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Observation of the Accelerated Diffusion in Nanoparticles of Paradibromobenzene /Paradihlorbenzene Solid Solution

Mesoscale and Nanoscale Physics 2009-10-21 v1 Materials Science

Abstract

P-dibromobenzene nanoparticles in a case of paradihlorbenzol molecules have been synthesized. Raman spectrums of these nanoparticles are measured. At diffusion of molecules of paradihlorbenzol in a pdibromobenzene nanoparticle solid solution formed. Modifications in structure of nanoparticles at diffusion are reflected in Raman spectrums. Unlike a solid solution single crystal, in nanoparticles the accelerated diffusion, D=1.3±0.021011cm2/sD = 1.3 \pm 0.02 10^{-11} cm^2/s, is observed at room temperature. Calculations show that the accelerated diffusion is caused by magnification of parametres of a lattice at reduction of sizes of nanoparticles.

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Cite

@article{arxiv.0910.3707,
  title  = {Observation of the Accelerated Diffusion in Nanoparticles of Paradibromobenzene /Paradihlorbenzene Solid Solution},
  author = {M. A. Korshunov},
  journal= {arXiv preprint arXiv:0910.3707},
  year   = {2009}
}

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3 pages