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Following experimental evidence that vibrational polaritons, formed from collective vibrational strong coupling (VSC) in optical microcavities, can modify ground-state reaction rates, a spate of theoretical explanations relying on…

Chemical Physics · Physics 2023-04-14 Matthew Du , Yong Rui Poh , Joel Yuen-Zhou

Recent experiments suggest that vibrational strong coupling (VSC) may significantly modify ground-state chemical reactions and their rates even without external pumping. The intrinsic mechanism of this "vacuum-field catalysis" remains…

Chemical Physics · Physics 2020-06-17 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

We study the dynamics of multimode polariton lasing in organic microcavities by using a second-order cumulant equation approach. By inspecting the time evolution of the photon mode occupations, we show that if multiple lasing peaks are…

Resonant photoelastic coupling in semiconductor nanostructures opens new perspectives for strongly enhanced light-sound interaction in optomechanical resonators. One potential problem, however, is the reduction of the cavity Q-factor…

Mesoscale and Nanoscale Physics · Physics 2014-11-19 G. Rozas , A. E. Bruchhausen , A. Fainstein , B. Jusserand , A. Lemaître

Semiconductor microcavities, in which strong coupling of excitons to confined photon modes leads to the formation of exciton-polariton modes, have increasingly become a focus for the study of spontaneous coherence, lasing, and condensation…

Strongly Correlated Electrons · Physics 2007-05-23 J. Keeling , F. M. Marchetti , M. H. Szymanska , P. B. Littlewood

The concept of modifying molecular dynamics in strongly coupled exciton-polariton systems is an emerging topic in photonics due to its potential to produce customized chemical systems with tailored photophysical properties. However, before…

Materials Science · Physics 2020-10-09 Bin Liu , Vinod M. Menon , Matthew Y. Sfeir

Strong spin-orbit coupling and inversion symmetry breaking in transition metal dichalcogenide monolayers yield the intriguing effects of valley-dependent optical selection rules. As such, it is possible to substantially polarize valley…

The rapidly developing and converging fields of polaritonic chemistry and quantum optics necessitate a unified approach to predict strongly-correlated light-matter interactions with atomic-scale resolution. Combining concepts from both…

Quantum Physics · Physics 2018-09-19 Johannes Flick , Prineha Narang

We developed a theory of electron scattering by a short-range repulsive potential in a cavity. In the regime of ultrastrong electron coupling to the cavity electromagnetic field, the vacuum fluctuations of the field result in the dynamical…

Mesoscale and Nanoscale Physics · Physics 2022-10-13 D. A. Zezyulin , S. A. Kolodny , O. V. Kibis , I. V. Tokatly , I. V. Iorsh

Planar microcavities filled with active materials containing excitonic resonances host radiative exciton-polariton (polariton) modes with in-plane wave vectors within the light cone. They also host at least one mode guided in the cavity…

Chemical reactions and energy transport phenomena have been experimentally reported to be significantly affected by strong light-matter interactions and vibrational polariton formation. These quasiparticles exhibit nontrivial transport…

Chemical Physics · Physics 2023-07-21 Enes Suyabatmaz , Raphael F. Ribeiro

We study the elastic response of a stationarily driven system of a cavity field strongly coupled with molecular excitons, taking into account the main dissipation channels due to the finite cavity linewidth and molecular vibrations. We show…

Quantum Physics · Physics 2021-02-24 Kalle S. U. Kansanen , J. Jussi Toppari , Tero T. Heikkilä

Cavity quantum electrodynamics provides a powerful tool to manipulate material properties, yet it remains a matter of debate whether and how quantized fields affect the periodicity of crystals. Here, we extend Bloch's theorem to crystals…

Materials Science · Physics 2026-01-14 Giovanna Bruno , Rosario Roberto Riso , Henrik Koch , Enrico Ronca

Strong coupling of molecules to vacuum fields has been widely reported to lead to modified chemical properties such as reaction rates. However, some recent attempts to reproduce infrared strong coupling results have not been successful,…

Mesoscale and Nanoscale Physics · Physics 2024-01-03 Philip A. Thomas , Wai Jue Tan , Vasyl G. Kravets , Alexander N. Grigorenko , William L. Barnes

A symmetrical structure consisting of a low refractive index dielectric layer between two metallic films, i.e. an optical cavity, surrounded by a semi-infinite dielectric medium of higher refractive index, forms an optical system capable of…

Optics · Physics 2025-05-06 Alejandro Doval , Yago Arosa , Raúl de la Fuente

We consider an array of coupled optical cavities, each containing a multi-atom ensemble. We show that the nonlinearity inherent in the cooperative dynamics of the atoms in each ensemble coupled to the respective cavity field allows for the…

Quantum Physics · Physics 2015-05-13 M. Paternostro , G. S. Agarwal , M. S. Kim

Band engineering stands as an efficient route to induce strongly correlated quantum many-body phenomena. Besides inspiring analogies among diverse physical fields, tuning on demand the group velocity is highly attractive in photonics…

We present a powerful formalism, disordered collective dynamics using truncated equations (d-CUT-E), to simulate the ultrafast quantum dynamics of molecular polaritons in the collective strong coupling regime, where a disordered ensemble of…

Quantum Physics · Physics 2024-04-09 Juan B. Pérez-Sánchez , Federico Mellini , Noel C. Giebink , Joel Yuen-Zhou

We study the collective optical response of an atomic ensemble confined within a single-mode optical cavity by stochastic electrodynamics simulations that include the effects of atomic position correlations, internal level structure, and…

Quantum Physics · Physics 2017-08-28 Mark D. Lee , Stewart D. Jenkins , Yael Bronstein , Janne Ruostekoski

We predict magnon polariton states circulating unidirectionally in a microwave cavity when loaded by a number of magnets on special lines. Realistic finite-element numerical simulations, including dielectric, time-dependent and non-linear…

Mesoscale and Nanoscale Physics · Physics 2020-08-26 Weichao Yu , Tao Yu , Gerrit E. W. Bauer
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