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We present a survey of the ortho-H2D+(1_{1,0}-1_{1,1}) line toward a sample of 10 starless cores and 6 protostellar cores, carried out at the Caltech Submillimeter Observatory. The high diagnostic power of this line is revealed for the…

Methanol and its precursor formaldehyde are among the most studied organic molecules in the interstellar medium and are abundant in the gaseous and solid phases. We recently developed a model to simulate CO hydrogenation via H atoms on…

Astrophysics of Galaxies · Physics 2015-05-14 H. M. Cuppen , E. F. van Dishoeck , E. Herbst , A. G. G. M. Tielens

IRAS 16293-2422 is a well studied low-mass protostar characterized by a strong level of deuterium fractionation. In the line of sight of the protostellar envelope, an additional absorption layer, rich in singly and doubly deuterated water…

Astrophysics of Galaxies · Physics 2014-10-24 V. Wakelam , C. Vastel , Y. Aikawa , A. Coutens , S. Bottinelli , E. Caux

We report a new detection of neutral deuterium in the sub Damped Lyman Alpha system with low metallicity [O/H]\,=\,$-2.042 \pm 0.005$ at $z_{\rm abs}=2.437$ towards QSO~J\,1444$+$2919. The hydrogen column density in this system is…

Astrophysics of Galaxies · Physics 2016-04-06 S. A. Balashev , E. O. Zavarygin , A. V. Ivanchik , K. N. Telikova , D. A. Varshalovich

We have detected new HD absorption systems at high redshifts, z_abs=2.626 and z_abs=1.777, identified in the spectra of the quasars J0812+3208 and Q1331+170, respectively. Each of these systems consists of two subsystems. The HD column…

Cosmology and Nongalactic Astrophysics · Physics 2010-09-22 S. A. Balashev , A. V. Ivanchik , D. A. Varshalovich

We report the detection of H2CO (formaldehyde) around the carbon-rich AGB star, IRC+10216. We find a fractional abundance with respect to molecular hydrogen of x(H2CO)= (1.3 {+1.5}{-0.8}) x 10^{-8}. This corresponds to a formaldehyde…

Astrophysics · Physics 2009-11-10 K. E. Saavik Ford , David A. Neufeld , Peter Schilke , Gary J. Melnick

Deuterium fractionation is considered as an important process to infer the chemical ages of prestellar cores in filaments. We present here the first magneto-hydrodynamical simulations including a chemical network to study deuterium…

Molecular deuteration is commonly seen in starless cores and is expected to occur on a timescale comparable to that of the core contraction. Thus, the deuteration serves as a chemical clock, allowing us to investigate dynamical theories of…

Astrophysics of Galaxies · Physics 2024-08-14 Sheng-Jun Lin , Shih-Ping Lai , Laurent Pagani , Charlène Lefèvre , Travis J. Thieme

Despite low elemental abundance of atomic deuterium in interstellar medium (ISM), observational evidences suggest that several species in gas-phase and in ices could be heavily fractionated. We explore various aspects of deuterium…

Astrophysics of Galaxies · Physics 2019-02-05 Ankan Das , Liton Majumdar , Sandip K. Chakrabarti , Dipen Sahu

Primordial abundances of light elements are sensitive to the physics of the early Universe and can directly constrain cosmological quantities, such as the baryon-to-photon ratio $\eta_{10}$, the baryon density and the number of neutrino…

The results of single-dish observations of low- and high-J transitions of selected molecules from protoplanetary disks around two TTauri stars (LkCa15 and TWHya) and two HerbigAe stars (HD163296 and MWC480) are reported. Simple molecules…

Astrophysics · Physics 2011-07-18 Wing-Fai Thi , Gerd-Jan van Zadelhoff , Ewine F. van Dishoeck

Aims. We aim to improve a previous model for the prediction of column densities and deuterium fractions of non- and singly deuterated methanol. Thereby, we try to identify crucial chemical and physical parameters, for which the study of…

Astrophysics of Galaxies · Physics 2023-12-20 W. Riedel , O. Sipilä , E. Redaelli , P. Caselli , A. I. Vasyunin , F. Dulieu , N. Watanabe

The ALMA interferometer, with its unprecedented combination of high-sensitivity and high-angular resolution, allows for (sub-)mm wavelength mapping of protostellar systems at Solar System scales. Astrochemistry has benefited from imaging…

While the abundance of elemental deuterium is relatively low (D/H ~ a few 1E-5), orders of magnitude higher D/H abundance ratios have been found for many interstellar molecules, enhanced by deuterium fractionation. In cold molecular clouds…

Astrophysics of Galaxies · Physics 2023-07-05 Arshia M. Jacob , Karl M. Menten , Friedrich Wyrowski , Olli Sipilä

Context: In the centre of pre-stellar cores, the deuterium fractionation is enhanced due to the cold temperatures and high densities. Therefore, the chemistry of deuterated molecules can be used to probe the evolution and the kinematics in…

Astrophysics of Galaxies · Physics 2022-08-24 K. Giers , S. Spezzano , F. Alves , P. Caselli , E. Redaelli , O. Sipilä , M. Ben Khalifa , L. Wiesenfeld , S. Brünken , L. Bizzocchi

Extremely large deuteration of several molecules has been observed towards prestellar cores and low-mass protostars for a decade. New observations performed towards low-mass protostars suggest that water presents a lower deuteration in the…

Astrophysics of Galaxies · Physics 2015-06-19 Vianney Taquet , Steven B. Charnley , Olli Sipilä

We present ground-based 2.1 to 4.2 microns observations of four low-mass protostars. We searched for the 4.1 microns OD stretch band, characteristic of solid HDO in grain mantles. We did not detect solid HDO in any of the four sources, but…

Astrophysics · Physics 2009-11-10 B. Parise , T. Simon , E. Caux , E. Dartois , C. Ceccarelli , J. Rayner , A. G. G. M. Tielens

Water is an important molecule in the chemical and thermal balance of dense molecular gas, but knowing its history through-out the various stages of the star formation is a fundamental problem. Its molecular deuteration provides us with a…

Solar and Stellar Astrophysics · Physics 2015-12-16 David Quénard , Vianney Taquet , Charlotte Vastel , Paola Caselli , Cecilia Ceccarelli

Primordial evaluations of the deuterium abundance should provide one of the best tests of Big Bang nucleosynthesis models. Space as well as ground based observations seem however to result in different values. This asks for more…

Astrophysics · Physics 2016-11-03 A. Vidal-Madjar

We present constraints on the deuterium to hydrogen ratio (D/H) in the metal-poor gas cloud at redshift $z=0.701$ towards QSO 1718+4807. We use new Keck spectra in addition to Hubble Space Telescope (HST) and International Ultraviolet…

Astrophysics · Physics 2009-10-31 David Tytler , Scott Burles , Limin Lu , Xiao-Ming Fan , Arthur Wolfe , Blair D. Savage