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We demonstrate the accuracy of ground-state energies of the transcorrelated Hamiltonian, employing sophisticated Jastrow factors obtained from variational Monte Carlo, together with the coupled cluster and distinguishable cluster methods at…

We present an accurate method for calculating hyperfine coupling constants (HFCCs) based on the complete active space second-order perturbation theory (CASPT2) with full internal contraction. The HFCCs are computed as a first-order property…

Chemical Physics · Physics 2017-03-20 Toru Shiozaki , Takeshi Yanai

We study the performance of spin-component-scaled second-order M{\o}ller-Plesset perturbation theory (SCS-MP2) for the prediction of the lattice constant, bulk modulus, and cohesive energy of 12 simple, three-dimensional, covalent and ionic…

Materials Science · Physics 2022-11-23 Tamar Goldzak , Xiao Wang , Hong-Zhou Ye , Timothy C. Berkelbach

This paper studies the statistical and computational limits of high-order clustering with planted structures. We focus on two clustering models, constant high-order clustering (CHC) and rank-one higher-order clustering (ROHC), and study the…

Statistics Theory · Mathematics 2023-10-04 Yuetian Luo , Anru R. Zhang

We make progress towards a 3D finite-element model for the magnetization of a high temperature superconductor (HTS): We suggest a method that takes into account demagnetisation effects and flux creep, while it neglects the effects…

Accurate state of charge estimation is critical for the success of electric vehicle battery management strategies, but it is well known that conventional estimators suffer from two fundamental shortcomings: cumulative errors that grow over…

Machine Learning · Computer Science 2026-05-14 Han Wang , Ying Wang , Bing Wang

The recursive least-squares (RLS) algorithm is one of the most well-known algorithms used in adaptive filtering, system identification and adaptive control. Its popularity is mainly due to its fast convergence speed, which is considered to…

Machine Learning · Computer Science 2011-06-06 H. He , D. Hu , X. Xu

We present an implementation and analysis of a stochastic high performance algorithm to calculate the correlation energy of three dimensional periodic systems in second-order M{\o}ller-Plesset perturbation theory (MP2). In particular we…

Chemical Physics · Physics 2018-02-12 Tobias Schäfer , Benjamin Ramberger , Georg Kresse

We present an efficient moment-based perturbation scheme for evaluating polarizability tensors of small molecules at a fraction of the computational cost of conventional energy-based approaches. Rather than applying explicit electric…

Chemical Physics · Physics 2026-05-26 Anoop Ajaya Kumar Nair , Julian Beßner , Timo Jacob , Elvar Örn Jónsson

Algebraic diagrammatic construction (ADC) theory is a computationally efficient and accurate approach for simulating electronic excitations in chemical systems. However, for the simulations of excited states in molecules with unpaired…

Chemical Physics · Physics 2022-11-15 Terrence L. Stahl , Samragni Banerjee , Alexander Yu. Sokolov

The task of computing wavefunctions that are accurate, yet simple enough mathematical objects to use for reasoning has long been a challenge in quantum chemistry. The difficulty in drawing physical conclusions from a wavefunction is often…

Chemical Physics · Physics 2024-03-12 Nicole M. Braunscheidel , Arnab Bachhar , Nicholas J. Mayhall

We embark on a quest to identify small molecules in the chemical space that can potentially violate Hund's rule. Utilizing twelve TDDFT approximations and the ADC(2) many-body method, we report the energies of S$_1$ and T$_1$ excited states…

Chemical Physics · Physics 2024-05-24 Atreyee Majumdar , Raghunathan Ramakrishnan

This paper proposes a tractable family of remainder-form mixed-monotone decomposition functions that are useful for over-approximating the image set of nonlinear mappings in reachability and estimation problems. Our approach applies to a…

Optimization and Control · Mathematics 2024-06-25 Mohammad Khajenejad , Sze Zheng Yong

We present two new algorithms for approximating and updating the hierarchical Tucker decomposition of tensor streams. The first algorithm, Batch Hierarchical Tucker - leaf to root (BHT-l2r), proposes an alternative and more efficient way of…

Numerical Analysis · Mathematics 2024-12-24 Doruk Aksoy , Alex A. Gorodetsky

We develop an expansion of the turbulent stress tensor into a double series of contributions from different scales of motion and different orders of space-derivatives of velocity, a Multi-Scale Gradient (MSG) expansion. The expansion is…

Chaotic Dynamics · Physics 2009-11-11 Gregory L. Eyink

Downfolding coupled cluster (CC) techniques have recently been introduced into quantum chemistry as a tool for the dimensionality reduction of the many-body quantum problem. As opposed to earlier formulations in physics and chemistry based…

Quantum Physics · Physics 2022-03-23 Nicholas P. Bauman , Karol Kowalski

Many real-world datasets are represented as tensors, i.e., multi-dimensional arrays of numerical values. Storing them without compression often requires substantial space, which grows exponentially with the order. While many tensor…

Machine Learning · Computer Science 2023-09-21 Taehyung Kwon , Jihoon Ko , Jinhong Jung , Kijung Shin

We introduce TQCompressor, a novel method for neural network model compression with improved tensor decompositions. We explore the challenges posed by the computational and storage demands of pre-trained language models in NLP tasks and…

Machine Learning · Computer Science 2024-01-30 V. Abronin , A. Naumov , D. Mazur , D. Bystrov , K. Tsarova , Ar. Melnikov , I. Oseledets , S. Dolgov , R. Brasher , M. Perelshtein

One of the most challenging problems in solid state systems is the microscopic analysis of electronic correlations. A paramount minimal model that encodes correlation effects is the Hubbard Hamiltonian, which -- albeit its simplicity -- is…

Strongly Correlated Electrons · Physics 2022-11-03 Karim Zantout , Steffen Backes , Roser Valenti

In this paper, we account for approaches of sparse recovery from large underdetermined linear models with perturbation present in both the measurements and the dictionary matrix. Existing methods have high computation and low efficiency.…

Information Theory · Computer Science 2012-05-02 Xuebing Han , Hao Zhang , Gang Li