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The discovery of superconductivity in La3Ni2O7 has attracted significant research interest in the field of nickelate superconductors. Despite extensive studies on pristine La3Ni2O7, the impact of oxygen vacancies (VO), a common type of…

Materials Science · Physics 2024-06-07 Xuelei Sui , Xiangru Han , Xiaojun Chen , Liang Qiao , Xiaohong Shao , Bing Huang

Understanding and controlling the director field configuration, shape, and orientation in nematic and cholesteric liquid crystals is of fundamental importance in several branches of science. Liquid crystalline droplets, also known as…

Soft Condensed Matter · Physics 2020-12-29 Hamed Almohammadi , Massimo Bagnani , Raffaele Mezzenga

The discovery of high-mobility two-dimensional electron gas and low carrier density superconductivity in multiple SrTiO$_3$-based heterostructures has stimulated intense interest in the surface properties of SrTiO$_3$. The recent discovery…

Mesoscale and Nanoscale Physics · Physics 2024-05-31 Cui Ding , Wenfeng Dong , Xiaotong Jiao , Zhiyu Zhang , Guanming Gong , Zhongxu Wei , Lili Wang , Jin-Feng Jia , Qi-Kun Xue

The Mott-insulating rare-earth titanates (RTiO$_3$, R being a rare-earth ion) are an important class of materials that encompasses interesting spin-orbital phases as well as ferromagnet-antiferromagnet and insulator-metal transitions. The…

In the R1/2D1/2MnO3 manganites (R: rare earth, D: divalent cation), the structural phase transition at Tco is commonly interpreted as a concomitant charge and orbital ordering (CO/OO) process driven by a cooperative Jahn-Teller effect and…

Strongly Correlated Electrons · Physics 2007-05-23 A. Daoud-Aladine , J. Rodriguez-Carvajal , L. Pinsard-Gaudart , M. T. Fernandez-Diaz , A. Revcolevschi

We propose a theory for bilayer nickelate materials, where a large tetragonal field - intrinsic or induced by epitaxial strain - lifts the orbital degeneracy and localizes the $3z^2-r^2$ orbital states. These states host local spins $S=1/2$…

Strongly Correlated Electrons · Physics 2026-01-22 Giniyat Khaliullin , Jiří Chaloupka

Although crystalline solids are characterized by their periodic structures, some are only periodic on average and deviate on a local scale. Distinct local orderings can exist with identical periodic structures making their differences…

Materials Science · Physics 2021-07-02 Nikolaj Roth , Jonas Beyer , Karl F. F. Fischer , Kaiyang Xia , Tiejun Zhu , Bo Brummerstedt Iversen

Divalent tin oxides have attracted considerable attention as novel p-type oxide semiconductors, which are essential for realizing future oxide electronic devices. Recently, p-type Sn2Nb2O7 and SnNb2O6 were developed; however, enhanced hole…

Materials Science · Physics 2020-12-25 Akane Samizo , Makoto Minohara , Naoto Kikuchi , Kyoko K. Bando , Yoshihiro Aiura , Ko Mibu , Keishi Nishio

The material class of rare earth nickelates with high Ni$^{3+}$ oxidation state is generating continued interest due to the occurrence of a metal-insulator transition with charge order and the appearance of non-collinear magnetic phases…

Strongly Correlated Electrons · Physics 2018-01-11 H. Guo , Z. W. Li , L. Zhao , Z. Hu , C. F. Chang , C. -Y. Kuo , W. Schmidt , A. Piovano , T. W. Pi , O. Sobolev , D. I. Khomskii , L. H. Tjeng , A. C. Komarek

Charge order is a central feature of the physics of cuprate superconductors and is known to arise from a modulation of holes with primarily oxygen character. Low-valence nickelate superconductors also host charge order, but the electronic…

Strongly Correlated Electrons · Physics 2023-03-29 Y. Shen , J. Sears , G. Fabbris , J. Li , J. Pelliciari , M. Mitrano , W. He , Junjie Zhang , J. F. Mitchell , V. Bisogni , M. R. Norman , S. Johnston , M. P. M. Dean

The recent discovery of superconductivity in oxygen-reduced monovalent nickelates has raised a new platform for the study of unconventional superconductivity, with similarities and differences with the cuprate high temperature…

Superconductivity · Physics 2021-03-16 Emily Been , Wei-Sheng Lee , Harold Y. Hwang , Yi Cui , Jan Zaanen , Thomas Devereaux , Brian Moritz , Chunjing Jia

For decades transition-metal oxides have generated a huge interest due to the multitude of physical phenomena they exhibit. In this class of materials, the rare-earth nickelates, $R$NiO$_3$, stand out for their rich phase diagram stemming…

Strongly Correlated Electrons · Physics 2023-09-18 Luca Binci , Michele Kotiuga , Iurii Timrov , Nicola Marzari

Trilayer nickelates, which exhibit a high degree of orbital polarization combined with an electron count (d8.67) corresponding to overdoped cuprates, have been identified as a promising candidate platform for achieving high-Tc…

Most perovskite oxides belong to the Pbnm space group, composed by an anisotropic unit cell, A-site antipolar displacements and oxygen octahedral tilts. Mapping the orientation of the orthorhombic unit cell in epitaxial heterostructures…

Resonant inelastic x-ray scattering is used to investigate the electronic origin of orbital polarization in nickelate heterostructures taking $\mathrm{LaTiO_3-LaNiO_3-3x(LaAlO_3)}$, a system with exceptionally large polarization, as a model…

We report the enthalpy of oxygen vacancy formation in thin films of electron-doped SrTiO$_{3}$, under different degrees of epitaxial stress. We demonstrate that both compressive and tensile strain decrease this energy at a very similar…

Materials Science · Physics 2017-05-24 L. Iglesias , A. Sarantopoulos , C. Magen , F. Rivadulla

Superconductivity is one of the most intriguing properties of matter described by an attractive interaction that bounds electrons into Cooper pairs. To date, the highest critical temperature at ambient conditions is achieved in copper…

Electronic tunability in crystals with weakly-bound layers can be achieved through layer stacking order. One such example is MoTe$_2$, where the low-temperature orthorhombic T$_d$ phase is topological and host to Weyl quasiparticles. The…

Materials Science · Physics 2019-04-17 John A. Schneeloch , Chunruo Duan , Xiaoping Wang , Jun Liu , Junjie Yang , Despina Louca

We investigate the structural and transport properties of vacancy-ordered monoclinic superconducting $\mathrm{TiO}$ thin films grown by molecular beam epitaxy. The evolution of the crystal structure during growth is monitored by in-situ…

Superconductivity · Physics 2023-12-11 Merve Baksi , Hawoong Hong , Divine P. Kumah

Oxygen vacancy ordering in perovskite-type transition-metal oxides plays an important role in the emergence of exotic electronic properties, as typified by superconducting cuprates. In this study, we predict the stability of…

Computational Physics · Physics 2020-04-15 Atsuto Seko , Shintaro Ishiwata
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