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Transition path theory (TPT) offers a powerful formalism for extracting the rate and mechanism of rare dynamical transitions between metastable states. Most applications of TPT either focus on systems with modestly sized state spaces or use…

Statistical Mechanics · Physics 2026-01-14 Nils E. Strand , Schuyler B. Nicholson , Hadrien Vroylandt , Todd R. Gingrich

Transition Path Theory (TPT) provides a rigorous framework to investigate the dynamics of rare thermally activated transitions. In this theory, a central role is played by the forward committor function q^+(x), which provides the ideal…

Statistical Mechanics · Physics 2018-08-15 G. Bartolucci , S. Orioli , P. Faccioli

We propose a novel approach for computing committor functions, which describe transitions of a stochastic process between metastable states. The committor function satisfies a backward Kolmogorov equation, and in typical high-dimensional…

Numerical Analysis · Mathematics 2021-08-04 Yian Chen , Jeremy Hoskins , Yuehaw Khoo , Michael Lindsey

A central object in the computational studies of rare events is the committor function. Though costly to compute, the committor function encodes complete mechanistic information of the processes involving rare events, including reaction…

Statistical Mechanics · Physics 2022-11-23 Muhammad R. Hasyim , Clay H. Batton , Kranthi K. Mandadapu

In this paper, we introduce a new finite expression method (FEX) to solve high-dimensional partial integro-differential equations (PIDEs). This approach builds upon the original FEX and its inherent advantages with new advances: 1) A novel…

Numerical Analysis · Mathematics 2025-06-19 Gareth Hardwick , Senwei Liang , Haizhao Yang

As an optimal one-dimensional reaction coordinate, the committor function not only describes the probability of a trajectory initiated at a phase space point first reaching the product state before reaching the reactant state, but also…

Chemical Physics · Physics 2024-10-08 Xiaojun Ji , Ru Wang , Hao Wang , Wenjian Liu

Designing efficient and accurate numerical solvers for high-dimensional partial differential equations (PDEs) remains a challenging and important topic in computational science and engineering, mainly due to the "curse of dimensionality" in…

Numerical Analysis · Mathematics 2025-08-20 Senwei Liang , Haizhao Yang

Rare events such as conformational changes in biomolecules, phase transitions, and chemical reactions are central to the behavior of many physical systems, yet they are extremely difficult to study computationally because unbiased…

Machine Learning · Statistics 2026-04-16 Yuanqi Du , Jiajun He , Dinghuai Zhang , Eric Vanden-Eijnden , Carles Domingo-Enrich

The probability that a configuration of a physical system reacts, or transitions from one metastable state to another, is quantified by the committor function. This function contains richly detailed mechanistic information about transition…

Statistical Mechanics · Physics 2024-08-13 Andrew R. Mitchell , Grant M. Rotskoff

Given two metastable states A and B of a biomolecular system, the problem is to calculate the likely paths of the transition from A to B. Such a calculation is more informative and more manageable if done for a reduced set of collective…

Computational Physics · Physics 2010-11-13 Ruijun Zhao , Juanfang Shen , Robert D. Skeel

The committor function is a central object of study in understanding transitions between metastable states in complex systems. However, computing the committor function for realistic systems at low temperatures is a challenging task, due to…

Computational Physics · Physics 2019-09-04 Qianxiao Li , Bo Lin , Weiqing Ren

Many processes in nature such as conformal changes in biomolecules and clusters of interacting particles, genetic switches, mechanical or electromechanical oscillators with added noise, and many others are modeled using stochastic…

Optimization and Control · Mathematics 2023-10-13 Jiaxin Yuan , Amar Shah , Channing Bentz , Maria Cameron

In this paper, we study a machine-learning-based solver for high-dimensional partial differential equations (PDEs). Computing accurate solutions efficiently for such problems remains challenging because of the curse of dimensionality, which…

Numerical Analysis · Mathematics 2026-04-27 Phuoc-Toan Huynh , Feng Bao , Haizhao Yang , Ahmed Zytoon

For a transition between two stable states, the committor is the probability that the dynamics leads to one stable state before the other. It can be estimated from trajectory data by minimizing an expression for the transition rate that…

Statistical Mechanics · Physics 2025-12-09 Chatipat Lorpaiboon , Jonathan Weare , Aaron R. Dinner

Solving partial differential equations (PDEs) with highly oscillatory solutions on complex domains remains a challenging and important problem. High-frequency oscillations and intricate geometries often result in prohibitively expensive…

Numerical Analysis · Mathematics 2025-10-28 Gareth Hardwick , Haizhao Yang

The committor functions are central to investigating rare but important events in molecular simulations. It is known that computing the committor function suffers from the curse of dimensionality. Recently, using neural networks to estimate…

Machine Learning · Statistics 2025-01-28 Yueyang Wang , Kejun Tang , Xili Wang , Xiaoliang Wan , Weiqing Ren , Chao Yang

Recent years have seen rapid advances in the data-driven analysis of dynamical systems based on Koopman operator theory and related approaches. On the other hand, low-rank tensor product approximations -- in particular the tensor train (TT)…

Numerical Analysis · Mathematics 2021-08-11 Feliks Nüske , Patrick Gelß , Stefan Klus , Cecilia Clementi

The problem of studying rare events is central to many areas of computer simulations. In a recent paper [Kang, P., et al., Nat. Comput. Sci. 4, 451-460, 2024], we have shown that a powerful way of solving this problem passes through the…

Computational Physics · Physics 2026-03-03 Enrico Trizio , Peilin Kang , Michele Parrinello

The committor function is a central object for quantifying the transitions between metastable states of dynamical systems. Recently, a number of computational methods based on deep neural networks have been developed for computing the…

Computational Physics · Physics 2024-04-10 Bo Lin , Weiqing Ren

Solving high-dimensional partial differential equations necessitates methods free of exponential scaling in the dimension of the problem. This work introduces a tensor network approach for the Kolmogorov backward equation via approximating…

Numerical Analysis · Mathematics 2024-04-24 Xun Tang , Leah Collis , Lexing Ying
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