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Related papers: On the 1$^1\Sigma^{+}_{\mathrm{u}}$ electronic sta…

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Despite its apparently simple nature with four valence electrons, the strontium dimer constitutes a challenge for modern electronic structure theory. Here we focus on excited electronic states of Sr$_2$, which we investigate theoretically…

The polarisation labelling spectroscopy technique was applied to study the C$^1\Pi_{\mathrm{u}}$ $\leftarrow$ X$^1\Sigma^{+}_{\mathrm{g}}$ band system in potassium dimer. About 1100 new rotationally resolved molecular lines were measured in…

Atomic Physics · Physics 2025-01-13 W. Jastrzebski , J Szczepkowski , P. Kowalczyk

We report a systematic study of the C(2)$^1\Pi_u$ electronic state in rubidium dimer, observed in polarization labelling spectroscopy experiment through the C $\leftarrow$ X$^{1}\Sigma^{+}_{g}$ transitions recorded under rotational…

Chemical Physics · Physics 2022-07-27 Asen Pashov , Pawel Kowalczyk , Jacek Szczepkowski , Wlodzimierz Jastrzebski

Polarisation labelling spectroscopy technique was employed to study the 3$^{1}\Pi_{u}$ state of Cs$_2$ molecule. The main equlibrium constants are $T_e=20684.60$cm$^{-1}$, $\omega_e=30.61$cm$^{-1}$ and $R_e=5.27$\r{A}. Vibrational levels…

Chemical Physics · Physics 2021-04-14 Jacek Szczepkowski , Anna Grochola , Wlodzimierz Jastrzebski , Pawel Kowalczyk

The $A^1\Sigma^+_u$ - $X^1\Sigma^+_g$ UV spectrum of Mg$_2$ has been investigated with high resolution employing Fourier-transform spectroscopy and laser excitation. Computer simulation and fit of line positions to the overlapping…

Atomic Physics · Physics 2014-10-20 Horst Knöckel , Steffen Rühmann , Eberhard Tiemann

Using the polarisation labelling spectroscopy, we performed the detailed analysis of the level structure of excited electronic states of the $^{39}$KCs molecule in the excitation energy interval between 17500~cm$^{-1}$ and 18600~cm$^{-1}$…

Photoionization spectroscopy of cold cesium dimers obtained by photoassociation of cold atoms in a magneto-optical trap is reported here. In particular, we report on the observation and on the spectroscopic analysis of all the excited…

LiSr was produced in a heat-pipe oven and its thermal emission spectrum around 9300 cm$^{-1}$ was recorded by a high resolution Fourier transform spectrometer. In addition, selected lines of the spectrum of deeply bound vibrational levels…

A {\gamma}-ray linear polarization measurement has been performed to directly determine the parities for the levels in 146Gd nucleus. High-spin states in this nucleus were populated in a reaction 115In + 34S at 140 MeV incident energy.…

A high resolution study of the electronic states 1^1\Sigma^+_u and 1^1\Pi_u which belong to the asymptote 4^1D + 5^1S and of the state 2(A)^1\Sigma^+_u, which correlates to the asymptote 5^1P + 5^1S, is performed by Fourier-transform…

Chemical Physics · Physics 2015-03-19 Alexander Stein , Horst Knöckel , Eberhard Tiemann

We have studied the X 1{\Sigma}+ and B 1{\Pi} states of 7Li85Rb using Laser Induced Fluorescence (LIF) spectroscopy and Fluorescence Excitation Spectroscopy (FES). We extract molecular constants for levels v" = 0-2 of the X 1{\Sigma}+ state…

Atomic Physics · Physics 2011-11-04 Sourav Dutta , Adeel Altaf , D. S. Elliott , Yong P. Chen

Using resonant two-step laser excitation of trapped $^{232}\mathrm{Th}^+$ ions, we observe 166 previously unknown energy levels of even parity within the energy range from 7.8 to 9.8 eV and angular momenta from $J=1/2$ to $7/2$. We also…

We present a measurement of the dynamic scalar and tensor polarizabilities of the excited state 3D1 in atomic ytterbium. The polarizabilities were measured by analyzing the spectral lineshape of the 408-nm 1S0->3D1 transition driven by a…

Atomic Physics · Physics 2010-12-15 D. R. Dounas-Frazer , K. Tsigutkin , A. Family , D. Budker

An experimental study of the long range behavior of the ground state X^1\Sigma^+_g of Sr_2 is performed by high resolution spectroscopy of asymptotic vibrational levels and the use of available photoassociation data. Ground state levels as…

Chemical Physics · Physics 2010-04-19 A. Stein , H. Knöckel , E. Tiemann

We present the first spectroscopic studies of the $C \ ^1\Sigma^+$ electronic state and the $A \ ^1\Sigma^+$ - $b \ ^3\Pi_{0^+}$ complex in $^7$Li - $^{85}$Rb. Using resonantly-enhanced, two-photon ionization, we observed $v = 7$, 9, 12, 13…

Atomic Physics · Physics 2016-12-21 I. C. Stevenson , D. B. Blasing , Y. P. Chen , D. S. Elliott

Accurate absolute level energies of the $B\,^1\Sigma^{+}_{u}$, $v=0-8, N$ and $EF\,^{1}\Sigma^{+}_{g}$, $v=0-21, N$ rovibrational quantum states of molecular deuterium are derived by combining results from a Doppler-free two-photon laser…

Atomic Physics · Physics 2014-10-10 E. J. Salumbides , D. Bailly , M. Vervloet , W. Ubachs

We study the effect of a strong static homogeneous electric field on the highly excited rovibrational levels of the LiCs dimer in its electronic ground state. Our full rovibrational investigation of the system includes the interaction with…

Atomic Physics · Physics 2015-05-13 Rosario Gonzalez-Ferez , Peter Schmelcher

The coupled states A^{1}\Sigma_{u}^{+} (^{1}D +}1}S), c^{3}\Pi_{u} (^{3}P + ^{1}S) and a^{3}\Sigma_{u}^{+} (^{3}P +}1}S) of the calcium dimer are investigated in a laser induced fluorescence experiment combined with high-resolution…

Atomic and Molecular Clusters · Physics 2016-08-16 O. Allard , St. Falke , A. Pashov , O. Dulieu , H. Knöckel , E. Tiemann

The double minimum E$^1\Sigma^{+}_{\mathrm{u}}$ state in caesium dimer was investigated by analysing spectra of the E$^1\Sigma^{+}_{\mathrm{u}}$ $\leftarrow$ X$^1\Sigma^{+}_{\mathrm{g}}$ band system, simplified by polarisation labelling. A…

Atomic Physics · Physics 2025-01-10 W. Jastrzebski , P. Kowalczyk , J. Szczepkowski , A. Pashov

State-of-the-art ab initio techniques have been applied to compute the potential energy curves for the electronic states in the A^1\Sigma_u^+, c^3\Pi_u, and a^3\Sigma_u^+ manifold of the strontium dimer, the spin-orbit and nonadiabatic…

Chemical Physics · Physics 2012-05-30 Wojciech Skomorowski , Filip Pawlowski , Christiane P. Koch , Robert Moszynski
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