English

On connecting density functional approximations to theory

Chemical Physics 2020-11-10 v1

Abstract

Usually, density functional models are considered approximations to density functional theory, However, there is no systematic connection between the two, and this can make us doubt about a linkage. This attitude can be further enforced by the vagueness of the argumentation for using spin densities. Questioning the foundations of density functional models leads to a search for alternative explanations. Seeing them as using models for pair densities is one of them. Another is considering density functional approximations as a way to extrapolate results obtained in a model system to those of a corresponding physical one.

Keywords

Cite

@article{arxiv.2011.04433,
  title  = {On connecting density functional approximations to theory},
  author = {Andreas Savin},
  journal= {arXiv preprint arXiv:2011.04433},
  year   = {2020}
}
R2 v1 2026-06-23T20:00:51.149Z