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We present an alternative to the Kohn-Sham formulation of density functional theory for the ground-state properties of strongly interacting electronic systems. The idea is to start from the limit of zero kinetic energy and systematically…

Strongly Correlated Electrons · Physics 2015-05-13 Paola Gori-Giorgi , Michael Seidl , G. Vignale

In this note, we study an optimal transportation problem arising in density functional theory. We derive an upper bound on the semi-classical Hohenberg-Kohn functional derived by Cotar, Friesecke and Kl\"{u}ppelberg (2012) which can be…

Optimization and Control · Mathematics 2015-06-12 Brendan Pass

AC-OPF (Alternative Current Optimal Power Flow)aims at minimizing the operating costs of a power gridunder physical constraints on voltages and power injections.Its mathematical formulation results in a nonconvex polynomial…

Optimization and Control · Mathematics 2023-05-31 Adrien Le Franc , Victor Magron , Jean-Bernard Lasserre , Manuel Ruiz , Patrick Panciatici

The importance of the Lieb-Simon proof of the relative exactness of Thomas-Fermi theory in the large-Z limit to modern density functional theory (DFT) is explored. The principle, that there is a specific semiclassical limit in which…

Mathematical Physics · Physics 2022-02-14 Kieron Burke

Forty-five years after the point de d\'epart [1] of density functional theory, its applications in chemistry and the study of electronic structures keep steadily growing. However, the precise form of the energy functional in terms of the…

Chemical Physics · Physics 2019-10-29 Philippe Blanchard , José M. Gracia-Bondía , Joseph C. Várilly

We consider the problem of electron transport along a one-dimensional disordered multiple-scattering conductor, and study the electron density for all the electronic levels. A model is proposed for the reduced density matrix of the system…

Disordered Systems and Neural Networks · Physics 2023-03-14 Gerardo Rivas , Miztli Yepez , Pier A. Mello

Biased diffusive transport of Brownian particles through irregularly shaped, narrow confining quasi-one-dimensional structures is investigated. The complexity of the higher dimensional diffusive dynamics is reduced by means of the so-called…

Statistical Mechanics · Physics 2009-09-22 P. Sekhar Burada , Gerhard Schmid , Peter Hänggi

The reliable prediction of optical and fundamental gaps of finite size systems using density functional theory requires to account for the potential self-interaction error, which is notorious for degrading the description of charge transfer…

Chemical Physics · Physics 2016-10-26 O. S. Bokareva , M. F. Shibl , M. J. Al-Marri , T. Pullerits , O. Kühn

We propose a new approach to deriving quantitative mean field approximations for any probability measure $P$ on $\mathbb{R}^n$ with density proportional to $e^{f(x)}$, for $f$ strongly concave. We bound the mean field approximation for the…

Probability · Mathematics 2022-06-06 Daniel Lacker , Sumit Mukherjee , Lane Chun Yeung

This note provides a succinct proof of a 1973 theorem of Lieb that establishes the concavity of a certain trace function. The development relies on a deep result from quantum information theory, the joint convexity of quantum relative…

Information Theory · Computer Science 2014-04-29 Joel A. Tropp

We prove an analogue of the Lieb--Thirring inequality for many-body quantum systems with the kinetic operator $\sum_i (-\Delta_i)^s$ and the interaction potential of the form $\sum_i \delta_i^{-2s}$ where $\delta_i$ is the nearest-neighbor…

Mathematical Physics · Physics 2025-01-03 G. K. Duong , Phan Thành Nam

The electron localization function (ELF) is a universal measure of electron localization that allows for, e.g., an effective characterization of physical bonds in molecular and solid state systems. In the context of the widely used…

Strongly Correlated Electrons · Physics 2019-08-20 Alexander Lindmaa , Joel Davidsson , Ann E. Mattsson , Rickard Armiento

Long-range interactions play a central role in electron transport. At the same time, they present a challenge for direct computer simulations, since sufficiently large portions of the bath have to be included in the computation to…

Computational Physics · Physics 2021-09-29 Weiqi Chu , Xiantao Li

Recently, in a series of papers [32,38,39,41], the ratio of $\ell_1$ and $\ell_2$ norms was proposed as a sparsity inducing function for noiseless compressed sensing. In this paper, we further study properties of such model in the noiseless…

Optimization and Control · Mathematics 2021-02-12 Liaoyuan Zeng , Peiran Yu , Ting Kei Pong

This work considers the confining and scattering phenomena of electrons in a Lieb lattice subjected to the influence of a rectangular electrostatic barrier. In this setup, hopping amplitudes between nearest neighbors in orthogonal…

Mesoscale and Nanoscale Physics · Physics 2023-05-24 Vít Jakubský , Kevin Zelaya

We introduce the semiclassical limit to electronic systems by taking the limit $\hbar\rightarrow 0$ in the solution of Schr\"odinger equations. We show that this limit is closely related to one type of strong correlation that is…

Computational Physics · Physics 2025-01-07 Yunzhi Li , Chen Li

We prove that the electron density function of a real physical system can be uniquely determined by its values on any finite subsystem. This establishes the existence of a rigorous density-functional theory for any open electronic system.…

Quantum Physics · Physics 2007-05-23 Xiao Zheng , Fan Wang , GuanHua Chen

We provide a framework to approximate the 2-Wasserstein distance and the optimal transport map, amenable to efficient training as well as statistical and geometric analysis. With the quadratic cost and considering the Kantorovich dual form…

Optimization and Control · Mathematics 2019-02-20 Amirhossein Taghvaei , Amin Jalali

We present a real-space method for first-principles nano-scale electronic transport calculations. We use the non-equilibrium Green's function method with density functional theory and implement absorbing boundary conditions (ABCs, also…

Mesoscale and Nanoscale Physics · Physics 2014-07-29 Baruch Feldman , Tamar Seideman , Oded Hod , Leeor Kronik

We study the transport properties of interacting electrons in a disordered quantum wire within the framework of the Luttinger liquid model. We demonstrate that the notion of weak localization is applicable to the strongly correlated…

Disordered Systems and Neural Networks · Physics 2007-05-23 I. V. Gornyi , A. D. Mirlin , D. G. Polyakov