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In this paper, we address an important question of the relationship between fluctuation theorems for the dissipated work $W_{d} = W-\Delta F$ with general finite-time (like Jarzynski equality and Crooks relation) and infinite-time (like…

Statistical Mechanics · Physics 2019-05-31 A. Mandaiya , I. M. Khaymovich

Systems that are driven out of thermal equilibrium typically dissipate random quantities of energy on microscopic scales. Crooks fluctuation theorem relates the distribution of these random work costs with the corresponding distribution for…

Quantum Physics · Physics 2018-02-13 Johan Aberg

Large deviation theory provides a framework to understand macroscopic fluctuations and collective phenomena in many-body nonequilibrium systems in terms of microscopic dynamics. In these lecture notes we discuss the large deviation…

Statistical Mechanics · Physics 2025-01-17 Pablo I. Hurtado

In equilibrium, the fluctuation-dissipation theorem (FDT) expresses the response of an observable to a small perturbation by a correlation function of this variable with another one that is conjugate to the perturbation with respect to…

Statistical Mechanics · Physics 2010-10-13 Udo Seifert , Thomas Speck

We present fluctuation theorems and moment generating function equalities for generalized thermodynamic observables and quantum dynamics described by completely positive trace preserving (CPTP) maps, with and without feedback control. Our…

Quantum Physics · Physics 2013-10-01 Tameem Albash , Daniel A. Lidar , Milad Marvian , Paolo Zanardi

A central endeavor of thermodynamics is the measurement of free energy changes. Regrettably, although we can measure the free energy of a system in thermodynamic equilibrium, typically all we can say about the free energy of a…

Statistical Mechanics · Physics 2012-04-10 David A. Sivak , Gavin E. Crooks

The Trajectory Class Fluctuation Theorem (TCFT) substantially strengthens the Second Law of Thermodynamics -- that, in point of fact, can be a rather weak bound on resource fluxes. Practically, it improves empirical estimates of free…

Statistical Mechanics · Physics 2024-04-30 Gregory Wimsatt , Alexander B. Boyd , James P. Crutchfield

The fluctuation-dissipation relation for the classical definition of work is extended to thermally isolated systems, in classical and quantum realms. From this, the optimal work variance is calculated, showing it achieves its minimum…

Statistical Mechanics · Physics 2023-11-01 Pierre Nazé

In this short communication, I give a very simple derivation of the Jarzynski equality, which allows to compute the free energy difference of a body, which is driven between two equilibrium states $A$ and $B$ by an external (time-dependent)…

Statistical Mechanics · Physics 2016-08-16 Frédéric Douarche

The work fluctuation theorem (FT) is a symmetry connecting the moment generating functions (MGFs) of the work extracted in a given process and in its time-reversed counterpart. We show that, equivalently, the FT for work in isolated quantum…

Quantum Physics · Physics 2023-11-29 Vasco Cavina , Sadeq S. Kadijani , Massimiliano Esposito , Thomas Schmidt

Mean-field theories of the glass transition predict a phase transition to a dynamically arrested state, yet no such transition is observed in experiments or simulations of finite-dimensional systems. We resolve this long-standing…

Soft Condensed Matter · Physics 2025-12-16 Corentin C. L. Laudicina , Liesbeth M. C. Janssen , Grzegorz Szamel

Stochastic thermodynamics is formulated under the assumption of perfect knowledge of all thermodynamic parameters. However, in any real-world experiment, there is non-zero uncertainty about the precise value of temperatures, chemical…

Statistical Mechanics · Physics 2024-01-11 Jan Korbel , David H. Wolpert

We study work extraction processes mediated by finite-time interactions with an ambient bath -- \emph{partial thermalizations} -- as continuous time Markov processes for two-level systems. Such a stochastic process results in fluctuations…

Statistical Mechanics · Physics 2021-05-05 Maria Quadeer , Kamil Korzekwa , Marco Tomamichel

Two approaches to small-scale and quantum thermodynamics are fluctuation relations and one-shot statistical mechanics. Fluctuation relations (such as Crooks' Theorem and Jarzynski's Equality) relate nonequilibrium behaviors to equilibrium…

Statistical Mechanics · Physics 2015-09-16 Nicole Yunger Halpern , Andrew J. P. Garner , Oscar C. O. Dahlsten , Vlatko Vedral

An equilibrium system which is perturbed by an external potential relaxes to a new equilibrium state, a process obeying the fluctuation-dissipation theorem. In contrast, perturbing by nonconservative forces yields a nonequilibrium steady…

Statistical Mechanics · Physics 2019-12-17 Kiryl Asheichyk , Matthias Krüger

We give a quantum version of the Jarzynski relation between the distribution of work done over a certain time-interval on a system and the difference of equilibrium free energies. The main new ingredient is the identification of work…

Condensed Matter · Physics 2015-05-26 Wojciech De Roeck , Christian Maes

Returning a system to a desired state under a force field involves a thermodynamic cost, i.e., {\it work}. This cost fluctuates for a small-scale system from one experimental realization to another. We introduce a general framework to…

Statistical Mechanics · Physics 2022-12-07 Deepak Gupta , Carlos A. Plata

We propose a method to evaluate general thermodynamic fluctuations in open quantum systems, based on performing a two-point measurement scheme on the system using dynamics-dependent thermodynamic observables. Our approach allows one to…

Quantum Physics · Physics 2026-04-30 Alessandra Colla , Andrea Smirne , Heinz-Peter Breuer , Bassano Vacchini

Fluctuation dynamics of an experimentally measured observable offer a primary signal for nonequilibrium systems, along with dynamics of the mean. While universal speed limits for the mean have actively been studied recently, constraints for…

Statistical Mechanics · Physics 2024-11-08 Ryusuke Hamazaki

The estimate of free energy changes based on Bennett's acceptance ratio method is examined in several limiting cases and compared with other estimates based on the Jarzynski equality and on the Crooks relation. While the absolute amount of…

Statistical Mechanics · Physics 2015-06-12 Seongjin Kim , Yong Woon Kim , Peter Talkner , Juyeon Yi
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