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In this paper we study a generalization of the 1D Hubbard model by considering density-density and Ising-type spin-spin nearest neighbor (NN) interactions, parameterized by $V$ and $J$, respectively. We present the T=0 phase diagram for…

Strongly Correlated Electrons · Physics 2015-05-30 Ferdinando Mancini , Evgeny Plekhanov , Gerardo Sica

Accurate predictions of material properties within the chemical space of transition metal fluorides (TMFs), using density functional theory (DFT) is important for advancing several technological applications. The state-of-the-art semi-local…

Materials Science · Physics 2024-12-17 Dereje Bekele Tekliye , Gopalakrishnan Sai Gautam

We introduce HP, an implementation of density-functional perturbation theory, designed to compute Hubbard parameters (on-site $U$ and inter-site $V$) in the framework of DFT+$U$ and DFT+$U$+$V$. The code does not require the use of…

Materials Science · Physics 2022-07-11 Iurii Timrov , Nicola Marzari , Matteo Cococcioni

We analyze effective d-wave interactions in the two-dimensional extended Hubbard model at weak coupling and small to moderate doping. The interactions are computed from a renormalization group flow. Attractive d-wave interactions are…

Strongly Correlated Electrons · Physics 2012-09-18 Christoph Husemann , Walter Metzner

We conduct a systematic investigation of the role of Hubbard U corrections in electronic structure calculations of two-dimensional (2D) materials containing 3d transition metals. Specifically, we use density functional theory (DFT) with the…

Materials Science · Physics 2024-11-19 Sahar Pakdel , Thomas Olsen , Kristian S. Thygesen

Exact ground states, charge densities and excitation energies are found using valence bond methods for N-site modified Hubbard models with uniform spacing. At the neutral-ionic transition (NIT), the ground state has a symmetry crossover in…

Strongly Correlated Electrons · Physics 2009-10-31 Y. Anusooya-Pati , Z. G. Soos , A. Painelli

Projector Quantum-Monte-Carlo Method is used to examine effects of the spin-independent $U_{fd}$ as well as spin-dependent $J_z$ Coulomb interaction between the localized $f$ and itinerant $d$ electrons on the stability of various types of…

Strongly Correlated Electrons · Physics 2016-11-23 Pavol Farkasovsky

We report $^{93}$Nb and $^{121}$Sb NMR and $^{57}$Fe M\"{o}ssbauer studies combined with DFT calculations of Nb$_{1-x}$Ti$_x$FeSb ($0\leqslant x \leqslant0.3$), one of the most promising thermoelectric systems for applications above 1000 K.…

Core-level spectra of 1s electrons of elements heavier than Ne show significant relativistic effects. We combine advances in orbital optimized DFT (OO-DFT) with the spin-free exact two-component (X2C) model for scalar relativistic effects,…

Chemical Physics · Physics 2022-04-19 Leonardo A. Cunha , Diptarka Hait , Richard Kang , Yuezhi Mao , Martin Head-Gordon

Spin excitations play a fundamental role in understanding magnetic properties of materials, and have significant technological implications for magnonic devices. However, accurately modeling these in transition-metal and rare-earth…

Materials Science · Physics 2025-05-07 Luca Binci , Nicola Marzari , Iurii Timrov

Electronic coupling matrix elements are important to the theoretical description of electron transfer processes. However, they are notoriously difficult to obtain accurately from time- dependent density functional theory (TDDFT). Here, we…

Chemical Physics · Physics 2018-12-07 Debashree Manna , Jochen Blumberger , Jan M. L. Martin , Leeor Kronik

LDA+DMFT (Local Density Approximation combined with Dynamical Mean-Field Theory) computation scheme has been used to calculate spectral properties of LaFeAsO -- the parent compound of the new high-T_c iron oxypnictides. The average Coulomb…

Strongly Correlated Electrons · Physics 2009-06-18 V. I. Anisimov , E. Z. Kurmaev , A. Moewes , I. A. Izyumov

I present a critical overview of so-called "{\it ab initio}" DFT (density fuctional theory) based calculation schemes for the description of the electronic structure, energy spectrum, and optical response for strongly correlated 3$d$…

Strongly Correlated Electrons · Physics 2023-01-31 A. S. Moskvin

We calculate Heisenberg-type magnetic exchange interactions for SrMnO$_3$ under isotropic volume expansion using an approach that is based on total energy variations due to infinitesimal spin rotations around a given reference state. Our…

Materials Science · Physics 2020-02-12 Xiangzhou Zhu , Alexander Edström , Claude Ederer

The sensitivity of Density Functional Theory plus Dynamical Mean Field Theory calculations to different constructions of the correlated orbitals is investigated via a detailed comparison of results obtained for the quantum material…

Strongly Correlated Electrons · Physics 2021-05-12 Jonathan Karp , Alexander Hampel , Andrew J. Millis

Determining the ground state of multi-orbital Hubbard models is critical for understanding strongly correlated electron materials, yet existing methods struggle to simultaneously reach zero temperature and infinite system size. The…

Strongly Correlated Electrons · Physics 2023-11-08 Zhengqian Cheng , Chris A. Marianetti

First principles calculations based on density functional theory are performed to investigate the structural, electronic and magnetic properties of wurtzite ZnO/NiO (0001) interface. By using DFT+U method we discover that the half-metallic…

Materials Science · Physics 2011-11-16 Z. P. Chen , L. Miao , X. S. Miao

Using the recently developed N-th order muffin-tin orbital-based downfolding technique in combination with the Dynamical Mean Field theory, we investigate the electronic properties of the much discussed Mott insulator TiOCl in the…

Strongly Correlated Electrons · Physics 2009-11-10 T. Saha-Dasgupta , A. Lichtenstein , R. Valenti

We revisit the electronic structure of Ni, using the density functional theory (DFT) and dynamical mean-field theory (DMFT) for the theoretical description of its electronic structure properties along with finite-temperature magnetism. Our…

Strongly Correlated Electrons · Physics 2024-09-04 Shivani Bhardwaj , Antik Sihi , Sudhir K. Pandey

Typical density-functional theory calculations that wrongly predict undoped cuprates to be metallic also predict Cu-O half- and full-breathing phonon energies that are significantly softer than observed, presumably because of weak on-site…

Strongly Correlated Electrons · Physics 2021-11-03 Tyler C. Sterling , Dmitry Reznik