$B\,^1\Sigma^{+}_{u}$ and $EF\,^{1}\Sigma^{+}_{g}$ level energies of D$_{2}$
Abstract
Accurate absolute level energies of the , and , rovibrational quantum states of molecular deuterium are derived by combining results from a Doppler-free two-photon laser excitation study on several lines in the (0,0) band, with results from a Fourier-transform spectroscopic emission study on a low-pressure hydrogen discharge. Level energy uncertainties as low as 0.0005 cm are obtained for some low-lying inner-well rovibrational levels, while uncertainties for higher-lying rovibrational levels and those of the outer-well states are nominally 0.005 cm. Level energies of rovibrational levels, for and are determined at an accuracy of 0.001 cm. Computed wavelengths of D Lyman transitions in the () bands are also tabulated for future applications.
Keywords
Cite
@article{arxiv.1410.2398,
title = {$B\,^1\Sigma^{+}_{u}$ and $EF\,^{1}\Sigma^{+}_{g}$ level energies of D$_{2}$},
author = {E. J. Salumbides and D. Bailly and M. Vervloet and W. Ubachs},
journal= {arXiv preprint arXiv:1410.2398},
year = {2014}
}
Comments
appears in Journal of Molecular Spectroscopy (2014)