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Learning exchange correlation functionals, used in quantum chemistry calculations, from data has become increasingly important in recent years, but training such a functional requires sophisticated software infrastructure. For this reason,…

Machine Learning · Computer Science 2023-09-29 Advika Vidhyadhiraja , Arun Pa Thiagarajan , Shang Zhu , Venkat Viswanathan , Bharath Ramsundar

Accelerated discovery with machine learning (ML) has begun to provide the advances in efficiency needed to overcome the combinatorial challenge of computational materials design. Nevertheless, ML-accelerated discovery both inherits the…

Materials Science · Physics 2022-05-09 Chenru Duan , Fang Liu , Aditya Nandy , Heather J. Kulik

As deep neural networks (DNNs) are increasingly used in safety-critical applications, there is a growing concern for their reliability. Even highly trained, high-performant networks are not 100% accurate. However, it is very difficult to…

Neural and Evolutionary Computing · Computer Science 2024-07-30 Eduard Pinconschi , Divya Gopinath , Rui Abreu , Corina S. Pasareanu

In recent years, "composite" density-functional-theory-based methods comprising specially optimized combinations of functionals, basis sets, and empirical corrections have become widely used owing to their robustness and computational…

Chemical Physics · Physics 2024-11-21 Corin C. Wagen , Jonathon E. Vandezande

Replicability analysis aims to identify the findings that replicated across independent studies that examine the same features. We provide powerful novel replicability analysis procedures for two studies for FWER and for FDR control on the…

Methodology · Statistics 2019-03-01 Marina Bogomolov , Ruth Heller

Feature upsampling is a fundamental and indispensable ingredient of almost all current network structures for dense prediction tasks. Recently, a popular similarity-based feature upsampling pipeline has been proposed, which utilizes a…

Computer Vision and Pattern Recognition · Computer Science 2025-02-11 Minghao Zhou , Hong Wang , Yefeng Zheng , Deyu Meng

We put forward a general procedure to obtain an approximate free energy density functional for any hard-core lattice gas, regardless of the shape of the particles, the underlying lattice or the dimension of the system. The procedure is…

Statistical Mechanics · Physics 2007-05-23 Luis Lafuente , Jose A. Cuesta

The universal density functional $F$ of density-functional theory is a complicated and ill-behaved function of the density-in particular, $F$ is not differentiable, making many formal manipulations more complicated. Whilst $F$ has been well…

Chemical Physics · Physics 2015-06-18 Simen Kvaal , Ulf Ekström , Andrew M. Teale , Trygve Helgaker

Kohn-Sham density functional theory is in principle an exact formulation of quantum mechanical electronic structure theory, but in practice we have to rely on approximate exchange-correlation (xc) functionals. The objective of our work has…

Chemical Physics · Physics 2013-09-09 Roberto Peverati , Donald G. Truhlar

Over the recent years the importance of numerical experiments has gradually been more recognized. Nonetheless, sufficient documentation of how computational results have been obtained is often not available. Especially in the scientific…

Mathematical Software · Computer Science 2021-05-10 Jörg Fehr , Jan Heiland , Christian Himpe , Jens Saak

In recent years impressive progress has been made in the development of highly accurate energy density functionals, which allow to treat medium-heavy nuclei. In this approach one tries to describe not only the ground state but also the…

Nuclear Theory · Physics 2014-11-21 M Baldo , LM Robledo , P. Schuck , X. Viñas

As the second component of SPARC (Simulation Package for Ab-initio Real-space Calculations), we present an accurate and efficient finite-difference formulation and parallel implementation of Density Functional Theory (DFT) for extended…

Computational Physics · Physics 2017-05-24 Swarnava Ghosh , Phanish Suryanarayana

Density Functional Theory (DFT) is the de facto workhorse for large-scale electronic structure calculations in chemistry and materials science. While plane-wave DFT implementations remain the most widely used, real-space DFT provides…

Despite the enormous success and popularity of density-functional theory, systematic verification and validation studies are still limited in number and scope. Here, we propose a protocol to test publicly available pseudopotential…

Materials Science · Physics 2018-12-10 Gianluca Prandini , Antimo Marrazzo , Ivano E. Castelli , Nicolas Mounet , Nicola Marzari

We introduce a systematic analysis of density functional approximation errors in solids by separating functional-driven from density-driven contributions using quantum Monte Carlo densities of silicon, sodium chloride, and copper as…

Materials Science · Physics 2026-05-15 Ayoub Aouina , Nicolas Tancogne-Dejean , Silvana Botti

The delocalization error of popular density functional approximations (DFAs) leads to diversified problems in present-day density functional theory calculations. For achieving a universal elimination of delocalization error, we develop a…

Chemical Physics · Physics 2017-09-07 Chen Li , Xiao Zheng , Neil Qiang Su , Weitao Yang

Usually, density functional models are considered approximations to density functional theory, However, there is no systematic connection between the two, and this can make us doubt about a linkage. This attitude can be further enforced by…

Chemical Physics · Physics 2020-11-10 Andreas Savin

Density functional theory (DFT) provides a theoretical framework for efficient and fairly accurate calculations of the electronic structure of molecules and crystals. The main features of density functional theory are described and DFT…

Chemical Physics · Physics 2012-06-12 Hauke Paulsen , Alfred Xaver Trautwein

In real life, data are often of poor quality as a result, for instance, of uncertainty, mismeasurements, missing values or bad inputs. This issue hampers an implicit yet crucial operation of every database management system: equality…

Logic in Computer Science · Computer Science 2024-04-30 Lhouari Nourine , Jean Marc Petit , Simon Vilmin

We reexamine the recently introduced basis-set correction theory based on density-functional theory consisting in correcting the basis-set incompleteness error of wave-function methods using a density functional. We use a one-dimensional…

Chemical Physics · Physics 2022-02-16 Diata Traore , Emmanuel Giner , Julien Toulouse
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