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The experimental realization of strong light-matter coupling with molecules initiated the rapidly evolving field of molecular polaritonics. Most studies focus on how exciton polaritons, which combine electronic excitations with confined…

Chemical Physics · Physics 2025-09-10 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Polaritonic chemistry investigates the possible modification of chemical and photochemical reactions by means of strong light-matter coupling in optical cavities, as demonstrated in numerous experiments over the last few years. These…

Quantum Physics · Physics 2025-07-30 Lucas Borges , Thomas Schnappinger , Markus Kowalewski

Nonadiabatic phenomena are investigated in the rovibrational motion of molecules confined in an infrared cavity. Conical intersections (CIs) between vibrational polaritons, similar to CIs between electronic polaritonic surfaces, are found.…

Quantum Physics · Physics 2021-02-24 Tamás Szidarovszky , Péter Badankó , Gábor J. Halász , Ágnes Vibók

Inspired by the recent experimental observation of strongly coupled polaritons in a Moir\'e heterobilayer, we study a model of dipole-interacting excitons localized on sites of a lattice and coupled to planar cavity photons. We calculate…

Strongly Correlated Electrons · Physics 2022-03-25 Alexander Edelman , Peter B. Littlewood

The collective response of an atomic ensemble is shaped by its macroscopic environment. We demonstrate this effect in the near-resonant transmission of light through a thermal rubidium vapor confined in a planar nanocavity. Our model…

Atomic Physics · Physics 2020-09-30 Helge Dobbertin , Robert Löw , Stefan Scheel

Strong coupling between light and matter generates hybrid polariton modes. We present a continuum formalism that expresses the polariton modes in terms of light and matter densities of states (DOS). We derive exact expressions for the light…

Materials Science · Physics 2024-12-03 Suman Gunasekaran , Ryan F. Pinard , Andrew J. Musser

We study a system consisting of a superconducting flux qubit strongly coupled to a microwave cavity. The fundamental cavity mode is externally driven and the response is investigated in the weak nonlinear regime. We find that near the…

Quantum Physics · Physics 2016-09-14 Eyal Buks , Chunqing Deng , Jean-Luc F. X. Orgazzi , Martin Otto , Adrian Lupascu

We present a quantum description of a planar microcavity photon mode strongly coupled to a semiconductor intersubband transition in presence of a two-dimensional electron gas. We show that, in this kind of system, the vacuum Rabi frequency…

Other Condensed Matter · Physics 2016-08-16 Cristiano Ciuti , Gérald Bastard , Iacopo Carusotto

We have developed a non-Markovian theory of the polariton luminescence taking the molecular vibrations into account. The calculations were made in the polariton basis. We have shown that the frequency shift and the polariton spectral lines…

Mesoscale and Nanoscale Physics · Physics 2022-04-19 B. D. Fainberg , V. Al. Osipov

Microscopic insights into nonlinear interactions are essential for advancing polaritonic devices. Existing studies often rely on phenomenological models that overlook important many-body processes. Based on a material-specific and…

Mesoscale and Nanoscale Physics · Physics 2026-03-31 Jonas K König , Jamie M Fitzgerald , Daniel Erkensten , Ermin Malic

Molecules constitute compact hybrid quantum optical systems that can interface photons, electronic degrees of freedom, localized mechanical vibrations and phonons. In particular, the strong vibronic interaction between electrons and nuclear…

We report the experimental study of a hybrid quantum solid state system comprising two-level artificial atoms coupled to cavity confined optical and vibrational modes. In this system combining cavity quantum electrodynamics and cavity…

Intermolecular bonds are weak compared to covalent bonds, but they are strong enough to influence the properties of large molecular systems. In this work, we investigate how strong light-matter coupling inside an optical cavity can modify…

Chemical Physics · Physics 2021-03-17 Tor S. Haugland , Christian Schäfer , Enrico Ronca , Angel Rubio , Henrik Koch

We report on the influence of disorder on an exciton-polariton condensate in a ZnO based bulk planar microcavity and compare experimental results with a theoretical model for a non-equilibrium condensate. Experimentally, we detect intensity…

Strong coupling between light and matter is possible with a variety of organic materials. In contrast to the simpler inorganic case, organic materials often have a complicated spectrum, with vibrationally dressed electronic transitions.…

Mesoscale and Nanoscale Physics · Physics 2018-02-02 M. Ahsan Zeb , Peter G. Kirton , Jonathan Keeling

In the vibrational strong coupling (VSC) regime, molecular vibrations and resonant low-frequency cavity modes form light-matter hybrid states, named vibrational polaritons, with characteristic IR spectroscopic signatures. Here, we introduce…

Chemical Physics · Physics 2025-12-02 Eric W. Fischer , Jan A. Syska , Peter Saalfrank

Polariton chemistry has emerged as a new approach to directing molecular systems via strong light-matter interactions in confined photonic media. In this work, we implement a classical electrodynamics-molecular dynamics method to…

Chemical Physics · Physics 2025-07-18 Tuan H. Nguyen , Raphael F. Ribeiro

We show how coupling an ensemble of bistable systems to a common cavity field affects the collective stochastic behavior of this ensemble. In particular, the cavity provides an effective interaction between the systems, and parametrically…

Statistical Mechanics · Physics 2024-01-24 Kalle S. U. Kansanen , Tero T. Heikkilä

New effects of polarization multistability and polarization hysteresis in a coherently driven polariton condensate in a semiconductor microcavity are predicted and theoretically analyzed. The multistability arises due to…

We present a study of the macroscopic dynamics of a polariton condensate formed by non-resonant optical excitation in a quasi-one-dimensional ring-shaped microcavity. The presence of a gradient in the cavity photon energy creates a…