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Recent high-pressure studies found that superconductivity can be achieved under very low pressure in the parent iron arsenide compound CaFe2As2, although details of the sharpness and temperature of transitions vary between liquid medium and…

Superconductivity · Physics 2009-11-13 W. Yu , A. A. Aczel , T. J. Williams , S. L. Bud'ko , N. Ni , P. C. Canfield , G. M. Luke

CaFe2As2 exhibits collapsed tetragonal (cT) structure and varied exotic behavior under pressure at low temperatures that led to debate on linking the structural changes to its exceptional electronic properties like superconductivity,…

Superconductivity · Physics 2017-12-12 Khadiza Ali , Kalobaran Maiti

We investigate the role of ligand states in the electronic properties of CaFe2As2 using high-resolution hard x-ray photoemission spectroscopy (HAXPES) at different sample temperatures. Experimental results indicate that the binding energy…

Superconductivity · Physics 2020-12-02 Ram Prakash Pandeya , Arindam Pramanik , A. Thamizhavel , Kalobaran Maiti

We have synthesized two iron-pnictide/chalcogenide materials, CuFeTe2 and Fe2As, which share crystallographic features with known iron-based superconductors, and carried out high-pressure electrical resistivity measurements on these…

At ambient pressure CaFe2As2 has been found to undergo a first order phase transition from a high temperature, tetragonal phase to a low temperature orthorhombic / antiferromagnetic phase upon cooling through T ~ 170 K. With the application…

Superconductivity in Iron-Arsenic based pnictides emerges in close proximity to an antiferromagnetic (AFM)ordered parent state and the AFM phase overlaps with superconducting (SC) phase in some pnictides for certain range of doping.…

Strongly Correlated Electrons · Physics 2015-01-20 Anirban Dutta , Neeraj Kumar , A. Thamizhavel , Anjan K. Gupta

The transient response of Ba(Fe(1-x)Co(x))2As2, x=0.08 was studied by pump-probe optical reflectivity. After ultrafast photoexcitation, hot electrons were found to relax with two different characteristic times, indicating the presence of…

We use angle-resolved photoemission spectroscopy (ARPES) to study the electronic properties of CaFe2As2 - parent compound of a pnictide superconductor. We find that the structural and magnetic transition is accompanied by a three- to…

We report synthesis, crystal structure and superconductivity in ThCr2Si2-type LaFe2As2 (La122). La122 was synthesized at 960{\deg}C for 1.5 h under a pressure of 3.4 GPa. An as-synthesized La122 (non-superconductor) had a collapsed…

Single-crystalline KFe2As2 and CaT2As2 (T = Fe, Co, Ni, Cu) are synthesized and investigated by resistivity, susceptibility and optical spectroscopy. It is found that CaCu2As2 exhibits a similar transition to the lattice abrupt collapse…

Superconductivity · Physics 2015-06-11 B. Cheng , B. F. Hu , R. Y. Chen , G. Xu , P. Zheng , J. L. Luo , N. L. Wang

From first principles calculations we unravel surprisingly strong interactions between arsenic ions in iron-pnictides, the strength of which is controlled by the Fe-spin state. Reducing the Fe-magnetic moment, weakens the Fe-As bonding, and…

Superconductivity · Physics 2009-02-19 T. Yildirim

Structural and electronic characterization of (Ca0.67Sr0.33)Fe2As2 has been performed as a func- tion of pressure up to 12 GPa using conventional and designer diamond anvil cells. The compound (Ca0.67Sr0.33)Fe2As2 behaves intermediate…

Superconductivity · Physics 2015-06-04 J. R. Jeffries , N. P. Butch , K. Kirshenbaum , S. R. Saha , S. T. Weir , Y. K. Vohra , J. Paglione

We report the effect of applied pressures on magnetic and superconducting order in single crystals of the aliovalent La-doped iron pnictide material Ca$_{1-x}$La$_{x}$Fe$_{2}$As$_{2}$. Using electrical transport, elastic neutron scattering…

We carried out combined transport and optical measurements for BaFe2As2 and five isostructural transition-metal (TM) pnictides. The low-energy optical conductivity spectra of these compounds are, to a good approximation, decomposed into a…

The tin-selenide and tin-sulfide classes of materials undergo multiple structural transitions under high pressure leading to periodic lattice distortions, superconductivity, and topologically non-trivial phases, yet a number of…

Materials Science · Physics 2020-10-23 Gyanu Prasad Kafle , Christoph Heil , Hari Paudyal , Elena R. Margine

Understanding the microscopic origins of electronic phases in high-transition temperature (high-Tc) superconductors is important for elucidating the mechanism of superconductivity. In the paramagnetic tetragonal phase of BaFe2-xTxAs2 (where…

Superconductivity · Physics 2014-08-13 Xingye Lu , J. T. Park , Rui Zhang , Huiqian Luo , Andriy H. Nevidomskyy , Qimiao Si , Pengcheng Dai

The temperature, field, and field-orientation dependences of the electronic specific heat Ce of the ironpnictide superconductor KFe2As2 have been investigated. Thermodynamic evidence of the presence of line nodes is obtained from the T and…

The magnetism of the second antiferromagnetic phase (AF2) arising in the iron-based LaFeAsO$_{1-x}$H$_{x}$ superconductor for $x\gtrsim0.4$ was investigated by muon spin rotation measurements under hydrostatic pressure up to 2.6 GPa. The…

Strongly Correlated Electrons · Physics 2020-05-13 M. Hiraishi , K. M. Kojima , H. Okabe , S. Takeshita , A. Koda , R. Kadono , R. Khasanov , S. Iimura , S. Matsuishi , H. Hosono

The Fe-based superconducting KxFe2-ySe2 (0.6 {\leg} x {\leg} 1, 0.2{\leg} y {\leg} 0.4) compounds, unlike the well-known RFe2As2 (R = Ba, Sr, Ca) superconductors, contain complex structural features and notable physical properties, such as…

Superconductivity · Physics 2011-04-29 J. Q. Li , Y. J. Song , H. X. Yang , Z. Wang , H. L. Shi , G. F. Chen , Z. W. Wang , Z. Chen , H. F. Tian

The ionization energy theory is used to calculate the evolution of the resistivity and specific heat curves with respect to different doping elements in the recently discovered superconducting Pnictide materials. Subsequently, the…

Superconductivity · Physics 2009-11-05 Andrew Das Arulsamy , Kostya "Ken" Ostrikov