On connecting density functional approximations to theory
Chemical Physics
2020-11-10 v1
Abstract
Usually, density functional models are considered approximations to density functional theory, However, there is no systematic connection between the two, and this can make us doubt about a linkage. This attitude can be further enforced by the vagueness of the argumentation for using spin densities. Questioning the foundations of density functional models leads to a search for alternative explanations. Seeing them as using models for pair densities is one of them. Another is considering density functional approximations as a way to extrapolate results obtained in a model system to those of a corresponding physical one.
Cite
@article{arxiv.2011.04433,
title = {On connecting density functional approximations to theory},
author = {Andreas Savin},
journal= {arXiv preprint arXiv:2011.04433},
year = {2020}
}