A. Ponomaryov , R. Klingeler

Layered LiMO2 (M = Ni, Co, Mn, and Al mixture) cathode materials used for Li-ion batteries are reputed to be highly reactive through their surface, where the chemistry changes rapidly when exposed to ambient air. However, conventional…

Lithium (Li) is a prototypical simple metal at ambient conditions, but exhibits remarkable changes in structural and electronic properties under compression. There has been intense debate about the structure of dense Li, and recent…

Materials Science · Physics 2023-06-21 Xiaoyang Wang , Zhenyu Wang , Pengyue Gao , Chengqian Zhang , Jian Lv , Han Wang , Haifeng Liu , Yanchao Wang , Yanming Ma

Lithium iron phosphate (LiFePO$_4$) is the prototypical two-phase battery material, whose complex patterns of lithium ion intercalation provide a testing ground for theories of electrochemical thermodynamics. Using a depth-averaged (a-b…

Chemical Physics · Physics 2018-08-21 Daniel A. Cogswell , Martin Z. Bazant

We present the technology of obtaining and the electrophysical properties of a multicomponent material 0.61PMN-0.20PT-0.09PS-0.1PFN:Li (PMN-PT-PS-PFN:Li). The addition of PFN into PMN-PT decreases the temperature of final sintering which is…

Materials Science · Physics 2013-09-25 R. Skulski , D. Bochenek , P. Niemiec , P. Wawrzała , J. Suchanicz

Understanding (de)lithiation heterogeneities in battery materials is key to ensuring optimal electrochemical performance and developing better energy storage devices. However, this remains challenging due to the complex three dimensional…

Effective passivation of lithium metal surfaces, and prevention of battery-shorting lithium dendrite growth, are critical for implementing lithium-metal-anodes for batteries with increased power densities. Nanoscale surface heterogeneities…

Materials Science · Physics 2017-10-03 Kevin Leung , Katherine L. Jungjohann

The lithium (Li) metal anode is essential for next generation high energy density rechargeable Li metal batteries. Although extensive studies have been performed to prolong the cycle life of Li metal batteries, the calendar life, which…

Materials Science · Physics 2022-04-26 Bingyu Lu , Weikang Li , Diyi Cheng , Miguel Ceja , Wurigumula Bao , Chengcheng Fang , Ying Shirley Meng

To unlock the full potential of lithium metal batteries, a deep understanding of lithium metal reactivity and its solid electrolyte interphase is essential. Correlative imaging, combining focused ion beam and electron microscopy offers a…

Despite being the major cause of battery safety issues and detrimental performance, a comprehensive growth mechanism for metallic lithium deposited at electrode surfaces in lithium metal batteries remains elusive. While lithium surface…

Materials Science · Physics 2023-04-05 Christophe Didier , Elliot P. Gilbert , Jitendra Mata , Vanessa Peterson

Metal components are extensively used as current collectors, anodes, and interlayers in lithium-ion batteries. Integrating these functions into one component enhances the cell energy density and simplifies its design. However, this…

The discovery of the Spite plateau in the abundances of 7Li for metal-poor stars led to the determination of an observationally deduced primordial lithium abundance. However, after the success of the Wilkinson Microwave Anisotropy Probe…

Astrophysics · Physics 2009-11-13 A. Hosford , S. G. Ryan , A. E. Garcia Perez , J. E. Norris , K. A. Olive

During the past decade, CoFe2O4 (hard)/Co-Fe alloy (soft) magnetic nanocomposites have been routinely prepared by partial reduction of CoFe2O4 nanoparticles. Monoxide (i.e., FeO or CoO) has often been detected as a byproduct of the…

Despite decades of study, the identity of the dominant \ce{Li+}-conducting phase within the inorganic SEI of Li-ion batteries remains unresolved. While the mosaic model describes LiF/\ce{Li2O}/\ce{Li2CO3} nanocrystallites within a…

Materials Science · Physics 2025-12-16 Peichen Zhong , Kristin A. Persson

In the search for improved permanent magnets, fueled by the geostrategic and environmental issues associated with rare-earth-based magnets, magnetically hard (high anisotropy)-soft (high magnetization) composite magnets hold promise as…

The morphologies of crystalline lithium peroxide (Li2O2) discharge products in Li-O2 batteries have been shown to exhibit a dependency on subtle variations within the battery cell-operating environment including exposure to ambient air,…

Materials Science · Physics 2016-06-22 Hariharan Katharajan , Kumar Virwani , A. David Erpelding , Jeannette M. Garcia

Muon spin relaxation measurements are reported on three members of the LixMPO4 series. The magnetic properties of stoichiometric samples with M = Ni, Co, Fe, were investigated at low-temperature. In LiNiPO4 we observe different forms of the…

Strongly Correlated Electrons · Physics 2013-05-29 P. J. Baker , I. Franke , F. L. Pratt , T. Lancaster , D. Prabhakaran , W. Hayes , S. J. Blundell

Non-destructive characterization of lithium-ion batteries provides critical insights for optimizing performance and lifespan while preserving structural integrity. Optimizing electrolyte design in commercial LIBs requires consideration of…

A Li-conversion alpha-Fe2O3@C nanocomposite anode and a high-voltage LiNi0.5Mn1.5O4 cathode are synthesized in parallel, characterized, and combined in a Li-ion battery. alpha-Fe2O3@C is prepared via annealing of maghemite iron oxide and…

Chemical Physics · Physics 2021-10-27 Shuangying Wei , Daniele Di Lecce , Riccardo Messini D'Agostini , Jusef Hassoun