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We theoretically investigate electrostatic properties between two charged surfaces with a grafted polyelectrolyte layer in an aqueous electrolyte solution by using the Poisson-Boltzmann approach accounting for ion partitioning. In order to…

Soft Condensed Matter · Physics 2022-02-07 Jun-Sik Sin

The recently developed modified Donnan (mD) model provides a simple and useful description of the electrical double layer in microporous carbon electrodes, suitable for incorporation in porous electrode theory. By postulating an attractive…

Chemical Physics · Physics 2014-01-22 P. M. Biesheuvel , S. Porada , M. Levi , M. Z. Bazant

The Jones-Ray effect is an anomalous minimum in the surface tension of aqueous electrolytes at millimolar salt concentrations. We experimentally demonstrated that intentionally added ionic surfactants induce the Jones-Ray effect. The…

Chemical Physics · Physics 2018-10-22 Yuki Uematsu , Kengo Chida , Hiroki Matsubara

We present a novel microfield approach for studying the dependence of the orientational polarization of the water in aqueous electrolyte solutions upon the salt concentration and temperature. The model takes into account the orientation of…

Chemical Physics · Physics 2016-07-15 Nir Gavish , Keith Promislow

The electronic properties of non-interacting particles moving on a two-dimensional bricklayer lattice are investigated numerically. In particular, the influence of disorder in form of a spatially varying random magnetic flux is studied. In…

Disordered Systems and Neural Networks · Physics 2009-12-22 L. Schweitzer

The intricate role of shear viscosity and ion-pair relaxations on ionic conductivity mechanisms and the underlying changes induced by salt concentration ($c$) in organic liquid electrolytes remain poorly understood despite their widespread…

When electrons are confined in two dimensions and subjected to strong magnetic fields, the Coulomb interactions between them become dominant and can lead to novel states of matter such as fractional quantum Hall liquids. In these liquids…

Mesoscale and Nanoscale Physics · Physics 2015-05-14 Kirill I. Bolotin , Fereshte Ghahari , Michael D. Shulman , Horst L. Stormer , Philip Kim

Using a solid electrolyte to tune the carrier density in thin-film materials is an emerging technique that has potential applications in both basic and applied research. Until now, only materials containing small ions, such as protons and…

Materials Science · Physics 2017-06-16 Jialin Zhao , Meng Wang , Xuefu Zhang , Yue Lv , Tianru Wu , Shan Qiao , Shufeng Song , Bo Gao

The article presents a comprehensive study of counterion dynamics around a generic linear polyelectrolyte (PE) chain with the help of coarse-grained computer simulations. The ion-chain coupling is discussed in the form of binding time,…

Soft Condensed Matter · Physics 2022-04-13 Keerthi Radhakrishnan , Sunil P. Singh

We study the adsorption-desorption transition of polyelectrolyte chains onto planar, cylindrical and spherical surfaces with arbitrarily high surface charge densities by massive Monte Carlo computer simulations. We examine in detail how the…

Soft Condensed Matter · Physics 2016-10-05 Sidney J. de Carvalho , Ralf Metzler , Andrey G. Cherstvy

In a two-dimensional electron gas, the electron-electron interaction generally becomes stronger at lower carrier densities and renormalizes the Fermi liquid parameters such as the effective mass of carriers. We combine experiment and theory…

Mesoscale and Nanoscale Physics · Physics 2016-11-03 J. Li , L. Z. Tan , K. Zou , A. A. Stabile , D. J. Seiwell , K. Watanabe , T. Taniguchi , Steven G. Louie , J. Zhu

We experimentally and theoretically consider highly condensed planar brushes made of charged polymers. Using x-ray reflectivity on polyelectrolytes which are anchored at the water-air interface, it is shown that such strongly stretched…

We measured the conductance fluctuation of bi- and trilayer graphene devices prepared on mechanical exfoliated graphene by an all-dry, lithography-free process using an ultrathin quartz filament as a shadow mask. Reproducible fluctuations…

Mesoscale and Nanoscale Physics · Physics 2009-11-13 Neal E. Staley , Conor Puls , Ying Liu

We report measurements of turbulent drag reduction of two different polyelectrolyte solutions: DNA and hydrolyzed Polyacrylamide. Changing the salt concentration in the solutions allows us to change the flexibility of the polymer chains.…

Fluid Dynamics · Physics 2007-05-23 Christian Wagner , Yassine Amarouchene , Patrick Doyle , Daniel Bonn

The complexation of a polyelectrolyte with an oppositely charged spherical macroion is studied for both salt free and salty solutions. When a polyelectrolyte winds around the macroion, its turns repel each other and form an almost…

Soft Condensed Matter · Physics 2009-10-31 T. T. Nguyen , B. I. Shklovskii

Mean-field electrostatics is used to calculate the bending moduli of an electric double layer for fixed surface charge density of a macroion in a symmetric 1:1 electrolyte. The resulting expressions for bending stiffness, Gaussian modulus,…

Soft Condensed Matter · Physics 2018-08-06 Guilherme Volpe Bossa , Bjorn K. Berntson , Sylvio May

The alloying of the group-III transparent semiconducting sesquioxides In$_2$O$_3$ and Ga$_2$O$_3$ can lead to a modulation of the properties of the parent compounds, e.g., the shallow- and deep-donor character of the oxygen vacancy or the…

Materials Science · Physics 2024-11-25 Alexandra Papadogianni , Takahiro Nagata , Oliver Bierwagen

We probe, using the Surface Forces Apparatus, the thermal response of poly(N-isopropylacrylamide) (PNIPAM) brushes of various grafting densities, grown from plasma-activated mica by means of surface-initiated polymerization. We thus show…

Soft Condensed Matter · Physics 2009-10-09 Ibrahim Bou Malham , Lionel Bureau

Thermodynamic and transport characteristics of a clean two-dimensional interacting electron gas are shown to be sensitive to the weak perpendicular magnetic field even at temperatures much higher than the cyclotron energy, when the quantum…

Mesoscale and Nanoscale Physics · Physics 2007-07-19 T. A. Sedrakyan , E. G. Mishchenko , M. E. Raikh

The generalized tight-binding model, based on the subenvelope functions of distinct sublattices, is developed to investigate the magnetic quantization in sliding bilayer graphenes. The relative shift of two graphene layers induces a…

Materials Science · Physics 2016-11-18 Yao-Kung Huang , Szu-Chao Chen , Yen-Hung Ho , Chiun-Yan Lin , Ming-Fa Lin