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An explanation is provided for the ultrafast photo-excited electron dynamics in low-spin Ruthenium (II) organic complexes. The experimentally-observed singlet to triplet decay in the metal-to-ligand charge-transfer (MLCT) states contradicts…

Strongly Correlated Electrons · Physics 2012-10-31 Jun Chang , A. J. Fedro , Michel van Veenendaal

Experiments on superconducting materials have unveiled unique emergent properties when they are driven far from equilibrium. However, a quantitative first-principles treatment that describes experimental observations is lacking. In this…

Ultracold metastable RbCs molecules are observed in a double species MOT through photoassociation near the Rb(5S$_{1/2}$)+Cs(6P$_{3/2}$) dissociation limit followed by radiative stabilization. The molecules are formed in their lowest…

Atomic Physics · Physics 2017-09-13 C. Gabbanini , O. Dulieu

The discovery of infinite-layer nickelate superconductors has spurred enormous interest. While the Ni$^{1+}$ cations possess nominally the same 3$d^9$ configuration as Cu$^{2+}$ in cuprates, the electronic structure variances remain…

P-dibromobenzene nanoparticles in a case of paradihlorbenzol molecules have been synthesized. Raman spectrums of these nanoparticles are measured. At diffusion of molecules of paradihlorbenzol in a pdibromobenzene nanoparticle solid…

Mesoscale and Nanoscale Physics · Physics 2009-10-21 M. A. Korshunov

Photodissociation of a molecule produces a spatial distribution of photofragments determined by the molecular structure and the characteristics of the dissociating light. Performing this basic chemical reaction at ultracold temperatures…

Atomic Physics · Physics 2018-01-24 M. McDonald , I. Majewska , C. -H. Lee , S. S. Kondov , B. H. McGuyer , R. Moszynski , T. Zelevinsky

To simulate a 200 nm photoexcitation in cyclobutanone to the n-3s Rydberg state, classical trajectories were excited from a Wigner distribution to the singlet state manifold based on excitation energies and oscillator strenghts. Twelve…

The elemental Nb is mainly investigated for its eminent superconducting properties. In contrary, we report of a relatively unexplored property, namely, its superior optoelectronic property in reduced dimension. We demonstrate here that…

The photothermal heterodyne imaging technique enabled studies of individual weakly absorbing nano-objects in various environments. It uses a photo-induced change in the refractive index of the environment. Taking advantage of the dramatic…

Accurate temperature measurement at the nanoscale is crucial for thermal management in next-generation microelectronic devices. Existing optical and scanning-probe thermometry techniques face limitations in spatial resolution, accuracy, or…

Time- and angle-resolved photoemission spectroscopy (TrARPES) is a powerful technique for capturing the ultrafast dynamics of charge carriers and revealing photo-induced phase transitions in quantum materials. However, the lack of widely…

Mesoscale and Nanoscale Physics · Physics 2022-01-05 Changhua Bao , Haoyuan Zhong , Shaohua Zhou , Runfa Feng , Yuan Wang , Shuyun Zhou

The ground and excited state electronic structure of the molecular photoswitches quadricyclane and norbornadiene is examined qualitatively and quantitatively. A new custom basis set is introduced, optimised for efficient yet accurate…

Chemical Physics · Physics 2025-10-07 Joseph C. Cooper , Adam Kirrander

We investigate the dynamics of molecular photoexcitation by unchirped femtosecond laser pulses using RbCs as a model system. This study is motivated by a goal of optimizing a two-color scheme of transferring vibrationally-excited ultracold…

Atomic Physics · Physics 2015-06-04 B. E. Londono , A. Derevianko , J. E. Mahecha , A. Crubellier , E. Luc-Koenig

Excitons diffusing to a charge-separating interface is a necessary step to convert energy into current in next-generation photovoltaics. In this report, made possible by a new ultrafast spectrometer design, we compare exciton dynamics…

The element specificity of soft X-ray spectroscopy makes it an ideal tool for analyzing the microscopic origin of ultrafast dynamics induced by localized optical excitation in metal-insulator heterostructures. Using [Fe/MgO]$_n$ as a model…

We report on noise and thermal conductance measurements taken in order to determine an upper bound on the performance of graphene as a terahertz photon detector. The main mechanism for sensitive terahertz detection in graphene is bolometric…

Mesoscale and Nanoscale Physics · Physics 2014-04-07 Christopher B. McKitterick , Heli Vora , Xu Du , Boris S. Karasik , Daniel E. Prober

Understanding the nature of the photoexcitation and ultrafast charge dynamics pathways in organic halide perovskite nanocubes and their aggregation into superlattices is key for the potential applications as tunable light emitters, photon…

Charge excitations across an electronic band gap play an important role in opto-electronics and light harvesting. In contrast to conventional semiconductors, studies of above-band-gap photoexcitations in strongly correlated materials are…

Pump-push-probe spectroscopy was employed for the exploration of charge-separation processes in organic photovoltaic blends as well as for proton-coupled electron-transfer (PCET) reactions in hydrogen-bonded complexes of…

Chemical Physics · Physics 2025-05-07 Sebastian V. Pios , Maxim F. Gelin , Wolfgang Domcke , Lipeng Chen

The development of many optical quantum technologies depends on the availability of solid-state single quantum emitters with near-perfect optical coherence. However, a standing issue that limits systematic improvement is the significant…