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We present in full detail a newly developed formalism enabling density functional perturbation theory (DFPT) calculations from a DFT+$U$ ground state. The implementation includes ultrasoft pseudopotentials and is valid for both insulating…

Strongly Correlated Electrons · Physics 2020-02-21 Andrea Floris , Iurii Timrov , Burak Himmetoglu , Nicola Marzari , Stefano de Gironcoli , Matteo Cococcioni

We assess the performance of recent density functionals for the exchange-correlation energy of a nonmolecular solid, by applying accurate calculations with the GAUSSIAN, BAND, and VASP codes to a test set of 24 solid metals and non-metals.…

Recently, Tao and Mo proposed an accurate meta-generalized gradient approximation for the exchange-correlation energy. The exchange part is derived from the density matrix expansion, while the correlation part is obtained by improving the…

Chemical Physics · Physics 2017-10-11 Yuxiang Mo , Guocai Tian , Jianmin Tao

We have optimized the exponents of Gaussian s and p basis functions for the elements H, B-F, and Al-Cl using the pseudopotentials of Goedecker, Teter, and Hutter [Phys. Rev. B 54, 1703 (1996)] by minimizing the total energy of dimers. We…

Other Condensed Matter · Physics 2007-12-21 Eeuwe S. Zijlstra , Nils Hunteman , Alan Kalitsov , Martin E. Garcia , Ulf von Barth

Long-range corrected (LC) hybrid functionals and asymptotically corrected (AC) model potentials are two distinct density functional methods with correct asymptotic behavior. They are known to be accurate for properties that are sensitive to…

Chemical Physics · Physics 2017-09-13 Chen-Wei Tsai , Yu-Chuan Su , Guan-De Li , Jeng-Da Chai

Certain excitations, especially ones of long-range charge transfer character, are poorly described by time-dependent density functional theory (TDDFT) when typical (semi-)local functionals are used. A proper description of these excitations…

Chemical Physics · Physics 2018-08-01 J. Garhammer , F. Hofmann , R. Armiento , S. Kümmel

Recently, Tao and Mo (TM) proposed an accurate all-purpose nonempirical meta-generalized gradient approximation (meta-GGA). The exchange part was derived from the density matrix approximation, while the correlation part is based on a…

Materials Science · Physics 2017-06-28 Yuxiang Mo , Guocai Tian , Jianmin Tao

Accurate band gap prediction in semiconductors is crucial for materials science and semiconductor technology advancements. This paper extends the Perdew-Burke-Ernzerhof (PBE) functional for a wide range of semiconductors, tackling the…

Materials Science · Physics 2024-08-01 Satadeep Bhattacharjee , Namitha Anna Koshi , Seung-Cheol Lee

We investigate fundamental properties of meta-generalized-gradient approximations (meta-GGAs) to the exchange-correlation energy functional, which have an implicit density dependence via the Kohn-Sham kinetic-energy density. To this…

Chemical Physics · Physics 2014-12-10 F. G. Eich , Maria Hellgren

A revised version of the semilocal exchange-correlation functional [Phys. Rev. Lett. 117, 073001 (2016)] (TM) is proposed by incorporating the modifications to its correlation content obtained from the full high-density second-order…

Materials Science · Physics 2020-07-01 Subrata Jana , Kedar Sharma , Prasanjit Samal

We study the recently measured beta-decay of $^{70}$Kr into $^{70}$Br within the framework of the large-scale shell model. The enhancement in the Gamow-Teller (GT) transition strength in $^{70}$Br compared to the $\beta$-decay of the…

Nuclear Theory · Physics 2025-07-17 Priyanka Choudhary , Chong Qi

A simple, novel, non-empirical, constraint-based orbital-free generalized gradient approximation (GGA) non-interacting kinetic energy density functional is presented along with illustrative applications. The innovation is adaptation of…

Chemical Physics · Physics 2018-08-01 K. Luo , V. V. Karasiev , S. B. Trickey

Germanium manganese compounds exhibit a variety of stable and metastable phases with different stoichiometry. These materials entail interesting electronic, magnetic and thermal properties both in their bulk form and as heterostructures.…

We present non-linear corrections (NLC) to the distribution functions at low values of $x$ and $Q^{2}$ using the parametrization $F_{2}(x,Q^{2})$ and $F_{L}(x,Q^{2})$. We use a direct method to extract non-linear corrections to the ratio of…

High Energy Physics - Phenomenology · Physics 2021-10-11 G. R. Boroun , B. Rezaei

The increasing use of high-throughput density-functional theory (DFT) calculations in the computational design and optimization of materials requires the availability of a comprehensive set of soft and transferable pseudopotentials. Here we…

Materials Science · Physics 2013-12-10 Kevin F. Garrity , Joseph W. Bennett , Karin M. Rabe , David Vanderbilt

It is known that the adiabatic approximation in time-dependent density functional theory usually provides a good description of low-lying excitations of molecules. In the present work, the capability of the adiabatic nonempirical…

Materials Science · Physics 2009-11-13 Jianmin Tao , Sergei Tretiak , Jian-Xin Zhu

We extend the previously proposed one-parameter double-hybrid density-functional theory [K. Sharkas, J. Toulouse, and A. Savin, J. Chem. Phys. 134, 064113 (2011)] to meta-generalized-gradient-approximation (meta-GGA) exchange-correlation…

Chemical Physics · Physics 2014-02-27 Sidi Ould Souvi , Kamal Sharkas , Julien Toulouse

The comparison study of high pressure superconducting state of recently synthesized H$_3$S and PH$_3$ compounds are conducted within the framework of the strong-coupling theory. By generalization of the standard Eliashberg equations to…

Superconductivity · Physics 2017-07-05 Artur P. Durajski

We report quasiparticle-energy calculations of the electronic bandstructure as measured by valence-band photoemission for selected II-VI compounds and group-III-nitrides. By applying GW as perturbation to the ground state of the fictitious,…

Materials Science · Physics 2009-11-11 Patrick Rinke , Abdallah Qteish , Joerg Neugebauer , Christoph Freysoldt , Matthias Scheffler

Lattice thermal conductivity (TC) of semiconductors is crucial for various applications, ranging from microelectronics to thermoelectrics. Data-driven approach can potentially establish the critical composition-property relationship needed…

Materials Science · Physics 2022-08-30 Zeyu Liu , Meng Jiang , Tengfei Luo