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Atomistic density functional theory (DFT) calculations of the capacitance between a metallic cylindric gate and a carbon nanotube (CNT) are reported. Results stressing the predominant effect of quantum capacitance in limiting or even…

Mesoscale and Nanoscale Physics · Physics 2007-05-23 L. Latessa , A. Pecchia , A. Di Carlo , P. Lugli

For a capacitor made of a semiconducting carbon nanotube (CNT) suspended above a metallic gate, Coulomb correlations between individual electrons can lead to a capacitance that is much larger than the geometric capacitance. We argue that…

Strongly Correlated Electrons · Physics 2015-04-22 Han Fu , B. I. Shklovskii , Brian Skinner

Recent advances in nanotechnology have provided new materials which have the potential to surpass copper and aluminum alloys in electrical conductivity, weight and ampacity [2-6]. Among these carbon nanotubes (CNTs) stand out due to their…

Applied Physics · Physics 2020-08-28 Farhad Daneshvar , Hung-Jue Sue

We explore the electric-field effect of carbon nanotubes (NTs) in electrolytes. Due to the large gate capacitance, Fermi energy shifts of order +/- 1 V can be induced, enabling to tune NTs from p to n-type. Consequently, large resistance…

Mesoscale and Nanoscale Physics · Physics 2016-08-31 M. Krueger , M. R. Buitelaar , T. Nussbaumer , C. Schoenenberger , L. Forro

In this work, we investigate the electrical conductivity of carbon nanotubes (CNTs), with a particular focus on the effects of doping. Using a first-principles approach, we study the electronic structure, phonon dispersion, and…

Materials Science · Physics 2024-08-07 Mina Yoon , German D. Samolyuk , Kai Li , James A. Hayne , Tolga Aytug

The conductivity of carbon nanotube (CNT) networks can be improved markedly by doping with nitric acid. In the present work, CNTs and junctions of CNTs functionalized with NO$_3$ molecules are investigated to understand the microscopic…

Applied Physics · Physics 2018-03-21 T. Ketolainen , V. Havu , E. Ö. Jónsson , M. J. Puska

The equilibrium density of fluids under nanoconfinement can differ substantially from their bulk density. Using a mean-field approach to describe the energetic landscape near the carbon nanotube (CNT) wall, we obtain analytical results…

Fluid Dynamics · Physics 2015-06-11 Gerald J. Wang , Nicolas G. Hadjiconstantinou

The electrostatic coupling between singled-walled carbon nanotube (SWNT) networks/arrays and planar gate electrodes in thin-film transistors (TFTs) is analyzed both in the quantum limit with an analytical model and in the classical limit…

Materials Science · Physics 2010-01-12 Qing Cao , Minggang Xia , Coskun Kocabas , Moonsub Shim , John A. Rogers , Slava V. Rotkin

We use space-charge (SC) theory (also called the capillary pore model) to describe the ionic conductance, $G$, of charged carbon nanotubes (CNTs). Based on the reversible adsorption of hydroxyl ions to CNT pore walls, we use a Langmuir…

Chemical Physics · Physics 2019-12-24 P. M. Biesheuvel , M. Z. Bazant

The performance of carbon nanotube (CNT) cables, a contender for copper-wire replacement, is tied to its metallic and semi-conducting-like conductivity responses with temperature; the origin of the semi-conducting-like response however is…

Carbon nanotube fibers are materials with an exceptional combination of properties, including higher toughness than carbon fibers, electrical conductivity above metals, large specific surface area (250 $\frac{m^2}{g}$) and high…

Applied Physics · Physics 2019-02-20 Belén Alemán , María Vila , Juan J. Vilatela

We report a measurement on quantum capacitance of individual semiconducting and small band gap SWNTs. The observed quantum capacitance is remarkably smaller than that originating from density of states and it implies a strong electron…

Mesoscale and Nanoscale Physics · Physics 2010-06-04 Junfeng Dai , Jun Li , Hualing Zeng , Xiaodong Cui

We study transport through multiply coupled carbon nano-tubes (quantum wires) and compute the conductances through the two wires as a function of the two gate voltages $g_1$ and $g_2$ controlling the chemical potential of the electrons in…

Mesoscale and Nanoscale Physics · Physics 2007-12-03 Sourin Das , Sumathi Rao

Carbon nanotubes (CTNs) with large aspect-ratios are extensively used to establish electrical connectedness in polymer melts at very low CNT loadings. However, the CNT size polydispersity and the quality of the dispersion are still not…

Materials Science · Physics 2017-10-10 Maryam Majidian , Claudio Grimaldi , László Forró , Arnaud Magrez

Calculations of the conductance of a carbon nanotube (CNT)-molecule-CNT structure are in agreement with experimental measurements [1]. The features in the transmission correspond directly to the features of the isolated molecular orbitals.…

Other Condensed Matter · Physics 2015-05-13 Nicolas A. Bruque , M. K. Ashraf , Roger K. Lake

High-performance solution-processed short-channel carbon nanotube (CNT) thin film transistors (TFTs) are fabricated using densely aligned arrays of metallic CNTs (m-CNTs) as source and drain electrodes, and aligned arrays of semiconducting…

Mesoscale and Nanoscale Physics · Physics 2015-06-18 Biddut K. Sarker , Narae Kang , Saiful I. Khondaker

Nanopores made with low dimensional semiconducting materials, such as carbon nanotubes and graphene slit pores, are used in supercapacitors. In theories and simulations of their operation, it is often assumed that such pores screen ion-ion…

Materials Science · Physics 2017-01-24 Alpha A. Lee , Dominic Vella , Alain Goriely

The electrolysis of CO$_2$ in molten carbonate has been introduced as an alternative mechanism to synthesize carbon nanomaterials inexpensively at high yield. Until recently, CO$_2$ was thought to be unreactive, making its removal a…

Materials Science · Physics 2022-01-21 Xinye Liu , Gad Licht , Xirui Wang , Stuart Licht

Water-flow in carbon nanotubes (CNT's) starkly contradicts classical fluid mechanics, with permeabilities that can exceed no-slip Haagen-Poiseuille predictions by two to five orders of magnitude. Semi-classical molecular dynamics accounts…

Materials Science · Physics 2022-07-27 Alberto Ambrosetti , Giorgio Palermo , Pier Luigi Silvestrelli

While it is well-known that electrode conductivity has a critical impact on rate-performance in battery electrodes, this relationship has been quantified only by computer simulations. Here we investigate the relationship between electrode…

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