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Rare-earth trihydrides ($R$H$_3$) exhibit intriguing coupled electronic and structural properties as a function of doping, hydrogen vacancies, and thermodynamic conditions. Theoretical studies of these materials typically rely on density…

Strongly Correlated Electrons · Physics 2024-10-07 Adam Denchfield , Hyeondeok Shin , Panchapakesan Ganesh , Russell J Hemley , Hyowon Park

Transition-metal compounds pose serious challenges to first-principles calculations based on density-functional theory (DFT), due to the inability of most approximate exchange-correlation functionals to capture the localization of valence…

Materials Science · Physics 2019-03-13 Matteo Cococcioni , Nicola Marzari

In the context of the modified Becke-Johnson (mBJ) potential, we recently underlined that $\bar{g}$, the average of $\left\vert\nabla\rho\right\vert/\rho$ in the unit cell, has markedly different values in transition-metal oxides and pure…

Materials Science · Physics 2022-01-04 Leila Kalantari , Fabien Tran , Peter Blaha

Phonon frequencies at {\Gamma},X,M,R-points of Brilloin zone in cubic phase of Ba(Ti,Zr,Hf)O3 were first time calculated by frozen phonon method using density functional theory (DFT) with hybrid exchange correlation functional PBE0. The…

Materials Science · Physics 2010-10-07 Robert A Evaestov

Accurately modeling compounds with partially filled $d$ and $f$ shells remains a hard challenge for density-functional theory, due to large self-interaction errors stemming from local or semi-local exchange-correlation functionals. Hubbard…

Materials Science · Physics 2026-01-19 Kinga Warda , Eric Macke , Iurii Timrov , Lucio Colombi Ciacchi , Piotr M. Kowalski

With the widespread use of self-consistent field methods, including Hartree-Fock and Density Functional Theory, the implications of accelerating these methods are immense. To this end, we develop a tensor hypercontraction construction with…

Chemical Physics · Physics 2025-08-27 Andreas Erbs Hillers-Bendtsen , Todd J. Martínez

The practical utility of M{\o}ller-Plesset (MP) perturbation theory is severely constrained by the use of Hartree-Fock (HF) orbitals. It has recently been shown that use of regularized orbital-optimized MP2 orbitals and scaling of MP3…

Chemical Physics · Physics 2021-01-06 Adam Rettig , Diptarka Hait , Luke W. Bertels , Martin Head-Gordon

We present an algorithm and implementation of integral-direct, density-fitted Hartree-Fock (HF) and second-order M{\o}ller-Plesset perturbation theory (MP2) for periodic systems. The new code eliminates the formerly prohibitive storage…

Chemical Physics · Physics 2022-10-11 Sylvia J. Bintrim , Timothy C. Berkelbach , Hong-Zhou Ye

We calculate the Hubbard bands for the half-filled Hubbard model on a Bethe lattice with infinite coordination number up to and including third order in the inverse Hubbard interaction. We employ the Kato--Takahashi perturbation theory to…

Strongly Correlated Electrons · Physics 2015-05-20 Daniel Ruhl , Florian Gebhard

The infinite-dimensional Hubbard model is studied by means of a modified perturbation theory. The approach reduces to the iterative perturbation theory for weak coupling. It is exact in the atomic limit and correctly reproduces the…

Strongly Correlated Electrons · Physics 2009-10-30 T. Wegner , M. Potthoff , W. Nolting

Half-metallic Heusler compounds are of significant interest for spintronics. For device fabrication, compounds that can be epitaxially grown on III-V semiconductors are particularly attractive. We present a first-principles investigation of…

We study the transfer of spectral weight in the optical spectra of a strongly correlated electron system as a function of temperature and interaction strength. Within a dynamical mean field theory of the Hubbard model that becomes exact in…

Condensed Matter · Physics 2009-10-28 M. J. Rozenberg , G. Kotliar , H. Kajueter , G. A. Thomas , D. H. Rapkine , J. M. Honig , P. Metcalf

The crystalline structure of ground-state orthorhombic SrRuO$_3$ is reproduced by applying hybrid density functional theory scheme to the functionals based on the revised generalized-gradient approximations for solid-state calculations. The…

Materials Science · Physics 2016-10-11 Š. Masys , V. Jonauskas

We combine the single site dynamical mean field theory (DMFT) with the non-local GW method. This is done fully self-consistently and we apply our formalism to a one-band Hubbard model. Eventually at self-consistency the full self-energy and…

Strongly Correlated Electrons · Physics 2007-05-23 K. Karlsson

We investigate the electronic and structural properties of CuO, which shows significant deviations from the trends obeyed by other transition-metal monoxides. Using an extended Hubbard corrective functional, we uncover an orbitally ordered…

Strongly Correlated Electrons · Physics 2011-12-14 Burak Himmetoglu , Renata M. Wentzcovitch , Matteo Cococcioni

Density functional theory augmented with Hubbard-$U$ corrections (DFT+$U$) is currently one of the widely used methods for first-principles electronic structure modeling of insulating transition metal oxides (TMOs). Since $U$ is relatively…

Computational Physics · Physics 2018-05-09 Samara Keshavarz , Johan Schött , Andrew J. Millis , Yaroslav O. Kvashnin

Accurately measuring the Hubble parameter is vital for understanding the expansion history and properties of the universe. In this paper, we propose a new method that supplements the covariance between redshift pairs to improve the…

Cosmology and Nongalactic Astrophysics · Physics 2024-01-23 Jian-Chen Zhang , Yu Hu , Kang Jiao , Hong-Feng Wang , Yuan-Bo Xie , Bo Yu , Li-Li Zhao , Tong-Jie Zhang

Band alignment between two materials is of fundamental importance for multitude of applications. However, density functional theory (DFT) either underestimates the bandgap - as is the case with local density approximation (LDA) or…

We formulate a set of equations that facilitate an exact numerical solution of the Kohn-Sham potential for a finite Hubbard chain with nearest neighbour hopping and arbitrary site potentials. The approach relies on a mapping of the…

Strongly Correlated Electrons · Physics 2018-10-25 Kossi Amouzouvi , Daniel Joubert

Strongly correlated fermions in a crystal or in an optical lattice in the presence of binary alloy disorder are investigated. We employ the statistical dynamical mean-field theory, which incorporates both, local fluctuations due to disorder…

Disordered Systems and Neural Networks · Physics 2010-09-15 Denis Semmler , Krzysztof Byczuk , Walter Hofstetter