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We present N2D+ 3-2 (IRAM) and H2D+ 1_11 - 1_10 and N2H+ 4-3 (JCMT) maps of the small cluster-forming Ophiuchus B2 core in the nearby Ophiuchus molecular cloud. In conjunction with previously published N2H+ 1-0 observations, the N2D+ data…
Observations of deuterated species are useful in probing the temperature, ionization level, evolutionary stage, chemistry, and thermal history of astrophysical environments. The analysis of data from ALMA and other new telescopes requires…
Clouds of high infrared extinction are promising sites of massive star/cluster formation. A large number of cloud cores discovered in recent years allows investigation of possible evolutionary sequence among cores in early phases. We have…
Prestellar cores are unique laboratories for studies of the chemical and physical conditions preceding star formation. We observed the prestellar core L1544 in the fundamental transition of ortho-H2D+ (1_1,0-1_1,1) at different positions…
Deuterium fractionation is known to enhance the [DCO+]/[HCO+] abundance ratio over the D/H elemental ratio of about 1e-5 in the cold and dense gas typically found in pre-stellar cores. We report the first detection and mapping of very…
Deuteration is a crucial tool to understand the complexity of interstellar chemical processes, especially when they involve the interplay of gas-phase and grain-surface chemistry. In the case of multiple deuteration, comparing observation…
We have observed the J=3-2 transition of N2H+ and N2D+ to investigate the trend of deuterium fractionation with evolutionary stage in three selected regions in the Infrared Dark Cloud (IRDC) G28.34+0.06 with the Submillimeter Telescope…
Deuterium fractionation provides a key diagnostic of the physical and chemical evolution of prestellar and protostellar cores, where it is strongly linked to CO depletion in cold, dense gas. We present the first spatially resolved maps of…
Deuterium fractionation provides a window to the thermal history of volatiles in the solar system and protoplanetary disks. While evidence of active molecular deuteration has been observed towards a handful of disks, it remains unclear…
We present observations of HDCO and H2CO emission toward a sample of 15 Class 0 protostars in the Orion A and B clouds. Of these, eleven protostars are Herschel-identified PACS Bright Red Sources (PBRS) and four are previously identified…
Prestellar cores represent the initial conditions of star formation, but heavy molecules such as CO are strongly depleted in their cold, dense interiors, limiting the ability to probe core centers. Deuterated molecular ions therefore emerge…
The deuterium enrichment of molecules is sensitive to their formation environment. Constraining patterns of deuterium chemistry in protoplanetary disks is therefore useful for probing how material is inherited or reprocessed throughout the…
Observations of star forming environments revealed that the abundances of some deuterated interstellar molecules are markedly larger than the cosmic D/H ratio of 10-5. Possible reasons for this pointed to grain surface chemistry. How- ever,…
The chemical evolution in high-mass star-forming regions is still poorly constrained. Studying the evolution of deuterated molecules allows to differentiate between subsequent stages of high-mass star formation regions due to the strong…
We report the detection of D2CO in a sample of starless dense cores, in which we previously measured the degree of CO depletion. The deuterium fractionation is found extremely high, [D2CO]/[H2CO] ~ 1-10 %, similar to that reported in…
We investigate deuterium chemistry coupled with the nuclear spin-state chemistry of H$_2$ and H$_3^+$ in protoplanetary disks. Multiple paths of deuterium fractionation are found; exchange reactions with D atoms, such as HCO$^+$ + D, are…
In this work, we study deuterium fractionation in four starless cores in the low-mass star-forming region L1688 in the Ophiuchus molecular cloud. We study how the deuterium fraction ($R_D$) changes with environment, compare deuteration of…
Understanding gas-grain chemistry of deuterium in star-forming objects may help to explain their history and present state. We aim to clarify how processes in ices affect the deuterium fractionation. In this regard, we investigate a…
iCOMs are species commonly found in the interstellar medium. They are believed to be crucial seed species for the build-up of chemical complexity in star forming regions as well as our own Solar System. Thus, understanding how their…
With a goal toward deriving the physical conditions in external galaxies, we present a survey of the formaldehyde emission in a sample of starburst systems. By extending a technique used to derive the spatial density in star formation…